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| 中文名 | 氯甲酸对甲苯 |
|---|---|
| 英文名 | p-Tolyl chloroformate |
| 中文别名 | 对甲苯基氯甲酸 |
| 英文别名 |
4-tolyl chloroformate
EINECS 213-332-8 p-Tolyl chloroforMate 5GR 1-chlorocarbonyloxy-4-methyl-benzene Chloroformic acid p-tolyl ester 4-toluyl chloroformate Chloroformic acid 4-methylphenyl ester Phenyl chloroformate 4-Methylphenyl chloroformate MFCD00013255 |
| 密度 | 1.234g/cm3 |
|---|---|
| 沸点 | 207.2ºC at 760mmHg |
| 分子式 | C8H7ClO2 |
| 分子量 | 170.59300 |
| 闪点 | 85.6ºC |
| 精确质量 | 170.01300 |
| PSA | 26.30000 |
| LogP | 2.73260 |
| 外观性状 | Liquid | Clear colorless |
| 折射率 | n20/D 1.5099(lit.) |
| 储存条件 | -4℃以下，避光，通风干燥处，密封保存 |
| 稳定性 | 常温常压下稳定 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:2 4.可旋转化学键数量:2 5.互变异构体数量:无 6.拓扑分子极性表面积26.3 7.重原子数量:11 8.表面电荷:0 9.复杂度:139 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：无色液体 2. 密度（g/mL,15℃）：1.188 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：99.5 6. 折射率：1.5099 7. 闪点（ºC）：86 8. 自燃点或引燃温度（ºC）：未确定 9. 比旋光度（º）： 未确定 10. 蒸气压（kPa,25ºC）：未确定 11. 饱和蒸气压（kPa,60ºC）：未确定 12. 燃烧热（KJ/mol）：未确定 13. 临界温度（ºC）：未确定 14. 临界压力（KPa）：未确定 15. 油水（辛醇/水）分配系数的对数值：未确定 16. 爆炸上限（%,V/V）：未确定 17. 爆炸下限（%,V/V）：未确定 18. 溶解性：未确定 |
Synonym: None known. SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/21/22 34 SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful by inhalation, in contact with skin and if swallowed. Causes burns.Moisture sensitive.Corrosive. Potential Health Effects Eye: Causes eye burns. Lachrymator (substance which increases the flow of tears). May cause chemical conjunctivitis and corneal damage. Skin: Causes skin burns. May cause irritation and dermatitis. May cause cyanosis of the extremities. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
Ingestion: May cause severe and permanent damage to the digestive tract. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause systemic effects. Inhalation: Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects. Inhalation at high concentrations may cause CNS depression and asphixiation. Chronic: Effects may be delayed. SECTION 4 - FIRST AID MEASURES Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes). Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: SECTION 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible liquid. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated. Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Do NOT get water inside containers. SECTION 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Do not get water inside containers. SECTION 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Contents may develop pressure upon prolonged storage. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Do not allow contact with water. Use only in a chemical fume hood. Discard contaminated shoes. Use caution when opening. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Keep from contact with moist air and steam. Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep refrigerated. (Store below 4C/39F.) Store protected from moisture. SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 937-62-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: colorless Odor: chloroform-like pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 99.5 deg C @ 20.00mm Hg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: 86 deg C ( 186.80 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 1.1880g/cm3 Molecular Formula: ClCO2C6H4CH3 Molecular Weight: 170.60 SECTION 10 - STABILITY AND REACTIVITY Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Conditions to Avoid: Incompatible materials, ignition sources, moisture, excess heat, exposure to moist air or water. Incompatibilities with Other Materials: Moisture. Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Has not been reported SECTION 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 937-62-2 unlisted. LD50/LC50: Not available. Carcinogenicity: P-Tolyl Chloroformate - Not listed by ACGIH, IARC, or NTP. SECTION 12 - ECOLOGICAL INFORMATION SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. SECTION 14 - TRANSPORT INFORMATION IATA Shipping Name: CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S. Hazard Class: 6.1 (8) UN Number: 3277 Packing Group: II IMO Shipping Name: CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S. Hazard Class: 6.1 (8) UN Number: 3277 Packing Group: II RID/ADR Shipping Name: CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S. Hazard Class: 6.1 (8) UN Number: 3277 Packing group: II SECTION 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 34 Causes burns. Safety Phrases: S 25 Avoid contact with eyes. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 937-62-2: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 937-62-2 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 937-62-2 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION MSDS Creation Date: 5/07/1999 Revision #6 Date: 3/18/2003 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages. SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 通常对水是不危害的，若无政府许可，勿将材料排入周围环境
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| 符号 |
GHS05, GHS06 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H301-H311-H314-H331 |
| 警示性声明 | P261-P280-P305 + P351 + P338-P310 |
| 个人防护装备 | Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| 危害码 (欧洲) | T: Toxic; |
| 风险声明 (欧洲) | R23/24/25 |
| 安全声明 (欧洲) | 26-27-36/37/39-45 |
| 危险品运输编码 | UN 3277 6.1/PG 2 |
| WGK德国 | 3 |
| 包装等级 | II |
| 危险类别 | 6.1(a) |
| 海关编码 | 2915900090 |
|
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937-62-2 |
| 文献：WO2008/38175 A2, ; Page/Page column 39 ; |
|
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937-62-2 |
| 文献：Journal of the Chemical Society, , p. 253 |
|
~%
937-62-2 |
| 文献：Nippon Kagaku Zasshi, , vol. 76, p. 1108,1110 Chem.Abstr., , p. 17750 |
| 上游产品 4 | |
|---|---|
| 下游产品 10 | |
| 海关编码 | 2915900090 |
|---|---|
| 中文概述 | 2915900090. 其他饱和无环一元羧酸及其酸酐（酰卤、过氧）化物、过氧酸及其卤化、硝化、磺化、亚硝化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:5.5%. 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| 监管条件 | A.入境货物通关单 B.出境货物通关单 |
| 检验检疫 | R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验 |
| Summary | 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0% |
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