| 中文名 | 1,12-二氯十二烷 |
|---|---|
| 英文名 | 1,12-dichlorododecane |
| 英文别名 |
EINECS 223-492-0
Dodecane, 1,12-dichloro- 1,12-DICHLORODODECANE 1,12-dichloro-dodecane 1,6-dichlorododecane 1,12-Dichlor-dodecan DODECAMETHYLENE DICHLORIDE MFCD00039368 |
| 密度 | 1.0±0.1 g/cm3 |
|---|---|
| 沸点 | 306.2±10.0 °C at 760 mmHg |
| 熔点 | 28-30ºC(lit.) |
| 分子式 | C12H24Cl2 |
| 分子量 | 239.225 |
| 闪点 | 128.0±23.0 °C |
| 精确质量 | 238.125504 |
| LogP | 6.50 |
| 蒸汽压 | 0.0±0.6 mmHg at 25°C |
| 折射率 | 1.453 |
| 储存条件 | 密封储存，储存于阴凉、干燥的库房。禁止存放在金属容器内。 |
| 稳定性 | 常温常压下稳定，避免与不相容材料接触。 与强氧化剂反应。 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:6.1 2.氢键供体数量:0 3.氢键受体数量:0 4.可旋转化学键数量:11 5.互变异构体数量:无 6.拓扑分子极性表面积0 7.重原子数量:14 8.表面电荷:0 9.复杂度:82.3 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：块状有特殊气味的固体 2. 密度（g/mL,25℃）：0.95 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：28-30 5. 沸点（ºC,常压）：299 6. 沸点（ºC,10mmHg）：170-172 7. 折射率(n20/D)：未确定 8. 闪点（ºC）：168 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：210 11. 蒸气压（mPa,20ºC）：未确定 12. 饱和蒸气压（kPa,25ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
Synonym:None Known Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to skin.The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: Causes skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Dusts at sufficient concentrations can form explosive mixtures with air. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Use agent most appropriate to extinguish fire. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Do not store in metal containers. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 3922-28-9: Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Respirators: A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: after melting, clear colorless Odor: Characteristic. pH: Not available. Vapor Pressure: Not available. Viscosity: mPas 40 deg C Boiling Point: 299 deg C @ 760.00mm Hg Freezing/Melting Point: 29 deg C Autoignition Temperature: 210 deg C ( 410.00 deg F) Flash Point: 168 deg C ( 334.40 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: 0.03 G/L (20C) Specific Gravity/Density: .9530g/cm3 Molecular Formula: C12H24Cl2 Molecular Weight: 239.23 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, dust generation, excess heat. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 3922-28-9 unlisted. LD50/LC50: Not available. Carcinogenicity: 1,12-Dichlorododecane - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: Not regulated. Hazard Class: UN Number: Packing Group: IMO Shipping Name: Not regulated. Hazard Class: UN Number: Packing Group: RID/ADR Shipping Name: Not regulated. Hazard Class: UN Number: Packing group: Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 38 Irritating to skin. Safety Phrases: S 37 Wear suitable gloves. WGK (Water Danger/Protection) CAS# 3922-28-9: 2 Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 3922-28-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 3922-28-9 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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3922-28-9
详细
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| 文献：Turro, Nicholas J.; Han, Nianhe; Lei, Xue-Gong; Fehlner, James R.; Abrams, Lloyd Journal of the American Chemical Society, 1995 , vol. 117, # 17 p. 4881 - 4893 |
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| 文献：Turro, Nicholas J.; Han, Nianhe; Lei, Xue-Gong; Fehlner, James R.; Abrams, Lloyd Journal of the American Chemical Society, 1995 , vol. 117, # 17 p. 4881 - 4893 |
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| 文献：Saotome,K. et al. Bulletin of the Chemical Society of Japan, 1966 , vol. 39, p. 480 - 484 |
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| 文献：Violleau; Thiebaud; Borredon; Le Gars Synthetic Communications, 2001 , vol. 31, # 3 p. 367 - 373 |
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详细
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| 文献：Mubarak, Mohammad S.; Peters, Dennis G. Journal of Organic Chemistry, 1995 , vol. 60, # 3 p. 681 - 685 |
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详细
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| 文献：Mubarak, Mohammad S.; Peters, Dennis G. Journal of Organic Chemistry, 1995 , vol. 60, # 3 p. 681 - 685 |
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详细
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| 文献：Turro, Nicholas J.; Fehlner, James R.; Hessler, Diane P.; Welsh, Kevin M.; Ruderman, Warren; et al. Journal of Organic Chemistry, 1988 , vol. 53, # 16 p. 3731 - 3735 |
| 海关编码 | 2903199000 |
|---|---|
| 中文概述 | 2903199000 其他无环烃的饱和氯化衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2903199000 other saturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0% |
