- 上海化源世纪贸易有限公司
- 上海市 上海市 普陀区
- 产品名：1,1,2-三氯-2,2,3-三氟环丁烷, 98%
- 纯度：98.0%
- 规格：
- 联系人：徐经理
- 联系电话：13311869306
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697-17-6
697-17-6结构式
| 中文名 | 三氯-三氯环丁烷 |
|---|---|
| 英文名 | 1,1,2-trichloro-2,3,3-trifluorocyclobutane |
| 中文别名 | 1,1,2-三氯-2,2,3-三氟环丁烷 |
| 英文别名 |
1,1,2-trichloro-2,3,3-trifluoro-cyclobutane
EINECS 211-804-8 2,3,3-Trifluor-1,1,2-trichlor-cyclobutan 1.1.2-Trifluoro-2.3.3-trichloro-cyclobutane 1.1.2-Trichlor-2.3.3-trifluorcyclobutan 2,3,3-trichloro-1,1,2-trifluorocyclobutane MFCD00039439 |
| 密度 | 1.594 g/mL at 25 °C(lit.) |
|---|---|
| 沸点 | 120 °C(lit.) |
| 分子式 | C4H2Cl3F3 |
| 分子量 | 213.41300 |
| 闪点 | 119-120°C |
| 精确质量 | 211.91700 |
| LogP | 3.10390 |
| 折射率 | n20/D 1.416(lit.) |
| 储存条件 | 存放在密封容器内，并放在阴凉，干燥处。储存的地方必须远离氧化剂。 |
| 稳定性 | 远离氧化物，火源，热源，明火。 |
| 分子结构 | 1、 摩尔折射率：33.40 2、 摩尔体积（m3/mol）：128.0 3、 等张比容（90.2K）：293.6 4、 表面张力（dyne/cm）：27.6 5、 介电常数： 6、 偶极距（10 -24cm 3）： 7、 极化率：13.24 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:3.1 2.氢键供体数量:0 3.氢键受体数量:3 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积0 7.重原子数量:10 8.表面电荷:0 9.复杂度:169 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:1 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：无色液体。 2. 密度（g/mL,25/4℃）：1.594 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：120 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,5.2kPa）：未确定 7. 折射率：1.416 8. 闪点（ºC）：119-120 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 。 |
Synonym:None Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/21/22 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.The toxicological properties of this material have not been fully investigated.Air sensitive. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated. Extinguishing Media: Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out. Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. Place under an inert atmosphere. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Handle under an inert atmosphere. Store protected from air. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Do not expose to air. Store under an inert atmosphere. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 697-17-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: almost colorless Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 120 deg C Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 1.5940g/cm3 Molecular Formula: C4H2Cl3F3 Molecular Weight: 213.42 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Conditions to Avoid: Incompatible materials, exposure to air, excess heat. Incompatibilities with Other Materials: Air, strong oxidizing agents, strong reducing agents, strong acids, strong bases. Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen fluoride gas. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 697-17-6 unlisted. LD50/LC50: Not available. Carcinogenicity: 1,1,2-Trichloro-2,3,3-Trifluorocyclobutane - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. Safety Phrases: S 28A After contact with skin, wash immediately with plenty of water. S 36/37 Wear suitable protective clothing and gloves. S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 697-17-6: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 697-17-6 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 697-17-6 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 通常对水是不危害的，若无政府许可，勿将材料排入周围环境。
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| 危害码 (欧洲) | Xn,Xi |
|---|---|
| 风险声明 (欧洲) | 20/21/22-36/37 |
| 安全声明 (欧洲) | S26-S36 |
| 危险品运输编码 | 2810 |
| WGK德国 | 3 |
| 包装等级 | III |
| 危险类别 | 6.1 |
| 海关编码 | 2903890090 |
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~53%
697-17-6 |
| 文献：Abdo, Basil T. Journal of Physical Chemistry A, 1999 , vol. 103, # 12 p. 1758 - 1767 |
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697-17-6 |
| 文献：Journal of the American Chemical Society, , vol. 91, p. 5933 - 5936 |
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697-17-6 |
| 文献：Journal of the American Chemical Society, , vol. 81, p. 2678 |
| 海关编码 | 2903890090 |
|---|---|
| 中文概述 | 2903890090. 其他环烷烃、环烯烃或环萜烯烃的卤化衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2903890090. halogenated derivatives of cyclanic, cyclenic or cyclotherpenic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0% |