68480-28-4
68480-28-4结构式
- 常用中文名：3-甲基-2-丁烯甲酸盐
- 常用英文名：prenyl formate
- CAS号：68480-28-4
- 分子式：C6H10O2
- 分子量：114.14200
- 发布时间：2018-08-13 10:55:22
- 更新时间：2024-01-03 12:47:59
| 中文名 | 3-甲基-2-丁烯甲酸盐 |
|---|---|
| 英文名 | 3-methylbut-2-enyl formate |
| 英文别名 |
formic acid-(3-methyl-but-2-enyl ester)
formiate de methyl-3 butene-2 ol-1 3,3-dimethylallyl formate 3-methylbut-2-en-1-yl formate formiate de prenyle 3-methyl-2-butenyl formate Ameisensaeure-(3-methyl-but-2-enylester) 3-Methyl-2-butenolformiat 2-Buten-1-ol,3-methyl-,formate 3-methyl but-2-enyl formate Prenyl formate |
| 密度 | 0.915g/cm3 |
|---|---|
| 沸点 | 139.6ºC at 760mmHg |
| 分子式 | C6H10O2 |
| 分子量 | 114.14200 |
| 闪点 | 41.4ºC |
| 精确质量 | 114.06800 |
| PSA | 26.30000 |
| LogP | 1.76150 |
| 折射率 | 1.421 |
Synonym:Phenyl format Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 68480-28-4: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: colorless Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 44 - 46 deg C @15mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C6H10O2 Molecular Weight: 114 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Oxidizing agents, acids, bases. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 68480-28-4 unlisted. LD50/LC50: Not available. Carcinogenicity: 3-Methylbut-2-enyl formate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 68480-28-4: No information available. Canada CAS# 68480-28-4 is listed on Canada's NDSL List. CAS# 68480-28-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 68480-28-4 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
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| 文献：Babin, Didier; Fourneron, Jean-Dominique; Julia, Marc Bulletin de la Societe Chimique de France, 1980 , vol. 2, # 11-12 p. 588 - 600 |
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| 文献：Tetrahedron Letters, , vol. 21, p. 1743 - 1746 |
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| 文献：Tetrahedron Letters, , vol. 21, p. 1743 - 1746 |
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| 文献：Tetrahedron Letters, , vol. 21, p. 1743 - 1746 |
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| 文献：Zhurnal Obshchei Khimii, , vol. 22, p. 611,614; engl. Ausg. S. 671, 673 |
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| 文献：Bulletin de la Societe Chimique de France, , vol. 2, # 11-12 p. 588 - 600 |
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68480-28-4
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| 文献：Bulletin de la Societe Chimique de France, , vol. 2, # 11-12 p. 588 - 600 |
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