14175-03-2

14175-03-2结构式

常用中文名：草酸钐(Ⅲ)十水合物
常用英文名：SAMARIUM(III) OXALATE DECAHYDRATE
CAS号：14175-03-2
分子式：C₆O₁₂Sm₂
分子量：564.77700
相关类别：有机原料羧酸类化合物及衍生物羧酸酯及其衍生物的盐
发布时间：2018-07-29 09:13:17
更新时间：2024-04-11 07:05:54

化源商城直购

中文名	草酸钐(III)
英文名	samarium oxalate
中文别名	十水草酸钐
英文别名	MFCD00150489 EINECS 221-844-8 samarium oxalate decahydrate Eslicarbazepine S5VXA428R4 Samariumoxalat-Decahydrat

沸点	365.1ºC at 760 mmHg
分子式	C₆O₁₂Sm₂
分子量	564.77700
闪点	188.8ºC
精确质量	567.77800
PSA	157.80000
外观性状	Crystalline \| White
蒸汽压	2.51E-06mmHg at 25°C
储存条件	常温密闭避光，通风干燥
稳定性	常温常压下稳定避免的物料：氧化物。微溶于水，25℃溶解度为0.054g。
水溶解性	0.000054g/100mL H2O [CRC10]
分子结构	1、摩尔折射率：无可用的 2、摩尔体积（cm³/mol）：无可用的 3、等张比容（90.2K）：无可用的 4、表面张力（dyne/cm）：无可用的 5、介电常数：无可用的 6、极化率（10^-24cm³）：无可用的 7、单一同位素质量：567.778375 Da 8、标称质量：568 Da 9、平均质量：564.777 Da
计算化学	1、疏水参数计算参考值（XlogP）：0 2、氢键供体数量：0 3、氢键受体数量：12 4、可旋转化学键数量：0 5、拓扑分子极性表面积（TPSA）：241 6、重原子数量：20 7、表面电荷：0 8、复杂度：60.5 9、同位素原子数量：0 10、确定原子立构中心数量：0 11、不确定原子立构中心数量：0 12、确定化学键立构中心数量：0 13、不确定化学键立构中心数量：0 14、共价键单元数量：5
更多	1. 性状：白色晶体。 2. 密度（g/mL,25/4℃）：未确定 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,5.2kPa）：未确定 7. 折射率：未确定 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：可溶解的

Section 1: Product Identification
Chemical Name:Samarium (III) oxalate hydrate(99.9%-Sm) (REO)
CAS Registry Number:14175-03-2
Formula:Sm2(C2O4)3.XH2O
EINECS Number:none
Chemical Family:salt of an organic acid

Synonym:samarium oxalate, Oxalic acid, samarium salt.

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound14175-03-2100%no datano data

Section 3: Hazards Identification
Soluble oxalates are harmful if swallowed. They precipitate calcium from the bloodstream causing violent
Emergency Overview:
muscular stimulation, convulsions, collapse, and death.
Primary Routes of Exposure:Ingestion, Inhalation of dust.
Eye Contact:May cause moderate to severe irritation of the eyes.
Skin Contact:May cause moderate to severe irritation of the skin.
Inhalation:Dust may be severely irritating to the nose, mucous membranes and respiratory tract.
Ingestion:Ingestion may cause vomiting, pain, violent muscular stimulation, convulsions, collapse, and death.
Soluble oxalates remove calcium from the bloodstream. This interferes with the central nervous system
Acute Health Affects:
causing violent convulsions and death.
Prolonged exposure to oxalates can lead to kidney failure resulting from calcium oxalate precipitation in renal
Chronic Health Affects:
tubes
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical
Skin Exposure:
assistance if irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Antidotes are said to be soluble calcium given orally, and calcium gluconate given intravenously, to be
Ingestion:
administered by trained medical personnel. Keep the victim calm. Give the victim water (only if conscious).

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam
If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a sealed container. Keep away from heat and moisture.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear appropriate chemical resistant gloves and protective clothing.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
Respirator:
requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white pwdr.
Molecular Weight:564.76
Melting Point:no data
Boiling Point:no data
Vapor Pressure:not applicable
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable solid
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:none
Decomposition Products:Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none

SECTION 16 - ADDITIONAL INFORMATION
N/A

毒理学数据:

1、急性毒性：主要的刺激性影响：

在皮肤上面：刺激皮肤和粘膜；

在眼睛上面：刺激的影响；没有已知的敏化影响。

生态学数据:

通常对水体是稍微有害的，不要将未稀释或大量产品接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。

危害码 (欧洲)	Xn
危险品运输编码	UN3288
包装等级	III
危险类别	6.1

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