214834-18-1

• 常用中文名：4-氨基硫代羰基四氢吡啶-1(2H)-甲酸叔丁酯
• 常用英文名：tert-Butyl 4-carbamothioylpiperidine-1-carboxylate
• CAS号：214834-18-1
• 分子式：C₁₁H₂₀N₂O₂S
• 分子量：244.354
• 发布时间：2018-08-22 23:02:15
• 更新时间：2024-01-02 17:10:25

名称

• 中文名: N－Boc-4-硫代甲酰胺
• 英文名: tert-butyl 4-carbamothioylpiperidine-1-carboxylate
• 中文别名: Boc-哌啶-4-硫代甲酰胺; 4-氨基硫代羰基四氢吡啶-1(2H)-甲酸叔丁酯
• 英文别名: tert-butyl 4-thiocarbamoylpiperidine-1-carboxylate; 1-Boc-4-thiocarbamoylpiperidine; 1-tert-Butoxycarbonylpiperidine-4-carbothioamide; tert-Butyl 4-carbamothioylpiperidine-1-carboxylate; Tert-butyl4-(aminocarbothioyl)tetrahydropyridine-1(2H)-carboxylate; 2-Methyl-2-propanyl 4-carbamothioyl-1-piperidinecarboxylate; tert-butyl 4-(aminocarbonothioyl)piperidine-1-carboxylate; 1-Piperidinecarboxylic acid, 4-(aminothioxomethyl)-, 1,1-dimethylethyl ester; tert-butyl-4-carbamothioylpiperidine-1-carboxylate; N-boc-4-aminothiocarbonylpiperidine; Piperidine-4-thiocarboxamide,N1-BOC protected

物化性质

• 密度: 1.2±0.1 g/cm3
• 沸点: 356.0±52.0 °C at 760 mmHg
• 熔点: 130-131ºC
• 分子式: C₁₁H₂₀N₂O₂S
• 分子量: 244.354
• 闪点: 169.1±30.7 °C
• 精确质量: 244.124542
• PSA: 87.65000
• LogP: 1.07
• 外观性状: 白色 固体
• 蒸汽压: 0.0±0.8 mmHg at 25°C
• 折射率: 1.546
• 储存条件: 室温

MSDS

Name: tert-Butyl 4-(aminocarbothioyl)tetrahydropyridine-1(2H)-carboxylate Material Safety Data Sheet Synonym: 1-(t-Butyloxycarbonyl)piperidine-4-thiocarboxamid CAS: 214834-18-1 Section 1 - Chemical Product MSDS Name:tert-Butyl 4-(aminocarbothioyl)tetrahydropyridine-1(2H)-carboxylate Material Safety Data Sheet Synonym:1-(t-Butyloxycarbonyl)piperidine-4-thiocarboxamid Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 214834-18-1 tert-Butyl 4-(aminocarbothioyl)tetrahy 95+% unlisted Hazard Symbols: None Listed. Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Not available. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 214834-18-1: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white Odor: stench pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 122 - 124 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Not available. Solubility in water: Specific Gravity/Density: Molecular Formula: C11H20N2O2S Molecular Weight: 244 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Oxidizing agents, reducing agents, acids, bases, acid chlorides. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 214834-18-1 unlisted. LD50/LC50: Not available. Carcinogenicity: tert-Butyl 4-(aminocarbothioyl)tetrahydropyridine-1(2H)-carboxylate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 214834-18-1: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 214834-18-1 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 214834-18-1 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xn:Harmful;
• 风险声明 (欧洲): R22;R36/37/38
• 安全声明 (欧洲): S22-S26-S36/37/39
• 海关编码: 2933399090

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海关

海关编码	2933399090
中文概述	2933399090. 其他结构含非稠合吡啶环的化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期
Summary	2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%