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| 中文名 | 双环[2.2.1]-5-庚烯-2-甲酸叔丁酯 |
|---|---|
| 英文名 | tert-Butyl Bicyclo[2.2.1]-5-heptene-2-carboxylate |
| 中文别名 |
T-丁基-5-降冰片-2-羧酸盐
双环[2.2.1]庚-5-烯-2-羧酸叔丁酯 5-降冰片烯-2-羧酸叔丁酯 |
| 英文别名 |
Bicyclo[2.2.1]hept-5-ene-2-carboxylic Acid tert-Butyl Ester (endo- and exo- mixture)
MFCD08704200 tert-Butyl 5-Norbornene-2-carboxylate (endo- and exo- mixture) tert-butyl bicyclo[2.2.1]hept-5-ene-2-carboxylate 5-Norbornene-2-carboxylic Acid tert-Butyl Ester (endo- and exo- mixture) tert-Butyl Bicyclo[2.2.1]hept-5-ene-2-carboxylate (endo- and exo- mixture) 2-Methyl-2-propanyl bicyclo[2.2.1]hept-5-ene-2-carboxylate 5-Norbornene-2-carboxylic t-Butyl ester Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, 1,1-dimethylethyl ester t-Butyl-5-Norbornene-2-Carboxylate tert-butyl bicyclo[2.2.1]hept-2-ene-5-carboxylate |
| 密度 | 1.0±0.1 g/cm3 |
|---|---|
| 沸点 | 243.1±19.0 °C at 760 mmHg |
| 分子式 | C12H18O2 |
| 分子量 | 194.270 |
| 闪点 | 92.2±9.0 °C |
| 精确质量 | 194.130676 |
| PSA | 26.30000 |
| LogP | 2.96 |
| 外观性状 | 无色至淡黄色液体 |
| 蒸汽压 | 0.0±0.5 mmHg at 25°C |
| 折射率 | 1.502 |
| 储存条件 | 室温， 密封， 干燥 |
|
tert-Butyl 5-Norbornene-2-carboxylate (endo- and exo- Revision number: 5.3
mixture) SAFETY DATA SHEET Section1. IDENTIFICATION Product name:tert-Butyl 5-Norbornene-2-carboxylate (endo- and exo- mixture)
Revision number:5.3
Section2. HAZARDS IDENTIFICATION GHS classification PHYSICAL HAZARDS Category 4 Flammable liquids HEALTH HAZARDS Category 2 Skin corrosion/irritation Serious eye damage/eye irritationCategory 2A ENVIRONMENTAL HAZARDSNot classified GHS label elements, including precautionary statements Pictograms or hazard symbols Signal wordWarning Combustible liquid Hazard statements Causes skin irritation Causes serious eye irritation Precautionary statements: Keep away from flames and hot surfaces. [Prevention] Wash hands thoroughly after handling. Wear protective gloves and eye/face protection. [Response]IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Gently wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. [Storage]Store in a well-ventilated place. Keep cool. [Disposal]Dispose of contents/container through a waste management company authorized by the local government. Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/mixture:Substance tert-Butyl 5-Norbornene-2-carboxylate (endo- and exo- mixture) Components: Percent:>95.0%(GC) CAS Number:154970-45-3 and exo- mixture) Section3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms:5-Norbornene-2-carboxylic Acid tert-Butyl Ester (endo- and exo- mixture) , tert-Butyl Bicyclo[2.2.1]hept-5-ene-2-carboxylate (endo- and exo- mixture) , Bicyclo[2.2.1]hept- 5-ene-2-carboxylic Acid tert-Butyl Ester (endo- and exo- mixture) Chemical Formula:C12H18O2 Section4. FIRST AID MEASURES Remove victim to fresh air and keep at rest in a position comfortable for breathing. Inhalation: Get medical advice/attention if you feel unwell. Remove/Take off immediately all contaminated clothing. Gently wash with plenty of Skin contact: soap and water. If skin irritation or rash occurs: Get medical advice/attention. Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion:Get medical advice/attention if you feel unwell. Rinse mouth. Protection of first-aiders:A rescuer should wear personal protective equipment, such as rubber gloves and air- tight goggles. Section5. FIRE-FIGHTING MEASURES Suitable extinguishingDry chemical, foam, carbon dioxide. media: Unsuitable extinguishing Water (It may scatter and spread fire.) media: Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Remove movable containers if safe to do so. Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment. equipment for firefighters: Section6. ACCIDENTAL RELEASE MEASURES Use personal protective equipment. Keep people away from and upwind of spill/leak. Personal precautions, protective equipment and Ensure adequate ventilation. Entry to non-involved personnel should be controlled emergency procedures: around the leakage area by roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust). containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected up: material should be promptly disposed of, in accordance with appropriate laws and regulations. Prevention of secondary Remove all sources of ignition. Fire-extinguishing devices should be prepared in hazards:case of a fire. Use spark-proof tools and explosion-proof equipment. Section7. HANDLING AND STORAGE Precautions for safe handling Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment. Prevent generation of vapour or mist. Keep away from flames and hot surfaces. Take measures to prevent the build up of electrostatic charge. Use explosion-proof equipment. Wash hands and face thoroughly after handling. Use a closed system, ventilation. Advice on safe handling: Avoid contact with skin, eyes and clothing. Conditions for safe storage, including any incompatibilities Storage conditions:Keep container tightly closed. Store in a cool, dark and well-ventilated place. Store away from incompatible materials such as oxidizing agents. Comply with laws. Packaging material: and exo- mixture) Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls:Install a closed system or local exhaust as possible so that workers should not be exposed directly. Also install safety shower and eye bath. Personal protective equipment Respiratory protection: Vapor respirator. Follow local and national regulations. Hand protection:Protective gloves. Safety glasses. A face-shield, if the situation requires. Eye protection: Skin and body protection: Protective clothing. Protective boots, if the situation requires. Section9. PHYSICAL AND CHEMICAL PROPERTIES Physical state (20°C):Liquid Clear Form: Colour:Colorless - Very pale yellow No data available Odour: pH: No data available Melting point/freezing point:No data available Boiling point/range:103°C/1.3kPa Flash point:No data available Flammability or explosive limits: Lower:No data available Upper:No data available Relative density:0.98 Solubility(ies): [Water]No data available [Other solvents]No data available Section10. STABILITY AND REACTIVITY Chemical stability:Stable under proper conditions. Possibility of hazardous No special reactivity has been reported. reactions: Conditions to avoid:Open flame Incompatible materials: Oxidizing agents Hazardous decomposition Carbon monoxide, Carbon dioxide products: Section11. TOXICOLOGICAL INFORMATION Acute Toxicity:No data available Skin corrosion/irritation: No data available Serious eyeNo data available damage/irritation: Germ cell mutagenicity: No data available Carcinogenicity: IARC =No data available NTP =No data available Reproductive toxicity:No data available Section12. ECOLOGICAL INFORMATION Ecotoxicity: Fish:No data available Crustacea:No data available No data available Algae: Persistence / degradability: No data available No data available Bioaccumulative potential(BCF): Mobility in soil Log Pow:No data available and exo- mixture) Section12. ECOLOGICAL INFORMATION Soil adsorption (Koc): No data available Henry's LawNo data available constant(PaM3/mol): Section13. DISPOSAL CONSIDERATIONS Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when disposing of the substance. Section14. TRANSPORT INFORMATION Hazards Class:Does not correspond to the classification standard of the United Nations UN-No:Not listed Section15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002 and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were prescribed. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危害码 (欧洲) | Xi |
|---|---|
| 海关编码 | 2916209090 |
|
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154970-45-3 |
| 文献：Russian Journal of Applied Chemistry, , vol. 79, # 10 p. 1621 - 1625 |
|
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154970-45-3 |
| 文献：US6372935 B1, ; Page column 9 ; |
| 海关编码 | 2916209090 |
|---|---|
| 中文概述 | 2916209090 其他（环烷、环烯、环萜烯）一元羧酸（包括酸酐、酰卤化物，过氧化物和过氧酸及该税号的衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:AB(入境货物通关单,出境货物通关单) 最惠国关税:6.5% 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装 |
| 监管条件 | A.入境货物通关单 B.出境货物通关单 |
| 检验检疫 | R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验 |
| Summary | 2916209090 other cyclanic, cyclenic or cyclotherpenic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0% |
