111480-84-3

• 常用中文名：2-砒啶磺酰氯盐酸盐
• 常用英文名：2-(Chlorosulfonyl)pyridinium chloride
• CAS号：111480-84-3
• 分子式：C₅H₅Cl₂NO₂S
• 分子量：214.070
• 相关类别： 化学试剂 有机试剂 酰卤
• 发布时间：2018-04-03 08:00:00
• 更新时间：2024-01-06 19:00:29

名称

• 中文名: 2-砒啶磺酰氯盐酸盐
• 英文名: pyridine-2-sulfonyl chloride,hydrochloride
• 中文别名: 2-嘧啶磺酰氯化物
• 英文别名: 2-(Chlorosulfonyl)pyridinium chloride; 2-Pyridinesulfonyl Chloride0,Hydrochloride; 2-Pyridinesulfonyl chloride,HCl; 2-pyridinesulfonyl chloride hydrochloride; Pyridyl-2-sulfonyl chloride hydrochloride; Pyridine-2-sulfonyl Chloride Monohydrochloride; 2-Pyridinesulfonyl chloride hydrochloride (1:1); 2-Pyridinesulfonyl chloride, hydrochloride (1:1); Pyridine-2-sulfonyl chloride hydrochloride (1:1); Pyridine-2-sulfonyl chloride hydrochloride; 2-Chlorosulfonyl-pyridinium chloride

物化性质

• 沸点: 314.4ºC at 760 mmHg
• 熔点: 77-81ºC
• 分子式: C₅H₅Cl₂NO₂S
• 分子量: 214.070
• 闪点: 143.9ºC
• 精确质量: 212.941803
• PSA: 55.41000
• LogP: 2.89190
• 外观性状: 灰白色固体
• 蒸汽压: 0.000344mmHg at 25°C
• 储存条件: Keep Cold

MSDS

Material Safety Data Sheet Section1. Identification of the substance 2-Pyridinesulfonyl chloride, HCl Product Name: Synonyms: Section2. Hazards identification Harmful by inhalation, in contact with skin, and if swallowed. H317:May cause an allergic skin reaction H319:Causes serious eye irritation P280:Wear protective gloves/protective clothing/eye protection/face protection P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing Section3. Composition/information on ingredients. Ingredient name:2-Pyridinesulfonyl chloride, HCl CAS number:111480-84-3 Section4. First aid measures Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing contaminated clothing and shoes. If irritation persists, seek medical attention. Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical attention. Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention. Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention. Section5. Fire fighting measures In the event of a fire involving this material, alone or in combination with other materials, use dry powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus should be worn. Section6. Accidental release measures Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national standards. Respiratory precaution:Wear approved mask/respirator Hand precaution:Wear suitable gloves/gauntlets Skin protection:Wear suitable protective clothing Eye protection:Wear suitable eye protection Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container for disposal. See section 12. Environmental precautions: Do not allow material to enter drains or water courses. Section7. Handling and storage This product should be handled only by, or under the close supervision of, those properly qualified Handling: in the handling and use of potentially hazardous chemicals, who should take into account the fire, health and chemical hazard data given on this sheet. Store in closed vessels, under −20◦C. Storage: Section8. Exposure Controls / Personal protection Engineering Controls: Use only in a chemical fume hood. Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles. General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse. Section9. Physical and chemical properties Appearance:Not specified Boiling point:No data Melting point:No data Flash point:No data Density:No data Molecular formula: C5H4ClNO2S.HCl Molecular weight: 214.1 Section10. Stability and reactivity Conditions to avoid: Heat, flames and sparks. Materials to avoid: Oxidizing agents. Possible hazardous combustion products: Carbon monoxide, nitrogen oxides, hydrogen chloride, sulfur oxides. Section11. Toxicological information No data. Section12. Ecological information No data. Section13. Disposal consideration Arrange disposal as special waste, by licensed disposal company, in consultation with local waste disposal authority, in accordance with national and regional regulations. Section14. Transportation information Non-harzardous for air and ground transportation. Section15. Regulatory information No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302, or have known CAS numbers that exceed the threshold reporting levels established by SARA Title III, Section 313. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi
• 风险声明 (欧洲): R34
• 安全声明 (欧洲): 26-36/37/39
• 危险品运输编码: UN 3261

合成路线

2637-34-5 ~54% 111480-84-3

文献：Hanessian, Stephen; Kagotani, Masahiro Synthesis, 1987 , # 4 p. 409 - 411

上下游产品

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111480-82-1