877-66-7

• 常用中文名：4-甲磺酰基苯肼盐酸盐
• 常用英文名：[4-(Methylsulfonyl)phenyl]hydrazine hydrochloride
• CAS号：877-66-7
• 分子式：C₇H₁₁ClN₂O₂S
• 分子量：222.69200
• 相关类别： 有机原料 烃类化合物及其衍生物 烃类磺化物
• 发布时间：2018-04-24 08:00:00
• 更新时间：2024-01-12 08:13:48

名称

• 中文名: 4-甲磺酰基苯肼盐酸盐
• 英文名: [4-(Methylsulfonyl)phenyl]hydrazine hydrochloride
• 中文别名: 4-甲磺酰基苯肼; 4-甲磺酰基苯肼HC; 4-甲基磺酰基苯肼盐酸盐; 对甲磺酰基苯肼盐酸盐
• 英文别名: 4-Methylsulfonylphenylhydrazine hydrochloride; MFCD00216494; EINECS 212-895-7

物化性质

• 密度: 1.351 g/cm3
• 沸点: 418.7ºC at 760 mmHg
• 熔点: 202ºC
• 分子式: C₇H₁₁ClN₂O₂S
• 分子量: 222.69200
• 闪点: 207ºC
• 精确质量: 222.02300
• PSA: 80.57000
• LogP: 3.03180
• 外观性状: 棕色至黄色粉末
• 储存条件: 室温

MSDS

Name: 4-Methylsulphonylphenylhydrazine Hydrochloride 95+% Material Safety Data Sheet Synonym: None Known CAS: 877-66-7 Section 1 - Chemical Product MSDS Name:4-Methylsulphonylphenylhydrazine Hydrochloride 95+% Material Safety Data Sheet Synonym:None Known Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 877-66-7 4-Methylsulphonylphenylhydrazine Hydro 95+% 212-895-7 Hazard Symbols: None Listed. Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution. Extinguishing Media: Use agent most appropriate to extinguish fire. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels. Exposure Limits CAS# 877-66-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder Color: off-white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 202 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: soluble Specific Gravity/Density: Molecular Formula: C7H10N2O2S.HCl Molecular Weight: 222.69 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, dust generation, excess heat, strong oxidants. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, sulfur oxides (SOx), including sulfur oxide and sulfur dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 877-66-7 unlisted. LD50/LC50: Not available. Carcinogenicity: 4-Methylsulphonylphenylhydrazine Hydrochloride - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: Not regulated. Hazard Class: UN Number: Packing Group: IMO Shipping Name: Not regulated. Hazard Class: UN Number: Packing Group: RID/ADR Shipping Name: Not regulated. Hazard Class: UN Number: Packing group: Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 877-66-7: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 877-66-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 877-66-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi: Irritant;
• 风险声明 (欧洲): R24/25
• 安全声明 (欧洲): 24/25
• 海关编码: 2928000090

合成路线

98-57-7 ~% 877-66-7

文献：Journal of Medicinal Chemistry, , vol. 47, # 25 p. 6195 - 6206

3466-32-8 ~% 877-66-7

文献：Journal fuer Praktische Chemie (Leipzig), , vol. <2> 132, p. 24,35

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海关

海关编码	2928000090
中文概述	2928000090 其他肼（联氨）及胲（羟胺）的有机衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%