152915-83-8

• 常用中文名：6-苄氧基萘-2-硼酸
• 常用英文名：Boronic acid,B-[6-(phenylmethoxy)-2-naphthalenyl]-
• CAS号：152915-83-8
• 分子式：C₁₇H₁₅BO₃
• 分子量：278.11000
• 发布时间：2018-04-04 08:00:00
• 更新时间：2024-01-12 09:40:30

名称

• 中文名: 6-(苄氧基)-2-萘硼酸
• 英文名: 6-Benzyloxy-2-naphthylboronic acid
• 英文别名: (6-phenylmethoxynaphthalen-2-yl)boronic acid

物化性质

• 密度: 1.24g/cm3
• 沸点: 510.4ºC at 760 mmHg
• 分子式: C₁₇H₁₅BO₃
• 分子量: 278.11000
• 闪点: 262.5ºC
• 精确质量: 278.11100
• PSA: 49.69000
• LogP: 2.09860
• 蒸汽压: 3.06E-11mmHg at 25°C
• 折射率: 1.655
• 储存条件: 2-8°C， 密封， 干燥

MSDS

Name: 6-(Benzyloxy)-2-naphthylboronic acid 97% Material Safety Data Sheet Synonym: CAS: 152915-83-8 Section 1 - Chemical Product MSDS Name:6-(Benzyloxy)-2-naphthylboronic acid 97% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 152915-83-8 6-(Benzyloxy)-2-naphthylboronic acid 97% unlisted Hazard Symbols: XI Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Keep refrigerated. (Store below 4C/39F.) Store in a tightly closed container. Store in a dry area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 152915-83-8: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C17H15BO3 Molecular Weight: 278.11 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, oxides of boron. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 152915-83-8 unlisted. LD50/LC50: Not available. Carcinogenicity: 6-(Benzyloxy)-2-naphthylboronic acid - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 152915-83-8: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 152915-83-8 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 152915-83-8 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi:Irritant;
• 风险声明 (欧洲): R36/37/38
• 安全声明 (欧洲): S26-S37/39
• 海关编码: 2931900090

合成路线

15231-91-1 ~% 152915-83-8

文献：Bioorganic and Medicinal Chemistry Letters, , vol. 16, # 21 p. 5639 - 5642

2234-45-9 ~% 152915-83-8

文献：Bioorganic and Medicinal Chemistry Letters, , vol. 16, # 21 p. 5639 - 5642

100-39-0 ~% 152915-83-8

文献：Bioorganic and Medicinal Chemistry Letters, , vol. 16, # 21 p. 5639 - 5642

上下游产品

上游产品  3
15231-91-1 2234-45-9 100-39-0
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海关

海关编码	2931900090
中文概述	2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%
Summary	2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%