22575-75-3

• 常用中文名：3-(2-氧代环十二烷基)丙酸
• 常用英文名：3-(2-oxocyclododecyl)propanoic acid
• CAS号：22575-75-3
• 分子式：C₁₅H₂₆O₃
• 分子量：254.36500
• 发布时间：2018-09-28 12:05:26
• 更新时间：2024-01-02 19:15:49

名称

• 中文名: 3-(2-氧代环十二烷基)丙酸
• 英文名: 3-(2-oxocyclododecyl)propanoic acid
• 英文别名: HMS547O19; Cyclododecanepropanoicacid,2-oxo

物化性质

• 密度: 0.985g/cm3
• 沸点: 421.8ºC at 760mmHg
• 熔点: 88ºC
• 分子式: C₁₅H₂₆O₃
• 分子量: 254.36500
• 闪点: 223ºC
• 精确质量: 254.18800
• PSA: 54.37000
• LogP: 3.95110
• 蒸汽压: 2.7E-08mmHg at 25°C
• 折射率: 1.462

MSDS

Name: 3-(2-Oxocyclododecyl)propanoic acid 97% Material Safety Data Sheet Synonym: CAS: 22575-75-3 Section 1 - Chemical Product MSDS Name:3-(2-Oxocyclododecyl)propanoic acid 97% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 22575-75-3 3-(2-Oxocyclododecyl)propanoic acid 97% unlisted Hazard Symbols: XI Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 22575-75-3: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white - off-white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 88 - 90 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C15H26O3 Molecular Weight: 254 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 22575-75-3 unlisted. LD50/LC50: Not available. Carcinogenicity: 3-(2-Oxocyclododecyl)propanoic acid - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 22575-75-3: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 22575-75-3 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 22575-75-3 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi:Irritant;
• 风险声明 (欧洲): R36/37/38
• 安全声明 (欧洲): S26-S37/39
• 海关编码: 2918300090

合成路线

57-57-8 4017-60-1 ~% 22575-75-3

文献：Daicel, Ltd. Patent: US4005107 A1, 1977 ;

57-57-8 4017-60-1 830-13-7 ~% 22575-75-3

文献：Daicel Ltd. Patent: US4085274 A1, 1978 ;

539-74-2 830-13-7 ~50% 22575-75-3

文献：Zakharkin, L. I.; Antonova, G. N.; Podvisotskaya, L. S. Russian Chemical Bulletin, 1995 , vol. 44, # 12 p. 2418 - 2419 Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1995 , # 12 p. 2521 - 2523

4936-20-3 ~% 22575-75-3

文献：Biemann et al. Journal of the American Chemical Society, 1957 , vol. 79, p. 5558,5562

62940-04-9 ~90% 22575-75-3

文献：Zakharkin, L. I.; Churilova, I. M. Journal of Organic Chemistry USSR (English Translation), 1987 , vol. 23, # 10 p. 1895 - 1899 Zhurnal Organicheskoi Khimii, 1987 , vol. 23, # 10 p. 2146 - 2150

830-13-7 ~% 22575-75-3

文献：Zakharkin, L. I.; Churilova, I. M. Journal of Organic Chemistry USSR (English Translation), 1987 , vol. 23, # 10 p. 1895 - 1899 Zhurnal Organicheskoi Khimii, 1987 , vol. 23, # 10 p. 2146 - 2150

40050-37-1 ~% 22575-75-3

文献：Bailey; Gilpin; Jones Journal of the Chemical Society. Perkin transactions 1, 1977 , # 3 p. 265 - 270

上下游产品

上游产品  6
57-57-8 4017-60-1 830-13-7 539-74-2
62940-04-9 40050-37-1
下游产品  0

海关

海关编码	2918300090
中文概述	2918300090 其他含醛基或酮基不含其他含氧基羧酸（包括酸酐、酰卤化物、过氧化物和过氧酸及该税号的衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%