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| 中文名 | 2,4,6-三氯苯腈 |
|---|---|
| 英文名 | 2,4,6-Trichlorobenzonitrile |
| 中文别名 |
2,4,6-三氯苯甲腈
2,4,6-三氯氰苯 |
| 英文别名 |
Benzonitrile, 2,4,6-trichloro-
2,4,6-trichloro-benzonitrile MFCD00052711 2,4,6-Trichlorobenzonitrile 2.4.6-Trichlor-benzonitril 2,4,6-trichlorobenzenecarbonitrile |
| 密度 | 1.5±0.1 g/cm3 |
|---|---|
| 沸点 | 303.1±37.0 °C at 760 mmHg |
| 熔点 | 80-82°C |
| 分子式 | C7H2Cl3N |
| 分子量 | 206.456 |
| 闪点 | 136.4±20.7 °C |
| 精确质量 | 204.925278 |
| PSA | 23.79000 |
| LogP | 3.36 |
| 蒸汽压 | 0.0±0.6 mmHg at 25°C |
| 折射率 | 1.601 |
| 储存条件 | 室温 |
| 分子结构 | 1、摩尔折射率：45.8 2、摩尔体积（cm3/mol）：133.6 3、等张比容（90.2K）：364.4 4、表面张力（dyne/cm）：55.2 5、介电常数：无可用的 6、极化率（10-24cm3）：18.15 7、单一同位素质量：204.925282 Da 8、标称质量：205 Da 9、平均质量：206.4565 Da |
|
2,4,6-Trichlorobenzonitrile
SAFETY DATA SHEET Section1. IDENTIFICATION Product name:2,4,6-Trichlorobenzonitrile Section2. HAZARDS IDENTIFICATION GHS classification
PHYSICAL HAZARDSNot classified
HEALTH HAZARDS Acute toxicity (Oral)Category 4 Category 4 Acute toxicity (Dermal) Acute toxicity (Inhalation)Category 4 Category 2 Skin corrosion/irritation Serious eye damage/eye irritationCategory 2A Not classified ENVIRONMENTAL HAZARDS GHS label elements, including precautionary statements Pictograms or hazard symbols Signal wordWarning Harmful if swallowed, in contact with skin or if inhaled Hazard statements Causes skin irritation Causes serious eye irritation Precautionary statements: Avoid breathing dust/fume/gas/mist/vapours/spray. [Prevention] Use only outdoors or in a well-ventilated area. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Wear protective gloves and eye/face protection. [Response]IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Gently wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. 2,4,6-Trichlorobenzonitrile Section2. HAZARDS IDENTIFICATION [Disposal]Dispose of contents/container through a waste management company authorized by the local government. Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/mixture:Substance Components:2,4,6-Trichlorobenzonitrile >97.0%(GC) Percent: CAS Number:6575-05-9 Chemical Formula:C7H2Cl3N Section4. FIRST AID MEASURES Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact:Remove/Take off immediately all contaminated clothing. Gently wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Rinse cautiously with water for several minutes. Remove contact lenses, if present Eye contact: and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion:Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Protection of first-aiders:A rescuer should wear personal protective equipment, such as rubber gloves and air- tight goggles. Section5. FIRE-FIGHTING MEASURES Suitable extinguishingDry chemical, foam, water spray, carbon dioxide. media: Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to generate poisonous fume. from the chemical: Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Remove movable containers if safe to do so. Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment. equipment for firefighters: Section6. ACCIDENTAL RELEASE MEASURES Personal precautions,Use personal protective equipment. Keep people away from and upwind of spill/leak. protective equipment and Entry to non-involved personnel should be controlled around the leakage area by emergency procedures: roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it. containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with up: appropriate laws and regulations. Section7. HANDLING AND STORAGE Precautions for safe handling Handling is performed in a well ventilated place. Wear suitable protective equipment. Technical measures: Prevent dispersion of dust. Wash hands and face thoroughly after handling. Use a local exhaust if dust or aerosol will be generated. Advice on safe handling: Avoid contact with