18424-17-4

• 常用中文名：六氟锑酸锂
• 常用英文名：lithium hexafluoroantimonate
• CAS号：18424-17-4
• 分子式：F₆LiSb
• 分子量：242.69100
• 相关类别： 无机化工 无机盐 金属卤化物及卤酸盐 金属氟化物及盐
• 发布时间：2018-06-10 06:46:10
• 更新时间：2024-01-14 10:57:01

名称

• 中文名: 六氟代锑酸锂
• 英文名: lithium,hexafluoroantimony(1-)
• 中文别名: 六氟锑酸锂
• 英文别名: Lithium hexafluoroantimonate; MFCD00042319; hexafluorostibine,lithium salt; lithium hexafluorostiboranuide

物化性质

• 分子式: F₆LiSb
• 分子量: 242.69100
• 精确质量: 241.91000
• LogP: 2.52120
• 外观性状: 固体;White to Almost white powder to crystal
• 储存条件:

  常温密闭避光，通风干燥

• 稳定性:

  常温常压下稳定

  避免的物料：水分/潮湿 酸
• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:7

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积0

  7.重原子数量:8

  8.表面电荷:0

  9.复杂度:62.7

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:2

• 更多:

  1. 性状：粉状

  2. 密度（g/mL,25/4℃）：不确定

  3. 相对蒸汽密度（g/mL,空气=1）：不确定

  4. 熔点（ºC）：不确定

  5. 沸点（ºC,常压）：不确定

  6. 沸点（ºC, 5.2kPa）：不确定

  7. 折射率：不确定

  8. 闪点（ºC）：不确定

  9. 比旋光度（º）：不确定

  10. 自燃点或引燃温度（ºC）：不确定

  11. 蒸气压（kPa,25ºC）：不确定

  12. 饱和蒸气压（kPa,60ºC）：不确定

  13. 燃烧热（KJ/mol）：不确定

  14. 临界温度（ºC）：不确定

  15. 临界压力（KPa）：不确定

  16. 油水（辛醇/水）分配系数的对数值：不确定

  17. 爆炸上限（%,V/V）：不确定

  18. 爆炸下限（%,V/V）：不确定

  19. 溶解性：不确定

MSDS

Section 1: Product Identification Chemical Name:Lithium hexafluoroantimonate,min. 97% CAS Registry Number:18424-17-4 Formula:LiSbF6 EINECS Number:none Chemical Family:halometallate salts Synonym:Lithium antimony hexafluoride Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound18424-17-4100%0.5mg/m3 (as Sb)0.5mg/m3 (as Sb) Section 3: Hazards Identification Dust causes burns to skin and eyes, bleeding gums, laryngitis, headache, anemia, skin eruptions, liver and Emergency Overview: kidney damage. Fluoride poisoning may cause nausea, diarrhea, and weakness Primary Routes of Exposure:Contact with skin and eyes. Inhalation of dust. Eye Contact:Causes burns and serious eye damage. Effects may not immediately appear. Skin Contact:Corrosive. Effects may not appear immediately. Antimony may cause dermatitis and skin eruptions. Inhalation of dust causes burning to the respiratory tract, causing coughing, sore throat, and labored Inhalation: breathing. Ingestion:Ingestion may lead to nausea, vomiting, bloody diarrhea, weakness, and convulsions. Lithium salts are toxic. Burns to eyes and skin. Fluoride poisoning may cause nausea, vomiting and cardiovascular collapse. Lithium Acute Health Affects: salts are toxic to the central nervous system. Prolonged exposure to hydrolysable fluorine compounds can cause deterioration of bone and tooth structure. Chronic Health Affects:Antimony dust may cause bleeding gums, laryngitis, headache, anemia, skin eruptions, liver and kidney damage NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Apply calcium gluconate jelly Skin Exposure: or water soluble calcium salts as antidote. Seek medical assistance. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:None. Material is non-flammable. Special Fire Fighting Procedures:No special fire fighting procedures required. Hazardous Combustion andIf involved in a fire this material may emit corrosive fumes of hydrofluoric acid. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate and swept up. Avoid Spill and Leak Procedures:raising dust. Spillage in areas not adequately ventilated may require an evacuation of area. Emergency response teams will require self-contained breathing apparatus. SECTION 7: Handling and Storage Store solid in a tightly sealed container away from moisture. Handle under a dry atmosphere of air or nitrogen. Handling and Storage: Prolonged exposure to the atmosphere may degrade the product. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. Ventilation:The material must be handled in an efficient fume hood. If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators Respirator: requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:The material must be handled in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:white to off-white pwdr. Molecular Weight:242.68 Melting Point:no data Boiling Point:no data Vapor Pressure:not applicable Specific Gravity:no data Odor:none Solubility in Water:soluble SECTION 10: Stability and Reactivity Stability:hygroscopic Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:contact with moisture Incompatibility:active metals and strong mineral acids Decomposition Products:Hydrofluoric acid, metal fluorides and antimony oxyfluorides SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Corrosive solids, toxic, N.O.S. Hazard Class (CFR):8 Additional Hazard Class (CFR):6.1 Packaging Group (CFR):II UN ID Number (CFR):UN# 2923 Shipping Name (IATA):Corrosive Solid, Toxic, N.O.S. Hazard Class (IATA):8 Additional Hazard Class (IATA):6.1 Packaging Group (IATA):II UN ID Number (IATA):UN# 2923 SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound: See Category Code N010 for reporting. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 对水体是危害的，即使小量产品不能接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。

安全

• 危害码 (欧洲): Xi,T,N,Xn
• 风险声明 (欧洲): 20/22-51/53
• 安全声明 (欧洲): S61
• 危险品运输编码: 1549
• 包装等级: III
• 危险类别: 6.1