3349-64-2

• 常用中文名：3,4-二氢-1(2H)-萘酮肟
• 常用英文名：3,4-Dihydronaphthalen-1(2H)-one oxime
• CAS号：3349-64-2
• 分子式：C₁₀H₁₁NO
• 分子量：161.200
• 发布时间：2018-06-21 09:01:27
• 更新时间：2024-01-02 01:06:13

名称

• 中文名: 四酮-1-肟
• 英文名: 1,2,3,4-tetrahydronaphthalen-1-one oxime
• 中文别名: 3,4-二氢-1(2H)-萘酮肟
• 英文别名: 1(2H)-Naphthalenone, 3,4-dihydro-, oxime; 3,4-dihydronaphthalen-1(2H)-one oxime; (E/Z)-3,4-dihydronaphthalen-1(2H)-one oxime; 3,4-dihydro-1(2H)-naphthalenone oxime; EINECS 222-106-8; Tetralone oxime; 1(2H)-Naphthalenone, 3,4-dihydro-, oxime, (1Z)-; 4-Dihydro-2H-naphthalen-1-one oxime; (1E)-3,4-dihydronaphthalen-1(2H)-one oxime; Tetralone-1-Oxime; (1E)-N-Hydroxy-3,4-dihydro-1(2H)-naphthalenimine; 1,2,3,4-Tetrahydronaphthalen-1-One Oxime; Tetralin-1-one oxime; BUTTPARK 954-12; 1(4H)-Naphthalenone, 2,3-dihydro, oxime; 3,4-DIHYDRO-2H-NAPHTHALEN-1-ONE OXIME; 1(2H)-Naphthalenone, 3,4-dihydro-, oxime, (1E)-; (1Z)-N-Hydroxy-3,4-dihydro-1(2H)-naphthalenimine; MFCD00029228; (1E)-N-hydroxy-3,4-dihydronaphthalen-1(2H)-imine; 1-Tetralone oxime

物化性质

• 密度: 1.2±0.1 g/cm3
• 沸点: 318.6±12.0 °C at 760 mmHg
• 熔点: 103ºC
• 分子式: C₁₀H₁₁NO
• 分子量: 161.200
• 闪点: 194.4±8.8 °C
• 精确质量: 161.084061
• PSA: 32.59000
• LogP: 2.28
• 蒸汽压: 0.0±0.7 mmHg at 25°C
• 折射率: 1.601
• 储存条件: 2-8°C

MSDS

Name: 1 2 3 4-Tetrahydronaphthalen-1-one oxime 97% Material Safety Data Sheet Synonym: CAS: 3349-64-2 Section 1 - Chemical Product MSDS Name:1 2 3 4-Tetrahydronaphthalen-1-one oxime 97% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 3349-64-2 1,2,3,4-Tetrahydronaphthalen-1-one oxi 97% 222-106-8 Hazard Symbols: None Listed. Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Not available. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 3349-64-2: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: off-white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 103 - 105 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C10H11NO Molecular Weight: 161 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Reducing agents, strong oxidizing agents, acid chlorides. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 3349-64-2 unlisted. LD50/LC50: Not available. Carcinogenicity: 1,2,3,4-Tetrahydronaphthalen-1-one oxime - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 3349-64-2: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 3349-64-2 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 3349-64-2 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi
• 风险声明 (欧洲): 36/37/38
• 安全声明 (欧洲): 26-36/37/39
• 海关编码: 2928000090

合成路线

529-34-0 ~97% 3349-64-2

文献：Tang, Wenjun; Capacci, Andrew; Sarvestani, Max; Wei, Xudong; Yee, Nathan K.; Senanayake, Chris H. Journal of Organic Chemistry, 2009 , vol. 74, # 24 p. 9528 - 9530

2217-40-5 ~66% 3349-64-2

文献：Suresh; Joseph; Jayachandran; Pol; Vinod; Sudalai; Sonawane; Ravindranathan Tetrahedron, 1995 , vol. 51, # 41 p. 11305 - 11318

447-53-0 ~66% 3349-64-2

文献：Okamoto, Tadashi; Kobayashi, Kenji; Oka, Shinzaburo; Tanimoto, Shigeo Journal of Organic Chemistry, 1988 , vol. 53, # 21 p. 4897 - 4901

119-64-2 ~% 3349-64-2

文献：Bulletin de la Societe Chimique de France, , p. 2001 - 2004

771-29-9 ~% 3349-64-2

文献：Chemische Berichte, , vol. 72, p. 1799,1804

上下游产品

上游产品  5
529-34-0 2217-40-5 447-53-0 119-64-2
771-29-9
下游产品  10
4424-80-0 22245-92-7 22246-45-3 529-34-0
24097-25-4 575-36-0 134-32-7 22246-79-3
6729-50-6 56182-28-6

海关

海关编码	2928000090
中文概述	2928000090 其他肼（联氨）及胲（羟胺）的有机衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%