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117-62-4价格

117-62-4

117-62-4结构式
117-62-4结构式

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中文名 2-萘胺-1,5-二磺酸
英文名 2-Amino-1,5-naphthalenedisulfonic acid
中文别名 1,5酸
2-氨基-1,5-萘二磺酸
异构C酸
磺化吐氏酸
英文别名 2-Aminonaphthalene-1,5-disulfonic acid
MFCD00021512
D SALT
Sulfonic Tobias Acid
EINECS 204-201-6
2-AMINO-1,5-NAPHTHALENE-DISULFONIC ACID
1,5-Naphthalenedisulfonic acid, 2-amino-
2-Naphthylamine-1,5-disulfonic acid
SULFO TOBIAS ACID
1,5-disulfo-2-aminonaphthalene
2-aminonaphthalene-1,5-disulphonic acid
kyselinasulfo-tobiasova
2-amino-1,5-naphthalenedisulfonic
2-Amino-1,5-naphthalenedisulfonic acid
2-amino-1,5-naphthalenedisulphonic acid
2-amino-naphthol-1,5-disulfonic acid
2-naphthylamine-1,5-disulphonic acid
SULPHOTOBIAS ACID
2-amino-1,5-naphthalenedisulfonate
2-amino-5-naphthalenedisulfonicacid
5-sulfo-tobiasaci
密度 1.8±0.1 g/cm3
熔点 > 300ºC
分子式 C10H9NO6S2
分子量 303.312
精确质量 302.987122
PSA 151.52000
LogP -0.43
外观性状 米色粉末
折射率 1.733
储存条件 库房通风低温干燥
水溶解性 soluble
分子结构

五、分子性质数据:

1、 摩尔折射率:68.62

2、 摩尔体积(m3/mol):171.3

3、 等张比容(90.2K):528.0

4、 表面张力(dyne/cm):90.1

5、 极化率(10-24cm3):27.20

计算化学

1.疏水参数计算参考值(XlogP):0.5

2.氢键供体数量:3

3.氢键受体数量:7

4.可旋转化学键数量:2

5.互变异构体数量:无

6.拓扑分子极性表面积152

7.重原子数量:19

8.表面电荷:0

9.复杂度:531

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

更多

1. 性状:未确定

2. 密度(g/mL,25℃):1.136

3. 相对蒸汽密度(g/mL,空气=1):未确定

4. 熔点(ºC):未确定

5. 沸点(ºC,常压):未确定

6. 沸点(ºC, KPa):未确定

7. 折射率:未确定

8. 闪点(ºC):未确定

9. 比旋光度(º):未确定

10. 自燃点或引燃温度(ºC):未确定

11. 蒸气压(mmHg, ºC):未确定

12. 饱和蒸气压(kPa, ºC):未确定

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC):未确定

15. 临界压力(KPa):未确定

16. 油水(辛醇/水)分配系数的对数值:未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V):未确定

19. 溶解性:未确定

Name: 2-Amino-1 5-Naphthalenedisulfonic Acid Tech. Material Safety Data Sheet
Synonym: 2-Naphthylamine-1,5-Disulfonic Acid
CAS: 117-62-4
Section 1 - Chemical Product MSDS Name:2-Amino-1 5-Naphthalenedisulfonic Acid Tech. Material Safety Data Sheet
Synonym:2-Naphthylamine-1,5-Disulfonic Acid

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
117-62-4 2-Amino-1,5-Naphthalenedisulfonic Acid ca 100 204-201-6
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause systemic effects.
Inhalation:
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.

Section 4 - FIRST AID MEASURES
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Use only in a well-ventilated area. Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 117-62-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: beige
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: > 300 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble
Specific Gravity/Density:
Molecular Formula: C10H9NO6S2
Molecular Weight: 303.29

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 117-62-4: QJ6135000 LD50/LC50:
CAS# 117-62-4: Draize test, rabbit, eye: 20 mg/24H Moderate; Draize test, rabbit, skin: 500 mg/24H Mild; Oral, rat: LD50 = 5430 mg/kg.
Carcinogenicity:
2-Amino-1,5-Naphthalenedisulfonic Acid - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 117-62-4: 1
Canada
CAS# 117-62-4 is listed on Canada's DSL List.
CAS# 117-62-4 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 117-62-4 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

毒理学数据:

1、 刺激性:兔经皮标准德雷兹染眼实验:500mg/24H 轻度刺激。

兔经眼标准德雷兹染眼实验:20mg/24H 中度刺激。

2、 急性毒性:大鼠经口LD5O:5430mg/kg

CHEMICAL IDENTIFICATION

RTECS NUMBER :
QJ6135000
CHEMICAL NAME :
1,5-Naphthalenedisulfonic acid, 2-amino-
CAS REGISTRY NUMBER :
117-62-4
BEILSTEIN REFERENCE NO. :
2888645
LAST UPDATED :
199701
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C10-H9-N-O6-S2
MOLECULAR WEIGHT :
303.32
WISWESSER LINE NOTATION :
L66J BSWQ CZ GSWQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1058,1986
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1058,1986 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5430 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1058,1986

危害码 (欧洲) C:Corrosive;
风险声明 (欧洲) R34
安全声明 (欧洲) S26-S28A
危险品运输编码 1759
WGK德国 2
RTECS号 QJ6135000
包装等级 III
危险类别 8
海关编码 2921499090

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文献:Journal fuer Praktische Chemie (Leipzig), , vol. <2> 103, p. 135,136, 151, 153

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117-62-4

文献:Chem. News J. Ind. Sci., , vol. 62, p. 163

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117-62-4

文献:Chem. News J. Ind. Sci., , vol. 73, p. 55

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117-62-4结构式

117-62-4

文献:Chem. News J. Ind. Sci., , vol. 62, p. 163
海关编码 2921499090
中文概述 2921499090 其他芳香单胺及衍生物及它们的盐. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
申报要素 品名, 成分含量, 用途
Summary 2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%