63155-04-4

• 常用中文名：4-氯-5-甲基苯-1,2-二胺
• 常用英文名：4-Chloro-5-methyl-1,2-benzenediamine
• CAS号：63155-04-4
• 分子式：C₇H₉ClN₂
• 分子量：156.613
• 发布时间：2018-12-29 06:31:25
• 更新时间：2024-01-06 18:51:05

名称

• 中文名: 4-氯-5-甲基苯-1,2-二胺
• 英文名: 4-Chloro-5-methylbenzene-1,2-diamine
• 中文别名: 1,2-二氨基-4-氯-5-甲基苯
• 英文别名: 4-Chloro-5-methyl-1,2-benzenediamine; 1,2-Benzenediamine, 4-chloro-5-methyl-; 4-CHLORO-5-METHYLBENZENE-1,2-DIAMINE

物化性质

• 密度: 1.3±0.1 g/cm3
• 沸点: 307.0±37.0 °C at 760 mmHg
• 熔点: 137ºC
• 分子式: C₇H₉ClN₂
• 分子量: 156.613
• 闪点: 139.4±26.5 °C
• 精确质量: 156.045425
• PSA: 52.04000
• LogP: 1.62
• 外观性状: 黄色固体
• 蒸汽压: 0.0±0.7 mmHg at 25°C
• 折射率: 1.648
• 储存条件: 室温， 避光保存， 惰性气氛

MSDS

Name: 4-Chloro-5-methylbenzene-1 2-diamine 95+% Material Safety Data Sheet Synonym: CAS: 63155-04-4 Section 1 - Chemical Product MSDS Name:4-Chloro-5-methylbenzene-1 2-diamine 95+% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 63155-04-4 4-Chloro-5-methylbenzene-1,2-diamine 95+% unlisted Hazard Symbols: XN Risk Phrases: 20/21/22 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. Causes respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 63155-04-4: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: brown Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 138 - 140 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Not available. Solubility in water: Specific Gravity/Density: Molecular Formula: C7H9ClN2 Molecular Weight: 157 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents, acids, acid chlorides. Hazardous Decomposition Products: Hydrogen chloride, chlorine, nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 63155-04-4 unlisted. LD50/LC50: Not available. Carcinogenicity: 4-Chloro-5-methylbenzene-1,2-diamine - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.* Hazard Class: 6.1 UN Number: 2811 Packing Group: III IMO Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing Group: III RID/ADR Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 63155-04-4: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 63155-04-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 63155-04-4 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xn:Harmful;
• 风险声明 (欧洲): R20/21/22
• 安全声明 (欧洲): 26-36/37/39
• 海关编码: 2921590090

合成路线

7149-80-6 ~% 63155-04-4

文献：Journal of the American Chemical Society, , vol. 74, p. 1087

121-86-8 ~% 63155-04-4

文献：Journal of the Chemical Society, , vol. 117, p. 789

95-49-8 ~% 63155-04-4

文献：Journal of the Chemical Society, , vol. 117, p. 789

56136-79-9 ~% 63155-04-4

文献：Journal of the Chemical Society, , vol. 117, p. 789

7149-73-7 ~% 63155-04-4

文献：Journal of the Chemical Society, , vol. 117, p. 789

上下游产品

上游产品  5
7149-73-7 7149-80-6 121-86-8 95-49-8
56136-79-9
下游产品  6
149703-60-6 2255-94-9 149703-56-0 683240-81-5
81449-99-2 646504-79-2

海关

海关编码	2921590090
中文概述	2921590090. 其他芳香多胺及衍生物及它们的盐. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2921590090. other aromatic polyamines and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%