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5137-55-3价格

5137-55-3

5137-55-3结构式
5137-55-3结构式

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中文名 甲基三辛基氯化铵
英文名 methyltrioctylammonium chloride
中文别名 甲基三正辛基氯化铵
氯化三辛基甲基铵
三辛基甲基氯化铵
三辛基甲基氯化铵
氯化甲基三辛基铵
三正辛基甲基氯化铵
三辛基甲基氯化鋁
英文别名 1-Octanaminium, N-methyl-N,N-dioctyl-, chloride (1:1)
CAPRIQUAT
N-Methyl-N,N-dioctyloctan-1-aminium chloride
tri-n-octylmethylammonium chloride
ALIQUAT 336
Methyl trioctyl ammonium chloride
tricaprylylmethylammonium chloride
ALIQUAT(TM) 336
MFCD00011862
methyltri(n-octyl)ammonium chloride
TOMAC
N-Methyl-N,N-dioctyl-1-octanaminium chloride
aliquat
Aliquat.(R). 336
Aliquat(rg 336
Trioctyl methyl ammonium chloride
ADOGEN 464
Methyltri-n-octylaMMoniuM Chloride
methyltri-C8,10-ammonium chloride
EINECS 225-896-2
trioctylmethylammonium chloride
Methyltrioctylammonium chloride
Aliquat 336N
密度 0.884 g/mL at 25 °C(lit.)
沸点 240°C
熔点 -20°C
分子式 C25H54ClN
分子量 404.156
闪点 >230 °F
精确质量 403.394470
LogP 5.51850
外观性状 黏的无色至淡橙色液体
折射率 n20/D 1.4665(lit.)
储存条件

避光,阴凉干燥处,密封保存

稳定性

1.常温常压下稳定,前橘黄色液体。

2.有刺激性。

水溶解性 水溶性:实际上不溶;水溶解度:6 g/l   30 °C;可溶于:甲醇,苯,氯仿
计算化学

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:1

4.可旋转化学键数量:21

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:27

8.表面电荷:0

9.复杂度:220

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:2

更多

1. 性状:黄色粘状液体

2. 密度:0.884

3. 相对蒸汽密度(g/mL,空气=1):不确定

4. 熔点(ºC):-20

5. 沸点(ºC,常压):不确定

6. 沸点(ºC,25mmHg):不确定

7. 折光率(nD20):不确定

8. 闪点(°C):132

9. 比旋光度(º, C=1, EtOH):不确定

10. 自燃点或引燃温度(ºC):不确定

11. 蒸气压(kPa,25ºC):不确定

12. 饱和蒸气压(kPa,60ºC):不确定

13. 燃烧热(KJ/mol):不确定

14. 临界温度(ºC):不确定

15. 临界压力(KPa):不确定

16. 油水(辛醇/水)分配系数的对数值:不确定

17. 爆炸上限(%,V/V):不确定

18. 爆炸下限(%,V/V):不确定

19. 溶解性:不确定

Name: Aliquat 336 Material Safety Data Sheet
Synonym: Methyltrioctylammonium chloride, Tricaprylylmethylammonium chloride; n-methyl-n,n-dioctyl-1-octanaminium chlorid
CAS: 5137-55-3
Section 1 - Chemical Product MSDS Name:Aliquat 336 Material Safety Data Sheet
Synonym:Methyltrioctylammonium chloride, Tricaprylylmethylammonium chloride; n-methyl-n,n-dioctyl-1-octanaminium chlorid

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
5137-55-3 Methyl tricaprylammonium chloride 85-95 225-896-2
Hazard Symbols: XN
Risk Phrases: 22 36/38 41

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes and skin. Risk of serious damage to eyes.Hygroscopic (absorbs moisture from the air).Toxic.
Potential Health Effects
Eye:
May result in corneal injury. Causes severe eye irritation and possible burns.
Skin:
May cause severe irritation and possible burns.
Ingestion:
Harmful if swallowed. May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns.
Inhalation:
May cause severe respiratory tract irritation and possible burns.
Harmful if inhaled.
Chronic:
Prolonged or repeated skin contact may cause dermatitis.

Section 4 - FIRST AID MEASURES
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Antidote: None reported.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Runoff from fire control or dilution water may cause pollution. This liquid floats on water and may travel to a source of ignition and spread fire.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. Flush area with dilute (5%) acetic acid, and collect rinsate for disposal.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Use with adequate ventilation. Use only in a chemical fume hood. Discard contaminated shoes.
Storage:
Keep away from sources of ignition. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 5137-55-3: CAS# 7732-18-5: CAS# 68603-15-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: viscous colorless to pale orange
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: 1500 mPas 30 deg C
Boiling Point: 225 deg C @ 760.00mm Hg
Freezing/Melting Point: -20 deg C
Autoignition Temperature: Not available.
Flash Point: 132 deg C ( 269.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in benzene, chloroform, isopropa
Specific Gravity/Density: .8840g/cm3
Molecular Formula: C25H54ClN
Molecular Weight: 404.15

