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| 中文名 | 乙烯基-d3溴化物,在THF(1M)中的溶液 |
|---|---|
| 英文名 | vinyl-d3 bromide |
| 英文别名 |
Brom-trichlor-aethen
bromotrichloroethylene Trichlorbromethylen 1-Brom-1.2.2-trideutero-aethylen 1-Brom-aethylen-1.2.2-d3 Brom-trideuterio-aethen Vinyl bromide-d3 bromo-trichloro-ethene Brom-trideuterio-aethylen trichlorovinyl bromide Brom-trichlor-aethylen Trideuterovinylbromid bromo-trideuterio-ethene Ethene,bromotrichloro |
| 密度 | 1.56 g/mL at 25ºC(lit.) |
|---|---|
| 沸点 | 16ºC/750 mmHg(lit.) |
| 熔点 | -139ºC(lit.) |
| 分子式 | C2BrD3 |
| 分子量 | 109.96800 |
| 精确质量 | 108.96100 |
| LogP | 1.52480 |
| 折射率 | n20/D 1.435(lit.) |
|
Section1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE Product identifiers Product name: Vinyl-d3 bromide CAS-No.: 4666-78-8 Relevant identified uses of the substance or mixture and uses advised against Identified uses: Laboratory chemicals, Manufacture of substances Section2. HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Flammable gases (Category 1) Gases under pressure (Liquefied gas) Carcinogenicity (Category 1B) Classification according to EU Directives 67/548/EEC or 1999/45/EC May cause cancer. Extremely flammable. Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal wordDanger Hazard statement(s) H220Extremely flammable gas. H280Contains gas under pressure; may explode if heated. H350May cause cancer. Precautionary statement(s) P201Obtain special instructions before use. P210Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P308 + P313IF exposed or concerned: Get medical advice/ attention. P410 + P403Protect from sunlight. Store in a well-ventilated place. Supplemental Hazardnone Statements Restricted to professional users. According to European Directive 67/548/EEC as amended. Hazard symbol(s) R-phrase(s) R45May cause cancer. R12Extremely flammable. S-phrase(s) S53Avoid exposure - obtain special instructions before use. S45In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Restricted to professional users. Other hazards - none Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substances Formula: C2D3Br Molecular Weight: 109,97 g/mol ComponentConcentration Vinyl-d3 bromide CAS-No.4666-78-8- Section4. FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Indication of any immediate medical attention and special treatment needed no data available Section5. FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Carbon oxides, Hydrogen bromide gas Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information Use water spray to cool unopened containers. Section6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and materials for containment and cleaning up Clean up promptly by sweeping or vacuum. Reference to other sections For disposal see section 13. Section7. HANDLING AND STORAGE Precautions for safe handling Avoid exposure - obtain special instructions before use.Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store under inert gas. hygroscopic Contents under pressure. hygroscopic Specific end uses no data available Section8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Section9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) AppearanceForm: Liquefied gas b) Odourno data available c) Odour Thresholdno data available d) pHno data available e) Melting point/freezingMelting point/range: -139 °C - lit. point f) Initial boiling point and 16 °C at 1.000 hPa - lit.16 °C at 1.000 hPa - lit. boiling range g) Flash pointno data available h) Evaporation rateno data available i) Flammability (solid, gas) no data available j) Upper/lowerUpper explosion limit: 13,5 %(V) at 1013 hPa flammability orLower explosion limit: 5,6 %(V) at 1013 hPa explosive limits k) Vapour pressureno data available l) Vapour densityno data available m) Relative density1,56 g/mL at 25 °C1,56 g/cm3 at 25 °C n) Water solubilityno data available o) Partition coefficient: n- no data available octanol/water p) Autoignitionno data available temperature q) Decompositionno data available temperature r) Viscosityno data available s) Explosive propertiesno data available t) Oxidizing propertiesno data available Other safety information no data available Section10. STABILITY AND REACTIVITY Reactivity no data available Chemical stability no data available Possibility of hazardous reactions no data available Conditions to avoid Heat, flames and sparks. Extremes of temperature and direct sunlight. Incompatible materials Bases, Oxidizing agents Hazardous decomposition products Other decomposition products - no data available Section11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity no data available Skin corrosion/irritation no data available Serious eye damage/eye irritation Respiratory or skin sensitization no data available Germ cell mutagenicity Carcinogenicity Possible human carcinogen IARC:2A - Group 2A: Probably carcinogenic to humans (Vinyl-d3 bromide) Reproductive toxicity Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects InhalationMay be harmful if inhaled. May cause respiratory tract irritation. IngestionMay be harmful if swallowed. SkinMay be harmful if absorbed through skin. May cause skin irritation. EyesMay cause eye irritation. Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Additional Information RTECS: Not available Section12. ECOLOGICAL INFORMATION Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment no data available Other adverse effects no data available Section13. DISPOSAL CONSIDERATIONS Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. Section14. TRANSPORT INFORMATION UN number ADR/RID: 1085IMDG: 1085IATA: 1085 UN proper shipping name ADR/RID: VINYL BROMIDE, STABILIZED IMDG: VINYL BROMIDE, STABILIZED IATA:Vinyl bromide, stabilized Passenger Aircraft: Not permitted for transport Transport hazard class(es) ADR/RID: 2.1IMDG: 2.1IATA: 2.1 Packaging group ADR/RID: -IMDG: -IATA: - Environmental hazards ADR/RID: noIMDG Marine pollutant: noIATA: no Special precautions for user no data available Section15. REGULATORY INFORMATION This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. Safety, health and environmental regulations/legislation specific for the substance or mixture no data available Chemical Safety Assessment no data available Section16. OTHER INFORMATION Further information Copyright 2012 Co. LLC. License granted to make unlimited paper copies for internal use only. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Corporation and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. See and/or the reverse side of invoice or packing slip for additional terms and conditions of sale. |
| 符号 |
GHS02, GHS08 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H220-H280-H350 |
| 警示性声明 | P201-P210-P308 + P313-P410 + P403 |
| 危害码 (欧洲) | F+: Highly flammable;T: Toxic; |
| 风险声明 (欧洲) | 45-12 |
| 安全声明 (欧洲) | 53-45 |
| 危险品运输编码 | UN 1085 2.1 |
|
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4666-78-8 |
| 文献：Jungers; Verhulst Mem.Acad.Belg.8gradChem.Abstr., 1949 , vol. 23, # 2 p. 36,37 Mem.Acad.Belg.8gradChem.Abstr., 1951 , p. 4638 |
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