| 中文名 | 3,6,9-三乙基-3,6,9-三甲基-1,4,7-三过氧壬烷 |
|---|---|
| 英文名 | 3,6,9-triethyl-3,6,9-trimethyl-1,2,4,5,7,8-hexaoxonane |
| 中文别名 | 3,6,9-三乙基-3,6,9-三甲基-1,4,7-三过氧化壬烷 |
| 英文别名 |
1,2,4,5,7,8-Hexoxonane,3,6,9-triethyl-3,6,9-trimethyl
3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxynonane MFCD02685709 3,6,9-triethyl-3,6,9-trimethyl-1,2,4,5,7,8-hexoxonane 3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane |
| 密度 | 0.875 |
|---|---|
| 沸点 | 246.6ºC at 760 mmHg |
| 熔点 | -20ºC |
| 分子式 | C12H24O6 |
| 分子量 | 264.31500 |
| 闪点 | 58ºC |
| 精确质量 | 264.15700 |
| PSA | 55.38000 |
| LogP | 3.22320 |
| 外观性状 | Solution | Clear |
| 蒸汽压 | 0.0422mmHg at 25°C |
| 折射率 | 1.392 |
| 储存条件 | 密闭于-20 ºC阴凉干燥环境中 |
| 稳定性 | 遵照规定使用和储存则不会分解。 |
| 分子结构 | 1、摩尔折射率：无可用 2、 摩尔体积（cm3/mol）：无可用 3、 等张比容（90.2K）：无可用 4、 表面张力（dyne/cm）：无可用 5、 极化率：无可用 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:3.4 2.氢键供体数量:0 3.氢键受体数量:6 4.可旋转化学键数量:3 5.互变异构体数量:无 6.拓扑分子极性表面积55.4 7.重原子数量:18 8.表面电荷:0 9.复杂度:213 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：无可用 2. 密度（g/mL,25/4℃）：0.875 3. 相对蒸汽密度（g/mL,空气=1）：无可用 4. 熔点（ºC）：-20 5. 沸点（ºC,常压）：无可用 6. 沸点（ºC,5.2kPa）：无可用 7. 折射率：无可用 8. 闪点（ºC）：58 9. 比旋光度（º）：无可用 10. 自燃点或引燃温度（ºC）：无可用 11. 蒸气压（kPa,25ºC）：无可用 12. 饱和蒸气压（kPa,60ºC）：无可用 13. 燃烧热（KJ/mol）：无可用 14. 临界温度（ºC）：无可用 15. 临界压力（KPa）：无可用 16. 油水（辛醇/水）分配系数的对数值：无可用 17. 爆炸上限（%,V/V）：无可用 18. 爆炸下限（%,V/V）：无可用 19. 溶解性：无可用 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 38 7 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to skin. May cause fire. Potential Health Effects Eye: May cause eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. Combustible liquid. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid mechanical shock and friction. Storage: Keep away from sources of ignition. Do not store near combustible materials. Store in a tightly closed container. Store in a dry area. Keep refrigerated. (Store below 4C/39F.) Keep away from reducing agents. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use explosion-proof ventilation equipment. Exposure Limits CAS# 24748-23-0: CAS# 64742-47-8: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Clear liquid Color: colorless Odor: mild odor pH: Not available. Vapor Pressure: < 0.1 kPa @ 20 deg Viscosity: 5 mPa.s 20 deg C Boiling Point: Not available. Freezing/Melting Point: -10 deg C Autoignition Temperature: Not available. Flash Point: 71 deg C ( 159.80 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Immiscible. Specific Gravity/Density: 0.875 Molecular Formula: C12H24O6 Molecular Weight: 264.32 Section 10 - STABILITY AND REACTIVITY Chemical Stability: A dangerous self-accelerating decomposition reaction and, under certain circumstances, explosion or fire can be caused by direct contact with incompatible substances or by thermal decomposition at and above the SADT (see Section 16). Conditions to Avoid: Incompatible materials, ignition sources, combustible materials. Incompatibilities with Other Materials: Reducing agents, acids, bases, rust, heavy metals. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, butane, acetone, methane. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 24748-23-0 unlisted. CAS# 64742-47-8: OA5504000 LD50/LC50: Not available. Not available. Carcinogenicity: 3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxynonane - Not listed by ACGIH, IARC, or NTP. Petroleum distillates - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Other No information available. Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI O Risk Phrases: R 38 Irritating to skin. R 7 May cause fire. Safety Phrases: S 3/7 Keep container tightly closed in a cool, well-ventilated place. S 14A Keep away from acids, reducing agents and polymerisation catalysts. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 24748-23-0: No information available. CAS# 64742-47-8: No information available. Canada CAS# 24748-23-0 is listed on Canada's NDSL List. CAS# 64742-47-8 is listed on Canada's DSL List. CAS# 24748-23-0 is not listed on Canada's Ingredient Disclosure List. CAS# 64742-47-8 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 24748-23-0 is listed on the TSCA inventory. CAS# 64742-47-8 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
|
生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。
|
| 危害码 (欧洲) | Xi,O |
|---|---|
| 风险声明 (欧洲) | R38;R43;R65;R7 |
| 安全声明 (欧洲) | S14-S26-S3/7-S36/37/39 |
| 海关编码 | 2909600000 |
| 海关编码 | 2909600000 |
|---|---|
| 中文概述 | 2909600000 过氧化醇、过氧化醚、过氧化酮及其卤化、磺化、硝化、亚硝化衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2909600000 alcohol peroxides, ether peroxides, ketone peroxides and their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0% |