skin, eyes and clothing. Conditions for safe storage, including any incompatibilities Keep container tightly closed. Store in a cool and dark place. Storage conditions: Store locked up. Store away from incompatible materials such as oxidizing agents. Packaging material:Comply with laws. 2,4,6-Trichlorobenzonitrile Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls:Install a closed system or local exhaust as possible so that workers should not be exposed directly. Also install safety shower and eye bath. Personal protective equipment Respiratory protection: Dust respirator, self-contained breathing apparatus(SCBA), supplied air respirator, etc. Use respirators approved under appropriate government standards and follow local and national regulations. Hand protection:Impervious gloves. Safety goggles. A face-shield, if the situation requires. Eye protection: Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires. Section9. PHYSICAL AND CHEMICAL PROPERTIES Physical state (20°C):Solid Crystal- Powder Form: Colour:White - Slightly pale reddish yellow No data available Odour: pH: No data available Melting point/freezing point:79°C Boiling point/range:No data available Flash point:No data available Flammability or explosive limits: Lower:No data available Upper:No data available Relative density:No data available Solubility(ies): [Water]No data available [Other solvents] Soluble:Toluene Section10. STABILITY AND REACTIVITY Chemical stability:Stable under proper conditions. Possibility of hazardous No special reactivity has been reported. reactions: Incompatible materials: Oxidizing agents Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx), Hydrogen chloride products: Section11. TOXICOLOGICAL INFORMATION Acute Toxicity:No data available Skin corrosion/irritation: No data available Serious eyeNo data available damage/irritation: Germ cell mutagenicity: No data available Carcinogenicity: IARC =No data available NTP =No data available Reproductive toxicity:No data available Section12. ECOLOGICAL INFORMATION Ecotoxicity: Fish:No data available Crustacea:No data available No data available Algae: Persistence / degradability: No data available No data available Bioaccumulative potential(BCF): 2,4,6-Trichlorobenzonitrile Section12. ECOLOGICAL INFORMATION Mobility in soil No data available Log Pow: Soil adsorption (Koc):No data available No data available Henry's Law constant(PaM3/mol): Section13. DISPOSAL CONSIDERATIONS Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when disposing of the substance. Section14. TRANSPORT INFORMATION Does not correspond to the classification standard of the United Nations Hazards Class: UN-No:Not listed Section15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002 and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were prescribed. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危害码 (欧洲) | Xi |
|---|---|
| 风险声明 (欧洲) | R36/37/38 |
| 安全声明 (欧洲) | S26-S36/37/39 |
| 危险品运输编码 | 3276 |
| 包装等级 | III |
| 危险类别 | 6.1 |
| 海关编码 | 2926909090 |
|
~85%
6575-05-9 |
| 文献：ELI LILLY AND COMPANY Patent: WO2006/44454 A1, 2006 ; Location in patent: Page/Page column 73-74 ; WO 2006/044454 A1 |
|
~%
6575-05-9 |
| 文献：Journal of the American Chemical Society, , vol. 62, p. 1432,1434 |
|
~80%
6575-05-9 |
| 文献：Rezaei, Ramin; Karami, Marzeih Chinese Chemical Letters, 2011 , vol. 22, # 7 p. 815 - 818 |
|
~%
6575-05-9 |
| 文献：US4530797 A1, ; |
|
~%
6575-05-9 |
| 文献：Chemische Berichte, , vol. 27, p. 3151 |
|
~%
6575-05-9 |
| 文献：Chemische Berichte, , vol. 27, p. 3151 |
|
~%
6575-05-9 |
| 文献：Recueil des Travaux Chimiques des Pays-Bas, , vol. 21, p. 384 Journal of the Chemical Society, , vol. 71, p. 231 Chemische Berichte, , vol. 27, p. 3152 |
| 上游产品 7 | |
|---|---|
| 下游产品 7 | |
| 海关编码 | 2926909090 |
|---|---|
| 中文概述 | 2926909090 其他腈基化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |
