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| 中文名 | 1-丁基-3-甲基咪唑甲磺酸 |
|---|---|
| 英文名 | 1-butyl-3-methylimidazol-3-ium,methyl sulfate |
| 中文别名 |
1-正丁基-3-甲基咪唑硫酸甲酯
1-丁基-3-甲基咪唑硫酸甲酯 1-丁基-3-甲基咪唑硫酸甲脂盐 |
| 英文别名 |
MFCD03095437
1-butyl-3-methyl-3H-imidazolium methyl sulfate [Emim][MeSO4] [BMIM][MeSO4] [C4C1im][MeSO4] Basionics(R) LQ02 1-Butyl-3-methylimidazolium methyl sulfate [BMIM][MeOSO3] 1-n-Butyl-3-methylimidazolium methyl sulfate |
| 密度 | 1.21 |
|---|---|
| 熔点 | -4°C(lit.) |
| 分子式 | C9H18N2O4S |
| 分子量 | 250.31500 |
| 精确质量 | 250.09900 |
| PSA | 83.62000 |
| LogP | 1.28650 |
| 外观性状 | liquid | yellow |
| 折射率 | n20/D 1.478 |
| 储存条件 | 保存方法：密闭，阴凉，通风干燥处 |
| 稳定性 | 避氧化物、碱 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:4 4.可旋转化学键数量:3 5.互变异构体数量:无 6.拓扑分子极性表面积83.6 7.重原子数量:16 8.表面电荷:0 9.复杂度:184 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:2 |
| 更多 | 1. 性状：液体 2. 密度（g/mL20 ºC）：1.21 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC3mmHg）：未确定 7. 折射率：n20/D 1.478 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（kPa,）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：完全可拌和的 |
|
Section 1: Product Identification Chemical Name:1-Butyl-3-methylimidazolium methanesulfonate, 98% [BMIM] [MeSO4] CAS Registry Number:401788-98-5 Formula:C9H18N2O4S EINECS Number:none Chemical Family:organic amine salt Synonym:3-Butyl-1-methyl-3H-imidazol-1-ium; methylsulfate
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound401788-98-5100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to eyes, skin and respiratory tract. Primary Routes of Exposure:Ingestion, eyes, inhalation, skin contact Eye Contact:Causes moderate to severe irritation of the eyes. Skin Contact:Causes moderate to severe irritation of the skin Causes irritation of the respiratory tract with burning pain in the nose and throat, coughing, and pulmonary Inhalation: edema. Ingestion:May be harmful or poisonous if swallowed. Severe irritant to the gastrointestinal system The methylsulfate fragment may act as a poisonous alkylating agent in the human body as does dimethyl Acute Health Affects: sulfate. Irritating to skin, eyes and respiratory tract. Chronic Health Affects:No information available on the long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:none Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, dry powder or foam Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus Special Fire Fighting Procedures: and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a cool, dry place in a tightly sealed container. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. Ventilation:If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:yellow liquid Molecular Weight:250.32 Melting Point:no data Boiling Point:no data Vapor Pressure:not applicable Specific Gravity:no data Odor:none Solubility in Water:soluble SECTION 10: Stability and Reactivity Stability:hygroscopic Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:contact with air and moisture Incompatibility:strong oxidizing agents Decomposition Products:carbon dioxide, carbon monoxide, nitrogen oxides, and organic fumes. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to federal, state, and local regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 1、其它有害作用：通常对水是稍微危害的，若无政府许可，勿将材料排入周围环境。
|
| 符号 |
GHS05 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H314 |
| 警示性声明 | P280-P305 + P351 + P338-P310 |
| 个人防护装备 | Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| 危害码 (欧洲) | C |
| 风险声明 (欧洲) | R34 |
| 安全声明 (欧洲) | 26-36-45 |
| 危险品运输编码 | UN 3265 8/PG 2 |
| WGK德国 | 3 |
| 包装等级 | II |
| 海关编码 | 2933290090 |
|
~77%
401788-98-5 |
| 文献：Pereiro, Ana B.; Verdia, Pedro; Tojo, Emilia; Rodriguez, Ana Journal of Chemical and Engineering Data, 2007 , vol. 52, # 2 p. 377 - 380 |
|
~%
401788-98-5 |
| 文献：Solvent Innovation GmbH Patent: EP1182196 A1, 2002 ; Location in patent: Page 11 ; |
|
~%
401788-98-5 |
| 文献：Itoh, Toshiyuki; Ouchi, Nozomi; Hayase, Shuichi; Nishimura, Yoshihito Chemistry Letters, 2003 , vol. 32, # 7 p. 654 - 655 |
|
~98%
401788-98-5 |
| 文献：MERCK PATENT GMBH Patent: WO2006/63654 A1, 2006 ; Location in patent: Page/Page column 19-20 ; |
|
~97%
401788-98-5 |
| 文献：MERCK PATENT GMBH Patent: WO2006/63654 A1, 2006 ; Location in patent: Page/Page column 29 ; |
| 海关编码 | 2933290090 |
|---|---|
| 中文概述 | 2933290090. 其他结构含非稠合咪唑环的化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0% |
| 申报要素 | 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期 |
| Summary | 2933290090. other compounds containing an unfused imidazole ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |
