68480-28-4

68480-28-4 structure
68480-28-4 structure
  • Name: prenyl formate
  • Chemical Name: 3-methylbut-2-enyl formate
  • CAS Number: 68480-28-4
  • Molecular Formula: C6H10O2
  • Molecular Weight: 114.14200
  • Create Date: 2018-08-13 10:55:22
  • Modify Date: 2024-01-03 12:47:59

Name 3-methylbut-2-enyl formate
Synonyms formic acid-(3-methyl-but-2-enyl ester)
formiate de methyl-3 butene-2 ol-1
3,3-dimethylallyl formate
3-methylbut-2-en-1-yl formate
formiate de prenyle
3-methyl-2-butenyl formate
Ameisensaeure-(3-methyl-but-2-enylester)
3-Methyl-2-butenolformiat
2-Buten-1-ol,3-methyl-,formate
3-methyl but-2-enyl formate
Prenyl formate
Density 0.915g/cm3
Boiling Point 139.6ºC at 760mmHg
Molecular Formula C6H10O2
Molecular Weight 114.14200
Flash Point 41.4ºC
Exact Mass 114.06800
PSA 26.30000
LogP 1.76150
Index of Refraction 1.421
Name: 3-Methylbut-2-enyl formate tech. Material Safety Data Sheet
Synonym: Phenyl format
CAS: 68480-28-4
Section 1 - Chemical Product MSDS Name:3-Methylbut-2-enyl formate tech. Material Safety Data Sheet
Synonym:Phenyl format

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
68480-28-4 3-Methylbut-2-enyl formate 270-906-0
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 68480-28-4: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 44 - 46 deg C @15mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H10O2
Molecular Weight: 114

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents, acids, bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 68480-28-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3-Methylbut-2-enyl formate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 68480-28-4: No information available.
Canada
CAS# 68480-28-4 is listed on Canada's NDSL List.
CAS# 68480-28-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 68480-28-4 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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Literature: Babin, Didier; Fourneron, Jean-Dominique; Julia, Marc Bulletin de la Societe Chimique de France, 1980 , vol. 2, # 11-12 p. 588 - 600

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Detail
Literature: Tetrahedron Letters, , vol. 21, p. 1743 - 1746

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68480-28-4 structure

68480-28-4

Detail
Literature: Tetrahedron Letters, , vol. 21, p. 1743 - 1746

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68480-28-4 structure

68480-28-4

Detail
Literature: Tetrahedron Letters, , vol. 21, p. 1743 - 1746

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68480-28-4 structure

68480-28-4

Literature: Zhurnal Obshchei Khimii, , vol. 22, p. 611,614; engl. Ausg. S. 671, 673

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68480-28-4 structure

68480-28-4

Literature: Bulletin de la Societe Chimique de France, , vol. 2, # 11-12 p. 588 - 600

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68480-28-4 structure

68480-28-4

Detail
Literature: Bulletin de la Societe Chimique de France, , vol. 2, # 11-12 p. 588 - 600