7582-04-9

• 常用中文名：丁烷-d10
• 常用英文名：1,1,1,2,2,3,3,4,4,4-decadeuteriobutane
• CAS号：7582-04-9
• 分子式：C₄D₁₀
• 分子量：68.18380
• 发布时间：2018-05-11 08:00:00
• 更新时间：2024-01-03 08:15:26
• 下载msds

名称

• 中文名: 丁烷-d10
• 英文名: 1,1,1,2,2,3,3,4,4,4-decadeuteriobutane
• 中文别名: 氘代丁烷
• 英文别名: MFCD00144856; Decadeuteriobutan; n-butane-d10; Butane-d10; n-Decadeuterio-butan; decadeuteriobutane

物化性质

• 密度: 2.11 (vs air)
• 沸点: -0.5ºC(lit.)
• 熔点: -138ºC(lit.)
• 分子式: C₄D₁₀
• 分子量: 68.18380
• 闪点: -60ºC
• 精确质量: 68.14100
• LogP: 1.80640
• 折射率: 1.354
• 储存条件: 密闭,阴凉干燥处保存，确保有良好的通风 温度不宜超过52°C
• 稳定性:

  避免强氧化剂，

  避免光，明火，高温

• 分子结构:

  五、分子性质数据：

  1、 摩尔折射率：20.58

  2、 摩尔体积（m³/mol）：94.5

  3、 等张比容（90.2K）：191.2

  4、 表面张力（dyne/cm）：16.7

  5、 介电常数（F/m）：1.76

  6、 极化率（10^-24cm³）：8.15

• 计算化学:

  1、 疏水参数计算参考值（XlogP）：

  2、 氢键供体数量：1

  3、 氢键受体数量：2

  4、 可旋转化学键数量：0

  5、 互变异构体数量：

  6、 拓扑分子极性表面积（TPSA）：37.3

  7、 重原子数量：5

  8、 表面电荷：0

  9、 复杂度：31

  10、 同位素原子数量：0

  11、 确定原子立构中心数量：0

  12、 不确定原子立构中心数量：0

  13、 确定化学键立构中心数量：0

  14、 不确定化学键立构中心数量：0

  15、 共价键单元数量：2

• 更多:

  1. 性状：气体

  2. 密度（g/mLat 25°C）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）：2.11

  4. 熔点（ºC）：-138

  5. 沸点（ºC,常压）：-0.5

  6. 沸点（ºC,0.76mmHg）：未确定

  7. 折射率（n20/D）：未确定

  8. 闪点（ºC）：-60

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（mmHg,37.7ºC）：2668.5

  12. 饱和蒸气压（kPa,114.4 ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（MPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：未确定

MSDS

SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifiers Product name: Butane-d10 REACH No.: A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline. CAS-No.: 7582-04-9 Relevant identified uses of the substance or mixture and uses advised against Identified uses: Laboratory chemicals, Manufacture of substances SECTION 2: Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Flammable gases (Category 1), H220 Flammable gases (Category 1), H220 Gases under pressure (Liquefied gas), H280 Gases under pressure (Liquefied gas), H280 Germ cell mutagenicity (Category 1B), H340 Carcinogenicity (Category 1A), H350 For the full text of the H-Statements mentioned in this Section, see Section 16. Classification according to EU Directives 67/548/EEC or 1999/45/EC F+ Extremely flammableR12 F+ Extremely flammableR12 R45 R46 For the full text of the R-phrases mentioned in this Section, see Section 16. Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal wordDanger Hazard statement(s) H220Extremely flammable gas. H280Contains gas under pressure; may explode if heated. H340May cause genetic defects. H350May cause cancer. Precautionary statement(s) P201Obtain special instructions before use. P210Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P308 + P313IF exposed or concerned: Get medical advice/ attention. P410 + P403Protect from sunlight. Store in a well-ventilated place. Supplemental Hazardnone Statements Restricted to professional users. Other hazards - none SECTION 3: Composition/information on ingredients Substances Chemical characterization : Isotopically labeled Formula: C4D10 Molecular Weight: 68,18 g/mol CAS-No.: 7582-04-9 Hazardous ingredients according to Regulation (EC) No 1272/2008 ComponentClassificationConcentration Butane-d10 CAS-No.7582-04-9Flam. Gas 1; Press. Gas ;<= 100 % Muta. 1B; Carc. 1A; H220, H280, H340, H350 Hazardous ingredients according to Directive 1999/45/EC ComponentClassificationConcentration Butane-d10 CAS-No.7582-04-9F+, , T, Carc.Cat.1, Mut.Cat.2, <= 100 % R12R45 - R46 - R12 For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16 SECTION 4: First aid measures Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 Indication of any immediate medical attention and special treatment needed no data available SECTION 5: Firefighting measures Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Carbon oxides Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information Use water spray to cool unopened containers. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and materials for containment and cleaning up Clean up promptly by sweeping or vacuum. Reference to other sections For disposal see section 13. SECTION 7: Handling and storage Precautions for safe handling Avoid exposure - obtain special instructions before use.Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store under inert gas. hygroscopic Specific end use(s) A part from the uses mentioned in section 1.2 no other specific uses are stipulated SECTION 8: Exposure controls/personal protection Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties a) AppearanceForm: Liquefied gas b) Odourno data available c) Odour Thresholdno data available d) pHno data available e) Melting point/freezingMelting point/range: -138 °C - lit. point f) Initial boiling point and-0,5 °C - lit. boiling range g) Flash point-60 °C - closed cup h) Evapouration rateno data available i) Flammability (solid, gas) no data available j) Upper/lowerUpper explosion limit: 8,5 %(V) at 1013 hPa flammability orLower explosion limit: 1,5 %(V) at 1013 hPa explosive limits k) Vapour pressureno data available l) Vapour densityno data available m) Relative densityno data available n) Water solubilityno data available o) Partition coefficient: n- no data available octanol/water p) Auto-ignitionno data available temperature q) Decompositionno data available temperature r) Viscosityno data available s) Explosive propertiesno data available t) Oxidizing propertiesno data available Other safety information no data available SECTION 10: Stability and reactivity Reactivity no data available Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions no data available Conditions to avoid Heat, flames and sparks. Extremes of temperature and direct sunlight. Incompatible materials Strong oxidizing agents Hazardous decomposition products Other decomposition products - no data available In the event of fire: see section 5 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity no data available Skin corrosion/irritation no data available Serious eye damage/eye irritation Respiratory or skin sensitisation no data available Germ cell mutagenicity In vivo tests showed mutagenic effects Carcinogenicity Human carcinogen. IARC:No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Additional Information RTECS: Not available To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. SECTION 12: Ecological information Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted Other adverse effects no data available SECTION 13: Disposal considerations Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. SECTION 14: Transport information UN number ADR/RID: 1011IMDG: 1011IATA: 1011 UN proper shipping name ADR/RID: BUTANE IMDG: BUTANE IATA:Butane Passenger Aircraft: Not permitted for transport Transport hazard class(es) ADR/RID: 2.1IMDG: 2.1IATA: 2.1 Packaging group ADR/RID: -IMDG: -IATA: - Environmental hazards ADR/RID: noIMDG Marine pollutant: noIATA: no Special precautions for user no data available SECTION 15 - REGULATORY INFORMATION N/A SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 符号: GHS02, GHS04, GHS08
• 信号词: Danger
• 危害声明: H220-H280-H340-H350
• 警示性声明: P201-P210-P280-P308 + P313-P377-P403
• 危害码 (欧洲): F,Xi
• 风险声明 (欧洲): 11-43
• 安全声明 (欧洲): 16-33-36/37
• 危险品运输编码: UN 1011 2.1