中文名 | 9-(环氧-2-甲基)-9H-咔唑 |
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英文名 | 9-(oxiran-2-ylmethyl)carbazole |
英文别名 |
[(carbazol-9-yl)methyl]oxirane
2-(9-carbazolyl)methyloxirane 9-(2-oxiranylmethyl)carbazole 9-(2,3-epoxypropyl)-9H-carbazole 9-(oxiran-2-ylmethyl)-9H-carbazole N-(2,3-Epoxypropyl)-carbazole 9-(2,3-epoxypropyl)carbazole BB_SC-0614 2-(carbazol-9-ylmethyl)oxirane |
密度 | 1.25g/cm3 |
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沸点 | 409.7ºC at 760 mmHg |
熔点 | 110ºC |
分子式 | C15H13NO |
分子量 | 223.27000 |
闪点 | 201.6ºC |
精确质量 | 223.10000 |
PSA | 17.46000 |
LogP | 3.19330 |
折射率 | 1.677 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/21/22 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. Causes respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 52131-82-5: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 110 - 112 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C15H13NO Molecular Weight: 223 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide, ammonia. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 52131-82-5 unlisted. LD50/LC50: Not available. Carcinogenicity: 9-(Oxiran-2-ylmethyl)-9H-carbazole - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.* Hazard Class: 6.1 UN Number: 2811 Packing Group: III IMO Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing Group: III RID/ADR Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 52131-82-5: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 52131-82-5 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 52131-82-5 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
风险声明 (欧洲) | 36/37/38 |
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安全声明 (欧洲) | 26-36/37/39 |
海关编码 | 2933990090 |
~90% 52131-82-5 |
文献:Bogdal; Lukasiewicz; Pielichowski; Bednarz Synthetic Communications, 2005 , vol. 35, # 23 p. 2973 - 2983 |
~69% 52131-82-5 |
文献:Bersot, Ross; Humphries, Paul Patent: US2013/303524 A1, 2013 ; Location in patent: Paragraph 0254-0255 ; |
~14% 52131-82-5 |
文献:Bogdal; Lukasiewicz; Pielichowski; Bednarz Synthetic Communications, 2005 , vol. 35, # 23 p. 2973 - 2983 |
~% 52131-82-5 |
文献:Lubczak, Renata Heterocyclic Communications, 2006 , vol. 12, # 3-4 p. 201 - 208 |
~% 52131-82-5 |
文献:Esrielew; Larin Zhurnal Obshchei Khimii, 1956 , vol. 26, p. 791 engl. Ausg. S. 905 |
上游产品 6 | |
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下游产品 5 | |
海关编码 | 2933990090 |
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中文概述 | 2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0% |
申报要素 | 品名, 成分含量, 用途, 乌洛托品请注明外观, 6-己内酰胺请注明外观, 签约日期 |
Summary | 2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |