614-72-2

• 常用中文名：2-氯苯乙醚
• 常用英文名：(2-Chloroethoxy)benzene
• CAS号：614-72-2
• 分子式：C₈H₉ClO
• 分子量：156.609
• 发布时间：2018-05-03 08:00:00
• 更新时间：2024-01-01 22:48:56

名称

• 中文名: 鄰氯苯基乙基醚
• 英文名: 2-Chlorophenetole
• 中文别名: 2-氯苯乙醚; 邻氯苯乙醚; 邻氯苯基乙基醚; 邻氯乙氧基苯
• 英文别名: 1-Chloro-2-ethoxybenzene; MFCD00058930; 2-Chlorophenyl ethyl ether; (2-Chloroethoxy)benzene; Benzene, (2-chloroethoxy)-; Benzene, 1-chloro-2-ethoxy-; EINECS 210-392-7; 2-phenoxyethyl chloride; 2-chloroethyl phenyl ether

物化性质

• 密度: 1.1±0.1 g/cm3
• 沸点: 210.0±0.0 °C at 760 mmHg
• 分子式: C₈H₉ClO
• 分子量: 156.609
• 闪点: 82.3±13.9 °C
• 精确质量: 156.034195
• PSA: 9.23000
• LogP: 3.21
• 蒸汽压: 0.3±0.4 mmHg at 25°C
• 折射率: 1.510
• 储存条件:

  贮存：

  将密器密封，储存密封的主藏器内，并放在阴凉， 干爽的位置。

• 稳定性:

  性质与稳定性：

  常温常压下，或不分解产物。

• 分子结构:

