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环丙胺

环丙胺用途

【用途一】
用作环丙沙星的中间体，亦用于农药和植物保护剂的合成
【用途二】
环丙胺是除草剂环丙津、杀虫剂灭蝇胺的中间体，也是医药中间体。
【用途三】
医药中间体，主要用于生产环丙氟哌酸，亦用于农药和植物保护剂的合成。

环丙胺名称

[ CAS 号 ]:
765-30-0

[ 中文名 ]:
环丙胺

[ 英文名 ]:
Cyclopropanamine

[中文别名 ]:

[英文别名 ]:

Cyclopropylamine
1,2-Ethanediamine,N-cyclopropyl
N-Cyclopropyl-aethylendiamin
c-propyl amine
cyclopropylNH2
N-cyclopropylethane-1,2-diamine
cyclopropyl-amine
Cyclopropanamine
cyclopropylethylenediamine
MFCD00001301

环丙胺物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
49.3±8.0 °C at 760 mmHg

[ 熔点 ]:
-50 °C

[ 分子式 ]:
C₃H₇N

[ 分子量 ]:
57.094

[ 闪点 ]:
-25.6±0.0 °C

[ 精确质量 ]:
57.057850

[ PSA ]:
26.02000

[ LogP ]:
-0.30

[ 外观性状 ]:
透明液体

[ 蒸汽压 ]:
299.8±0.1 mmHg at 25°C

[ 折射率 ]:
1.484

[ 储存条件 ]:
Flammables area

[ 水溶解性 ]:
水溶性：完全混溶

环丙胺MSDS

环丙胺安全信息

[ 符号 ]:

GHS02, GHS05, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H302-H314

[ 警示性声明 ]:
P210-P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US)

[ 危害码 (欧洲) ]:
C:Corrosive

[ 风险声明 (欧洲) ]:
R11;R22;R34

[ 安全声明 (欧洲) ]:
S16-S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 2733 3/PG 2

[ WGK德国 ]:
2

[ RTECS号 ]:
GZ0685500

[ 包装等级 ]:
II

[ 危险类别 ]:
3

[ 海关编码 ]:
2921300090

环丙胺合成路线

环丙胺上下游产品

环丙胺上游产品

环丙胺下游产品

环丙胺制备

可有多种合成路线：（1）以1,3-丙二醇为原料，经溴化、氰化、环合、酰胺化、霍夫曼重排得产物；（2）以γ-丁内酯为原料，经高压氯化、酯化、环合、氨解、霍夫曼降解得产物；（3）以乙酰乙酸乙酯为原料，经与环氧乙烷缩合并环化、开环再环合、肟化、重排、降解得产物。

环丙胺海关

[ 海关编码 ]: 2921300090

[ 中文概述 ]:
2921300090 其他环（烷，烯，萜烯）单胺或多胺（包括其衍生物及它们的盐）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2921300090 other cyclanic, cyclenic or cyclotherpenic mono- or polyamines, and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

环丙胺文献

Synthesis and antibacterial activity of some novel 4-oxopyrido[2,3-a]phenothiazines.

Arch. Pharm. (Weinheim) 347(11) , 861-72, (2014)

A series of substituted 4-oxopyrido[2,3-a]phenothiazine-3-carboxylic acids (6a-d) were prepared via cyclization of the corresponding ethyl 7-(arylthioxy)-8-nitro(or azido)-4-oxoquinoline-3-carboxylate...

Cyclopropylamines from N,N-dialkylcarboxamides and Grignard reagents in the presence of titanium tetraisopropoxide or methyltitanium triisopropoxide.

Chemistry 16 , 13862-13875, (2010)

Thirty-three different N,N-dialkyl- and N-alkyl-N-phosphorylalkyl-substituted carboxamides 9-17 were treated with unsubstituted as well as with 2-alkyl-, 2,2-dialkyl-, and 3-alkenyl-substituted ethylm...

Cyclopropylamine inactivation of cytochromes P450: role of metabolic intermediate complexes.

Arch. Biochem. Biophys. 436(2) , 265-75, (2005)

The inactivation of cytochrome P450 enzymes by cyclopropylamines has been attributed to a mechanism involving initial one-electron oxidation at nitrogen followed by scission of the cyclopropane ring l...

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环丙胺