- 上海化源世纪贸易有限公司
- 上海市 上海市 普陀区
- 产品名：(Z)-2-formamido-α-(methoxyimino)thiazol-4-aceticacid
- 纯度：97.0%
- 规格：
- 联系人：徐经理
- 联系电话：13311869306
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65872-43-7
65872-43-7结构式
- 常用中文名：(Z)-2-(2-甲酰氨基噻唑-4-基)-2-甲氧亚氨基乙酸
- 常用英文名：2-(2-Formamidothiazole-4-yl)-2-methoxyimino acetic acid
- CAS号：65872-43-7
- 分子式：C7H7N3O4S
- 分子量：229.213
- 发布时间：2018-12-31 12:59:09
- 更新时间：2024-01-09 12:22:44
| 中文名 | (Z)-[2-(甲酰氨基)噻唑-4-基](甲氧基亚氨基)乙酸 |
|---|---|
| 英文名 | 2-(2-Formamidothiazole-4-yl)-2-methoxyimino acetic acid |
| 中文别名 |
(Z)-2-(2-甲酰氨基噻唑-4-基)-2-甲氧亚氨基乙酸
(Z)-2-(甲酰氨基)-α-(甲氧亚氨基)-4-噻唑乙酸 |
| 英文别名 |
(2Z)-[2-(formylamino)-1,3-thiazol-4-yl](methoxyimino)ethanoic acid
EINECS 265-958-6 MFCD00010413 4-Thiazoleacetic acid, 2-(formylamino)-α-(methoxyimino)-, (αZ)- (2Z)-(2-Formamido-1,3-thiazol-4-yl)(methoxyimino)acetic acid N-Formyloxamidine Acid 2-(2-Formamidothiazole-4-yl)-2-methoxyimino acetic acid |
| 密度 | 1.6±0.1 g/cm3 |
|---|---|
| 沸点 | 438.5±55.0 °C at 760 mmHg |
| 熔点 | 163 °C (dec.)(lit.) |
| 分子式 | C7H7N3O4S |
| 分子量 | 229.213 |
| 闪点 | 219.0±31.5 °C |
| 精确质量 | 229.015732 |
| PSA | 129.12000 |
| LogP | 0.05 |
| 外观性状 | 灰白色固体 |
| 蒸汽压 | 0.0±1.1 mmHg at 25°C |
| 折射率 | 1.664 |
| 储存条件 | 密闭于2-8 ºC阴凉干燥环境中 |
| 稳定性 | 遵照规定使用和储存则不会分解。 |
| 分子结构 | 1、 疏水参数计算参考值（XlogP）：0.8 2、 氢键供体数量：2 3、 氢键受体数量：6 4、 可旋转化学键数量：4 5、 拓扑分子极性表面积（TPSA）：101 6、 重原子数量：15 7、 表面电荷：0 8、 复杂度：283 9、 同位素原子数量：0 10、 确定原子立构中心数量：0 11、 不确定原子立构中心数量：0 12、 确定化学键立构中心数量：1 13、 不确定化学键立构中心数量：0 14、 共价键单元数量：1 |
| 计算化学 | 五、分子性质数据： 1、 摩尔折射率：52.98 2、 摩尔体积（m3/mol）：142.9 3、 等张比容（90.2K）：407.2 4、 表面张力（dyne/cm）：65.9 5、 极化率：21.00 6、 介电常数：未确定 |
| 更多 | 1. 性状：米黄色粉末 2. 密度（g/mL,25/4℃）：无可用 3. 相对蒸汽密度（g/mL,空气=1）：无可用 4. 熔点（ºC）：163 5. 沸点（ºC,常压）：无可用 6. 沸点（ºC,5.2kPa）：无可用 7. 折射率：无可用 8. 闪点（ºC）：无可用 9. 比旋光度（º）：无可用 10. 自燃点或引燃温度（ºC）：无可用 11. 蒸气压（kPa,25ºC）：无可用 12. 饱和蒸气压（kPa,60ºC）：无可用 13. 燃烧热（KJ/mol）：无可用 14. 临界温度（ºC）：无可用 15. 临界压力（KPa）：无可用 16. 油水（辛醇/水）分配系数的对数值：无可用 17. 爆炸上限（%,V/V）：无可用 18. 爆炸下限（%,V/V）：无可用 19. 溶解性：无可用 |
Synonym: SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Hazard Symbols: XI SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated.Moisture sensitive. Potential Health Effects Eye: Causes eye irritation. Skin:
Causes skin irritation. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Inhalation: Causes respiratory tract irritation. Chronic: No information found. SECTION 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: SECTION 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. SECTION 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. SECTION 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Limits CAS# 65872-43-7: Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear a chemical apron. Respirators: A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: off-white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 165 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C7H7N3O4S Molecular Weight: 229.18 SECTION 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Has not been reported SECTION 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 65872-43-7 unlisted. LD50/LC50: Not available. Carcinogenicity: 2-(2-formamidothiazole-4-yl)-2-methoxyimino acetic acid, 95% - Not listed by ACGIH, IARC, or NTP. SECTION 12 - ECOLOGICAL INFORMATION SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. SECTION 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. SECTION 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 65872-43-7: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 65872-43-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 65872-43-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages. SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。
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| 符号 |
GHS07 |
|---|---|
| 信号词 | Warning |
| 危害声明 | H315-H319-H335 |
| 警示性声明 | P261-P305 + P351 + P338 |
| 个人防护装备 | dust mask type N95 (US);Eyeshields;Gloves |
| 危害码 (欧洲) | Xi: Irritant; |
| 风险声明 (欧洲) | R36/37/38 |
| 安全声明 (欧洲) | S26-S36 |
| 危险品运输编码 | NONH for all modes of transport |
| WGK德国 | 3 |
| 海关编码 | 2934100090 |
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65872-43-7 |
| 文献：US4288436 A1, ; |
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65872-43-7 |
| 文献：Perrone; Alpegiani; Giudici; et al. Journal of Heterocyclic Chemistry, 1984 , vol. 21, # 4 p. 1097 - 1111 |
| 上游产品 2 | |
|---|---|
| 下游产品 0 | |
| 海关编码 | 2934100090 |
|---|---|
| 中文概述 | 2934100090. 结构上含有一个非稠合噻唑环的化合物(不论是否氢化). 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2934100090 other compounds containing an unfused thiazole ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0% |