37904-03-3
37904-03-3结构式
- 常用中文名：4-氧-4-(4-甲苯胺基)丁-2-烯酸
- 常用英文名：2-Butenoic acid,4-[(4-methylphenyl)amino]-4-oxo-
- CAS号：37904-03-3
- 分子式：C11H11NO3
- 分子量：205.21000
- 发布时间：2018-12-05 16:14:11
- 更新时间：2024-01-27 21:25:35
| 中文名 | 4-氧-4-(4-甲苯胺基)丁-2-烯酸 |
|---|---|
| 英文名 | 4-oxo-4-(4-toluidino)but-2-enoic acid |
| 英文别名 |
N-p-Tolyl-maleamidsaeure
N-(4-METHYLPHENYL)MALEAMIC ACID Maleinsaeure-mono-p-toluidid N-p-Tolyl-maleinamidsaeure N-p-tolyl-maleamic acid (Z)-4-[(4-methylphenyl)amino]-4-oxo-2-butenoic acid |
| 密度 | 1.282g/cm3 |
|---|---|
| 沸点 | 446ºC at 760mmHg |
| 熔点 | 205ºC |
| 分子式 | C11H11NO3 |
| 分子量 | 205.21000 |
| 闪点 | 223.5ºC |
| 精确质量 | 205.07400 |
| PSA | 66.40000 |
| LogP | 1.64730 |
| 折射率 | 1.62 |
Synonym:N-(4-Methylphenyl)maleamic aci Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 37904-03-3: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: yellow Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 205 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C11H11NO3 Molecular Weight: 205 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 37904-03-3 unlisted. LD50/LC50: Not available. Carcinogenicity: 4-Oxo-4-(4-toluidino)but-2-enoic acid - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 37904-03-3: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 37904-03-3 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 37904-03-3 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危害码 (欧洲) | Xi:Irritant; |
|---|---|
| 风险声明 (欧洲) | R36/37/38 |
| 安全声明 (欧洲) | S26-S37/39 |
|
~83%
37904-03-3 |
| 文献：European Journal of Organic Chemistry, , # 6 p. 1254 - 1260 |
