335-27-3

• 常用中文名：全氟-1,3-二甲基环己烷
• 常用英文名：PERFLUORO-1,3-DIMETHYLCYCLOHEXANE
• CAS号：335-27-3
• 分子式：C₈F₁₆
• 分子量：400.06000
• 相关类别： 有机原料 烃类化合物及其衍生物 烃类卤化物
• 发布时间：2018-02-08 08:00:00
• 更新时间：2024-01-02 18:54:55
• Perfluoro-1,3-dimethylcyclohexane is perfluorinated branched cyclohexane used as a synthesis reagent for amorphous fluorocarbon film preparation by plasma polymerization, and for hydroformylation of linear terminal alkenes. As a chemically inert compound similar in properties to other perfluorocarbons, perfluoro-1,3-dimethylcyclohexane is an ideal tracer for other fluorocarbons as it can be detected at very low concentrations.

名称

• 中文名: 全氟-1,3-二甲基环己烷
• 英文名: perfluoro-1,3-dimethylcyclohexane
• 中文别名: 全氟(1,3-二甲基环己胺)
• 英文别名: Perfluor-1,3-dimethylcyclohexan; EINECS 206-386-9; 1,1,2,2,3,3,4,5,5,6-decafluoro-4,6-bis-trifluoromethyl-cyclohexane; HEXADECAFLUORO-1,3-DIMETHYLCYCLOHEXANE; FLUTECR PP3; FLUTEC PP3; MFCD00001469; Decafluor-1,3-bis-trifluormethyl-cyclohexan; Cyclohexane,perfluoro-1,3-dimethyl; FLUTEC PP3102; decafluoro-1,3-bis-trifluoromethyl-cyclohexane

物化性质

• 密度: 1.85 g/mL at 20 °C(lit.)
• 沸点: 101-102 °C(lit.)
• 熔点: −55 °C(lit.)
• 分子式: C₈F₁₆
• 分子量: 400.06000
• 闪点: None
• 精确质量: 399.97400
• LogP: 5.08240
• 外观性状: 无色液体
• 蒸汽密度: 14 (vs air)
• 折射率: n20/D 1.3(lit.)
• 储存条件: 室温
• 分子结构:

  1、 摩尔折射率：39.01

  2、 摩尔体积（m³/mol）：227.5

  3、 等张比容（90.2K）：437.3

  4、 表面张力（dyne/cm）：13.6

  5、 极化率（10 ^-24cm ³）：15.46

• 计算化学:

  1.疏水参数计算参考值（XlogP）:5.4

  2.氢键供体数量:0

  3.氢键受体数量:16

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积0

  7.重原子数量:24

  8.表面电荷:0

  9.复杂度:479

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:2

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  一、物性数据

  性状：不可用

  密度（g/mL,25/4℃）：1.85

  相对蒸汽密度（g/mL,空气=1）：14

  熔点（ºC）：-55

  沸点（ºC,常压）：101-102

  沸点（ºC,5.2kPa）：不可用

  折射率：1.3

  闪点（ºC）：不可用

  比旋光度（º）：不可用

  自燃点或引燃温度（ºC）：不可用

  蒸气压（kPa,25ºC）：不可用

  饱和蒸气压（kPa,60ºC）：不可用

  燃烧热（KJ/mol）：不可用

  临界温度（ºC）：不可用

  临界压力（KPa）：不可用

  油水（辛醇/水）分配系数的对数值：不可用

  爆炸上限（%,V/V）：不可用

  爆炸下限（%,V/V）：不可用

  溶解性：不可用

MSDS

Name: Perfluoro-1 3-dimethylcyclohexane tech. 80% Material Safety Data Sheet Synonym: Hexadecafluoro-1,3-dimethylcyclohexane CAS: 335-27-3 Section 1 - Chemical Product MSDS Name:Perfluoro-1 3-dimethylcyclohexane tech. 80% Material Safety Data Sheet Synonym:Hexadecafluoro-1,3-dimethylcyclohexane Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 335-27-3 Perfluoro-1,3-dimethylcyclohexane 80 206-386-9 Hazard Symbols: XI Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Inhalation: Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Use extinguishing media appropriate to the surrounding fire. Substance is noncombustible. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated. Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 335-27-3: CAS# 7732-18-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: colorless Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 101 - 102 deg C Freezing/Melting Point: -55 deg C Autoignition Temperature: Not available. Flash Point: None Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 1.8280g/cm3 Molecular Formula: C8F16 Molecular Weight: 400.06 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Conditions to Avoid: Incompatible materials, excess heat. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen fluoride gas. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 335-27-3 unlisted. CAS# 7732-18-5: ZC0110000 LD50/LC50: Not available. CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg. Carcinogenicity: Perfluoro-1,3-dimethylcyclohexane - Not listed by ACGIH, IARC, or NTP. Water - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 28A After contact with skin, wash immediately with plenty of water. S 37 Wear suitable gloves. S 37/39 Wear suitable gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 335-27-3: No information available. CAS# 7732-18-5: No information available. Canada CAS# 335-27-3 is listed on Canada's NDSL List. CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 335-27-3 is not listed on Canada's Ingredient Disclosure List. CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 335-27-3 is listed on the TSCA inventory. CAS# 7732-18-5 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

毒理学数据: 二、毒理学数据： 急性毒性：不可用。 生态学数据: 三、生态学数据： 1、其它有害作用：该物质对环境可能有危害，对水体应给予特别注意。

安全

• 符号: GHS07
• 信号词: Warning
• 危害声明: H315-H319-H335
• 警示性声明: P261-P305 + P351 + P338
• 个人防护装备: Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
• 危害码 (欧洲): Xi:Irritant;
• 风险声明 (欧洲): R36/37/38
• 安全声明 (欧洲): S26-S36
• 危险品运输编码: NONH for all modes of transport
• WGK德国: 3
• RTECS号: GV4990000
• 海关编码: 2903890090

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海关

海关编码	2903890090
中文概述	2903890090. 其他环烷烃、环烯烃或环萜烯烃的卤化衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2903890090. halogenated derivatives of cyclanic, cyclenic or cyclotherpenic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%