  五、分子性质数据：

  1、 摩尔折射率：42.45

  2、 摩尔体积（m³/mol）：141.8

  3、 等张比容（90.2K）：339.5

  4、 表面张力（dyne/cm）：32.8

  5、 极化率（10 ^-24cm ³）：16.83

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:1

  4.可旋转化学键数量:2

  5.互变异构体数量:无

  6.拓扑分子极性表面积9.2

  7.重原子数量:10

  8.表面电荷:0

  9.复杂度:95.3

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

MSDS

2-Chlorophenetole Revision number: 1 SAFETY DATA SHEET Section1. BASE INFORMATION Product name:2-Chlorophenetole Revision number:1 Section2. HAZARDS IDENTIFICATION Classification of the GHS PHYSICAL HAZARDS Flammable liquidsCategory 4 Not classified HEALTH HAZARDS ENVIRONMENTAL HAZARDSNot classified GHS label elements Pictograms or hazard symbolsNone Warning Signal word Hazard statementCombustible liquid Precautionary statements [Prevention]Keep away from flames and hot surfaces. Wear protective gloves and eye/face protection. [Storage]Store in a well-ventilated place. Keep cool. Dispose of contents/container through a waste management company authorized by [Disposal] the local government Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/mixture:Substance Component(s):2-Chlorophenetole Percent:>99.0%(GC) 614-72-2 CAS Number: Synonyms:1-Chloro-2-ethoxybenzene Chemical Formula:C8H9ClO Section4. FIRST AID MEASURES Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. Skin contact:Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation or rash occurs: Get medical advice/attention. Rinse cautiously with water for several minutes. Remove contact lenses, if present Eye contact: and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion:Get medical advice/attention if you feel unwell. Rinse mouth. Protection of first-aiders:A rescuer should wear personal protective equipment, such as rubber gloves and air- tight goggles. 2-Chlorophenetole Section5. FIRE-FIGHTING MEASURES Suitable extinguishingDry chemical, foam, water spray, carbon dioxide. media: Extinguishing media not to Solid streams of water be used: Specific hazards:Take care as it may decompose upon combustion or in high temperatures to generate poisonous fume. Specific methods:Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Remove movable containers if safe to do so. Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment. equipment for firefighters: Section6. ACCIDENTAL RELEASE MEASURES Use personal protective equipment. Keep people away from and upwind of spill/leak. Personal precautions, protective equipment and Ensure adequate ventilation. Entry to non-involved personnel should be controlled emergency procedures: around the leakage area by roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust). containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected up: material should be promptly disposed of, in accordance with appropriate laws and regulations. Prevention of secondary Remove all sources of ignition. Fire-extinguishing devices should be prepared in hazards:case of a fire. Use spark-proof tools and explosion-proof equipment. Section7. HANDLING AND STORAGE Handling Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment. Prevent generation of vapor or mist. Keep away from flames and hot surfaces. Take measures to prevent the build up of electrostatic charge. Use explosion-proof equipment. Wash hands and face thoroughly after handling. Use a closed system, ventilation. Advice on safe handling:Avoid contact with skin, eyes and clothing. Storage Storage conditions:Keep container tightly closed. Store in a cool, dark and well-ventilated place. Store away from incompatible materials such as oxidizing agents. Packaging material:Law is followed. Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Install a closed system or local exhaust as possible so that workers should not be Engineering controls: exposed directly. Also install safety shower and eye bath. Personal protective equipment Respiratory protection: Vapor respirator. Follow local and national regulations. Hand protection:Protective gloves. Eye protection:Safety glasses. A face-shield, if the situation requires. Skin and body protection: Protective clothing. Protective boots, if the situation requires. Section9. PHYSICAL AND CHEMICAL PROPERTIES Physical state (20°C):Liquid Form:clear Color:Colorless - Slightly pale yellow Odor:No data available pH: No data available Melting point/freezing point:No data available 210 °C Boiling Point/Range: Flash Point:No data available 2-Chlorophenetole Section9. PHYSICAL AND CHEMICAL PROPERTIES Explosive limits No data available Lower: Upper:No data available 1.14 Density: Solubility:No data available Section10. STABILITY AND REACTIVITY Stability:Stable under proper conditions. Reactivity:No special reactivity has been reported. Incompartible materials: oxidizing agents Hazardous Decomposition Carbon monoxide, Carbon dioxide, Hydrogen chloride Products: Section11. TOXICOLOGICAL INFORMATION No data available Acute Toxicity: Skin corrosion/irritation: No data available No data available Serious eye damage/irritation: Germ cell mutagenicity: No data available Carcinogenicity: No data available IARC = NTP =No data available No data available Reproductive toxicity: Section12. ECOLOGICAL INFORMATION Ecotoxicity: Fish:No data available Crustacea:No data available Algae:No data available Persistence / degradability: No data available BioaccumulativeNo data available potential(BCF): Mobillity in soil log Pow:No data available Soil adsorption (Koc):No data available Henry's LawNo data available constant(PaM3/mol): Section13. DISPOSAL CONSIDERATIONS Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when disposing of the substance. Section14. TRANSPORT INFORMATION Hazards Class:Does not correspond to the classification standard of the United Nations UN-No:Not Listed Section15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were prescribed. 2-Chlorophenetole SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 三、生态学数据： 1、其它有害作用：该物质对环境可能有危害，对水体应给予特别注意。

安全

• 风险声明 (欧洲): R36/37/38
• 安全声明 (欧洲): S26-S36/37/39
• 海关编码: 2909309090

合成路线

64-67-5 95-57-8 ~86% 614-72-2

文献：Basak, Anindita; Nayak, Mrinal K.; Chakraborti, Asit K. Tetrahedron Letters, 1998 , vol. 39, # 27 p. 4883 - 4886

64-17-5 95-50-1 ~% 614-72-2

文献：Tetrahedron, , vol. 39, # 20 p. 3437 - 3440

103-73-1 ~7% 622-61-7 614-72-2

文献：Chemistry Letters, , p. 661 - 662

1080-32-6 1193-00-6 ~% 614-72-2

文献：Kogyo Kagaku Zasshi, , vol. 60, p. 21,22 Chem.Abstr., , p. 4177

95-57-8 ~% 614-72-2

文献：Justus Liebigs Annalen der Chemie, , vol. 176, p. 41 Justus Liebigs Annalen der Chemie, , vol. 182, p. 94

94-70-2 ~% 614-72-2

文献：Journal de Chimie Physique et de Physico-Chimie Biologique, , vol. 20, p. 60 Chem. Zentralbl., , vol. 94, # III p. 918

95-51-2 ~% 614-72-2

文献：Justus Liebigs Annalen der Chemie, , vol. 176, p. 41 Justus Liebigs Annalen der Chemie, , vol. 182, p. 94

64-19-7 103-73-1 ~% 622-61-7 614-72-2

文献：Journal of the Chemical Society, , p. 3939

上下游产品

上游产品  10
64-67-5 95-57-8 64-17-5 95-50-1
103-73-1 1080-32-6 1193-00-6 94-70-2
95-51-2 64-19-7
下游产品  4
37612-59-2 103-73-1 1864-92-2 5493-71-0

海关

海关编码	2909309090
中文概述	2909309090 其他芳香醚及其卤化衍生物、磺化、硝化衍生物（包括亚硝化衍生物）。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%