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 5137-55-3: BR8575000 CAS# 7732-18-5: ZC0110000 CAS# 68603-15-6: AZ0878000 LD50/LC50:
CAS# 5137-55-3: Draize test, rabbit, skin: 0.5 mL Severe; Oral, mouse: LD50 = 280 mg/kg; Oral, rat: LD50 = 223 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 68603-15-6.
Carcinogenicity:
Methyl tricaprylammonium chloride - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Alcohols, c6-12 - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/38 Irritating to eyes and skin.
R 41 Risk of serious damage to eyes.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 5137-55-3: 2
CAS# 7732-18-5: No information available.
CAS# 68603-15-6: 1
Canada
CAS# 5137-55-3 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 68603-15-6 is listed on Canada's DSL List.
CAS# 5137-55-3 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 68603-15-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 5137-55-3 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 68603-15-6 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

毒理学数据:

1、急性毒性:大鼠口径LD50:223 mg/kg;大鼠腹腔LD50:6600 ug/kg;小鼠口径LD50:280 mg/kg;

兔子腹腔LDLo:10 mg/kg;豚鼠腹腔LDLo:10 mg/kg

2、 皮肤/眼睛刺激:兔子皮肤标准Draize测试:0.5 mLREACTION SEVERITY : Severe

生态学数据:

该物质对环境可能有危害,对水体应给予特别注意

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BR8575000
CHEMICAL NAME :
Ammonium, methyltrioctyl-, chloride
CAS REGISTRY NUMBER :
5137-55-3
LAST UPDATED :
199710
DATA ITEMS CITED :
10
MOLECULAR FORMULA :
C25-H54-N.Cl
MOLECULAR WEIGHT :
404.25
WISWESSER LINE NOTATION :
8K8&8&1 &G

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
AEHA** U.S. Army, Environmental Hygiene Agency Reports. (Edgewood Arsenal, MD 21010) Volume(issue)/page/year: 33-3-68/1971 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
223 mg/kg
TOXIC EFFECTS :
Gastrointestinal - hypermotility, diarrhea Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
AEHA** U.S. Army, Environmental Hygiene Agency Reports. (Edgewood Arsenal, MD 21010) Volume(issue)/page/year: 33-3-68/1971
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
6600 ug/kg
TOXIC EFFECTS :
Behavioral - muscle weakness
REFERENCE :
AEHA** U.S. Army, Environmental Hygiene Agency Reports. (Edgewood Arsenal, MD 21010) Volume(issue)/page/year: 33-3-68/1971
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
280 mg/kg
TOXIC EFFECTS :
Behavioral - muscle weakness
REFERENCE :
AEHA** U.S. Army, Environmental Hygiene Agency Reports. (Edgewood Arsenal, MD 21010) Volume(issue)/page/year: 33-3-68/1971
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
3300 ug/kg
TOXIC EFFECTS :
Behavioral - muscle weakness
REFERENCE :
AEHA** U.S. Army, Environmental Hygiene Agency Reports. (Edgewood Arsenal, MD 21010) Volume(issue)/page/year: 33-3-68/1971
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
10 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AEHA** U.S. Army, Environmental Hygiene Agency Reports. (Edgewood Arsenal, MD 21010) Volume(issue)/page/year: 33-3-68/1971
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
10 mg/kg
TOXIC EFFECTS :
Behavioral - muscle weakness
REFERENCE :
AEHA** U.S. Army, Environmental Hygiene Agency Reports. (Edgewood Arsenal, MD 21010) Volume(issue)/page/year: 33-3-68/1971 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X7902 No. of Facilities: 10 (estimated) No. of Industries: 2 No. of Occupations: 2 No. of Employees: 10 (estimated) No. of Female Employees: 7 (estimated)

危害码 (欧洲) Xn:Harmful
风险声明 (欧洲) R22;R38;R41;R50/53
安全声明 (欧洲) S26-S39-S60-S61
危险品运输编码 UN 2810 6.1/PG 3
WGK德国 3
RTECS号 UZ2997500
包装等级 III
危险类别 6.1
海关编码 2827101000

1.高压釜法
将396克(1摩尔)N235和300毫升乙醇混和于高压釜内,釜体用于冰一丙酮冷却。然后倒入2摩尔氯甲烷(预先冷冻液化,收集在锥形瓶内),立即关闭高压釜,搅拌并加热至100在<10公斤/厘米2的压力下反应4一5小时后,冷至室温,放出残余的氯甲烷。然后真空蒸馏除去乙醇,即得棕色产物,约重430克(95一100%)。
2.常压法
将100毫升询52克,0.2摩尔)N235和与N236的体积比为1.5:1的异辛醇置于管式反应器中,在150毫升/分的流量下通入氯甲烷约20分钟。然后加热至130℃。以微小气泡的流速通入氯甲烷,反应5一7小时。冷却,将反应物转移至液膜蒸发器中,在120-130℃/3一5mm真空蒸馏蒸去溶剂即得产品。转化率为60-70%.

5137-55-3 preparation

海关编码 2923900090
中文概述 2923900090 其他季铵盐及季铵碱。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%
申报要素 品名, 成分含量, 用途
Summary 2923900090 other quaternary ammonium salts and hydroxides。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%