13146-23-1

• 常用中文名：苯基乙炔铜(I)
• 常用英文名：Copper(I)phenylacetylide
• CAS号：13146-23-1
• 分子式：C₈H₅Cu
• 分子量：164.67100
• 发布时间：2018-08-02 05:48:20
• 更新时间：2024-01-07 17:00:39

名称

• 中文名: 苯基乙酰基铜
• 英文名: copper (i) phenylacetylide
• 英文别名: Cu phenylacetylide; Copper(I) phenylacetylide; CUPROUS PHENYLACETYLIDE; copper phenylacetylenide; MFCD00015578; Copperphenylacetylide

物化性质

• 分子式: C₈H₅Cu
• 分子量: 164.67100
• 精确质量: 163.96900
• LogP: 1.54240
• 外观性状: 黄色固体
• 储存条件:

  常温密闭，阴凉通风干燥

• 稳定性:

  常温常压下稳定

  避免的物料 氧化物 水分/潮湿 空气 酸

• 分子结构:

  1、摩尔折射率：无可用的

  2、摩尔体积（cm³/mol）：无可用的

  3、等张比容（90.2K）：无可用的

  4、表面张力（dyne/cm）：无可用的

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：无可用的

  7、单一同位素质量：163.968726 Da

  8、标称质量：164 Da

  9、平均质量：164.6713 Da

• 计算化学:

  1、 疏水参数计算参考值（XlogP）：0.8

  2、 氢键供体数量：2

  3、 氢键受体数量：2

  4、 可旋转化学键数量：4

  5、 互变异构体数量：2

  6、 拓扑分子极性表面积（TPSA）：54.1

  7、 重原子数量：17

  8、 表面电荷：0

  9、 复杂度：270

  10、 同位素原子数量：0

  11、 确定原子立构中心数量： 0

  12、 不确定原子立构中心数量：0

  13、 确定化学键立构中心数量：0

  14、 不确定化学键立构中心数量：0

  15、 共价键单元数量：1

• 更多:

  1. 性状：黄色浅棕色粉末。

  2. 密度（g/mL, 25 ℃ ）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：未确定

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC，5mmHg）：未确定

  7. 折射率：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（20ºC）：未确定

  12. 饱和蒸气压（kPa,60ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：未确定

MSDS

Section 1: Product Identification Chemical Name:Copper (I) phenylacetylide, min. 97% CAS Registry Number:13146-23-1 Formula:C6H5CCCu EINECS Number:none Chemical Family:organometallic complex Synonym:1-phenyl-2-copper-ethyne Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound13146-23-1100%1mg/m3 (as Cu)1mg/m3 (as Cu) Section 3: Hazards Identification Emergency Overview:May be irritating to the skin, eyes and respiratory tract. Primary Routes of Exposure:Ingestion, inhalation Eye Contact:May cause slight to mild irritation of the eyes. Skin Contact:May cause slight to mild irritation of the skin. Inhalation:Inhalation of dust can lead to irritation of the respiratory tract. Ingestion:Ingestion of copper compounds may lead to vomiting, exhaustion, anemia, convulsions and coma. May be irritating to skin, eyes and respiratory tract. Ingestion of large amounts of copper compounds may lead Acute Health Affects: to vomiting, exhaustion, anemia, convulsions and coma. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self- contained breathing apparatus and full protective clothing. Hazardous Combustion andCombustible material. If involved in a fire this material may emit toxic and corrosive fumes. Decomposion Products: Unusual Fire or Explosion Hazards: Dust will form explosive mixtures with air SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Store material in a cool, dry place in a tightly sealed container under an inert atmosphere of nitrogen or argon. Handling and Storage: SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:yellow xtl. Molecular Weight:164.67 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:Insoluble SECTION 10: Stability and Reactivity Stability:air sensitive, moisture sensitive Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:Oxidizing agents and halogens Decomposition Products:copper oxide, carbon monoxide, carbon dioxide, and organic fumes. SECTION 11: Toxicological Information RTECS Data:No specific information available on this product. Carcinogenic Effects:No data Mutagenic Effects:No data Tetratogenic Effects:No data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound: See category N100 for reporting. Second Ingredient:None SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

毒理学数据: 主要的刺激性影响： 在皮肤上面：刺激皮肤和粘膜 在眼睛上面：刺激的影响 致敏作用：没有已知的敏化现象 生态学数据: 通常对水体是稍微有害的，不要将未稀释或大量产品接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。

安全

• 危害码 (欧洲): F+
• 风险声明 (欧洲): 20/21/22
• 安全声明 (欧洲): 22-36/37/39
• 危险品运输编码: UN3088
• 包装等级: II
• 危险类别: 4.2
• 海关编码: 2902909090

海关

海关编码	2902909090
中文概述	2902909090. 其他芳香烃. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:2.0%. 普通关税:30.0%
申报要素	品名, 成分含量
Summary	2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%