34624-38-9

• 常用中文名：2-(3-甲氧基苯基)乙酰肼
• 常用英文名：2-(3-Methoxyphenyl)acetohydrazide
• CAS号：34624-38-9
• 分子式：C₉H₁₂N₂O₂
• 分子量：180.20400
• 发布时间：2018-05-14 08:00:00
• 更新时间：2024-02-05 13:26:21

名称

• 中文名: 2-(3-甲氧基苯基)乙肼
• 英文名: 2-(3-Methoxyphenyl)acetohydrazide
• 英文别名: 2-(3-methoxyphenyl)acetohydrazide; 2-(3-Methoxyphenyl)ethanohydrazide

物化性质

• 密度: 1.156g/cm3
• 沸点: 402.6ºC at 760mmHg
• 熔点: 89ºC
• 分子式: C₉H₁₂N₂O₂
• 分子量: 180.20400
• 闪点: 197.3ºC
• 精确质量: 180.09000
• PSA: 64.35000
• LogP: 1.31880
• 折射率: 1.549
• 储存条件: 2-8°C，避光保存，惰性气氛

MSDS

Name: 2-(3-Methoxyphenyl)ethanohydrazide 97% Material Safety Data Sheet Synonym: 3-Methoxyphenylacetic acid hydrazid CAS: 34624-38-9 Section 1 - Chemical Product MSDS Name:2-(3-Methoxyphenyl)ethanohydrazide 97% Material Safety Data Sheet Synonym:3-Methoxyphenylacetic acid hydrazid Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 34624-38-9 2-(3-Methoxyphenyl)ethanohydrazide 97% unlisted Hazard Symbols: XI Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 34624-38-9: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 45 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C9H12N2O2 Molecular Weight: 180 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Not available. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 34624-38-9 unlisted. LD50/LC50: Not available. Carcinogenicity: 2-(3-Methoxyphenyl)ethanohydrazide - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 34624-38-9: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 34624-38-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 34624-38-9 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi: Irritant;
• 风险声明 (欧洲): R20/21/22
• 安全声明 (欧洲): 26-36/37/39
• 海关编码: 2928000090

合成路线

18927-05-4 ~88% 34624-38-9

文献：Prata, Jose V.; Clemente, Dina-Telma S.; Prabhakar, Sundaresan; Lobo, Ana M.; Mourato, Isabel; Branco, Paula S. Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 4 p. 513 - 528

1798-09-0 ~% 34624-38-9

文献：Journal of the Brazilian Chemical Society, , vol. 23, # 5 p. 854 - 860

上下游产品

上游产品  2
18927-05-4 1798-09-0
下游产品  0

海关

海关编码	2928000090
中文概述	2928000090 其他肼（联氨）及胲（羟胺）的有机衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%