35856-62-3

• 常用中文名：哌啶-1-磺酰氯
• 常用英文名：Piperidine-1-sulfonyl chloride
• CAS号：35856-62-3
• 分子式：C₅H₁₀ClNO₂S
• 分子量：183.656
• 发布时间：2018-04-17 08:00:00
• 更新时间：2024-01-03 09:10:29
• 下载msds

名称

• 中文名: 哌啶-1-磺酰氯
• 英文名: 1-Piperidinesulfonyl chloride
• 中文别名: 哌啶磺酰氯
• 英文别名: 1-Piperidinesulfonyl chloride; piperidine-1-sulfonyl chloride

物化性质

• 密度: 1.4±0.1 g/cm3
• 沸点: 274.2±7.0 °C at 760 mmHg
• 分子式: C₅H₁₀ClNO₂S
• 分子量: 183.656
• 闪点: 119.6±18.2 °C
• 精确质量: 183.012070
• PSA: 45.76000
• LogP: 0.79
• 蒸汽压: 0.0±0.6 mmHg at 25°C
• 折射率: 1.533
• 储存条件: 2-8°C

MSDS

Material Safety Data Sheet Section1. Identification of the substance Product Name: Piperidine-1-sulfonyl chloride Synonyms: Section2. Hazards identification Harmful by inhalation, in contact with skin, and if swallowed. H314:Causes severe skin burns and eye damage H318:Causes serious eye damage P260:Do not breathe dust/fume/gas/mist/vapours/spray P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting P405:Store locked up Section3. Composition/information on ingredients. Ingredient name:Piperidine-1-sulfonyl chloride CAS number:35856-62-3 Section4. First aid measures Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing contaminated clothing and shoes. If irritation persists, seek medical attention. Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical attention. Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention. Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention. Section5. Fire fighting measures In the event of a fire involving this material, alone or in combination with other materials, use dry powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus should be worn. Section6. Accidental release measures Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national standards. Respiratory precaution:Wear approved mask/respirator Hand precaution:Wear suitable gloves/gauntlets Skin protection:Wear suitable protective clothing Eye protection:Wear suitable eye protection Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container for disposal. See section 12. Environmental precautions: Do not allow material to enter drains or water courses. Section7. Handling and storage Handling:This product should be handled only by, or under the close supervision of, those properly qualified in the handling and use of potentially hazardous chemicals, who should take into account the fire, health and chemical hazard data given on this sheet. Storage:Store in closed vessels, refrigerated. Section8. Exposure Controls / Personal protection Engineering Controls: Use only in a chemical fume hood. Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles. General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse. Section9. Physical and chemical properties Appearance:Not specified Boiling point:No data Melting point:No data Flash point:No data Density:No data Molecular formula: C5H10ClNO2S Molecular weight: 183.7 Section10. Stability and reactivity Conditions to avoid: Heat, flames and sparks. Materials to avoid: Oxidizing agents. Possible hazardous combustion products: Carbon monoxide, nitrogen oxides, hydrogen chloride, sulfur oxides. Section11. Toxicological information No data. Section12. Ecological information No data. Section13. Disposal consideration Arrange disposal as special waste, by licensed disposal company, in consultation with local waste disposal authority, in accordance with national and regional regulations. Section14. Transportation information UN Number:UN3265 Class: 8 Packing group: II Proper shipping name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Piperidine-1-sulfonyl chloride) Section15. Regulatory information No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302, or have known CAS numbers that exceed the threshold reporting levels established by SARA Title III, Section 313. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 符号: GHS05
• 信号词: Danger
• 危害声明: H314
• 警示性声明: P280-P305 + P351 + P338-P310
• 危害码 (欧洲): C
• 危险品运输编码: 3265.0
• 海关编码: 2933399090

合成路线

110-89-4 ~63% 35856-62-3

文献：Padma, D. K.; Bhat, V. Subrahmanya; Murthy, A. R. Vasudeva Journal of Fluorine Chemistry, 1982 , vol. 20, p. 425 - 438

110-89-4 ~62% 35856-62-3 6091-44-7

文献：Journal of the American Chemical Society, , vol. 135, # 29 p. 10638 - 10641

6091-44-7 ~% 35856-62-3

文献：Bioorganic and Medicinal Chemistry Letters, , vol. 7, # 24 p. 3075 - 3080

110-85-0 ~% 35856-62-3

文献：US6372778 B1, ; Example 150 ; US 6372778 B1

2156-71-0 ~% 35856-62-3

文献：Justus Liebigs Annalen der Chemie, , vol. 624, p. 25,29

110-89-4 16475-29-9 ~% 35856-62-3

文献：Bulletin de la Societe Chimique de France, , vol. <5> 3, p. 2143,2146, 2149, 2150

上下游产品

上游产品  5
110-89-4 6091-44-7 110-85-0 2156-71-0
16475-29-9
下游产品  6
35088-89-2 32176-33-3 2851-09-4 90233-68-4
4703-22-4 5033-23-8

海关

海关编码	2933399090
中文概述	2933399090. 其他结构含非稠合吡啶环的化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期
Summary	2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%