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10159-79-2

10159-79-2结构式
10159-79-2结构式

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中文名 八氢-2H-喹啉-1-甲醇
英文名 2,3,4,6,7,8,9,9a-octahydro-1H-quinolizin-1-ylmethanol
英文别名 Octahydro-2H-Quinolizine-1-Methanol
2H-Quinolizine-1-methanol,octahydro-,(1R-trans)
(+-)-Epilupinin
Octahydro-2H-quinolizin-1-ylmethanol
UPCMLD-DP047
1-Hydroxymethylchinalisidin
<14C>-Lupinin
(1R,9aR)-1-(Octahydroquinolizin-1-yl)methanol
DL-1-Epilupinin
octahydroquinolizin-1-yl-methanol
2H-Quinolizine-1-methanol,octahydro-,(1S-cis)
1-Epilupinine
密度 1.04 g/cm3
沸点 245ºC at 760 mmHg
熔点 68-70ºC
分子式 C10H19NO
分子量 169.26400
闪点 99.1ºC
精确质量 169.14700
PSA 23.47000
LogP 1.18110
蒸汽压 0.00489mmHg at 25°C
折射率 1.525
Name: Octahydro-2H-quinolizin-1-ylmethanol 97% Material Safety Data Sheet
Synonym: Lupinin
CAS: 10159-79-2
Section 1 - Chemical Product MSDS Name:Octahydro-2H-quinolizin-1-ylmethanol 97% Material Safety Data Sheet
Synonym:Lupinin

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
10159-79-2 Octahydro-2H-quinolizin-1-ylmethanol 97% unlisted
Hazard Symbols: T
Risk Phrases: 23/24/25

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Toxic in contact with skin.
Ingestion:
May cause irritation of the digestive tract. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. May cause tingling and numbness of the extremities. Continued exposure may result in muscular weakness, difficulty in maintaining balance, and clumsiness in walking and the use of hands. Toxic if swallowed.
Inhalation:
May cause respiratory tract irritation. Toxic if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 10159-79-2: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 269 - 270 deg C @755mmHg
Freezing/Melting Point: 68 - 70 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: C10H19NO
Molecular Weight: 169

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 10159-79-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Octahydro-2H-quinolizin-1-ylmethanol - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: ALKALOIDS, SOLID, N.O.S.*
Hazard Class: 6.1
UN Number: 1544
Packing Group: III
IMO
Shipping Name: ALKALOID SALTS, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 1544
Packing Group: III
RID/ADR
Shipping Name: ALKALOIDS, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 1544
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 10159-79-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 10159-79-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10159-79-2 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
危害码 (欧洲) Xi: Irritant;
风险声明 (欧洲) R23/24/25
安全声明 (欧洲) S23
危险品运输编码 UN 1544

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10159-79-2结构式

10159-79-2

文献:Journal of the Chemical Society - Perkin Transactions 1, , # 2 p. 219 - 224

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10159-79-2结构式

10159-79-2

文献:Journal of the Chemical Society - Perkin Transactions 1, , # 2 p. 219 - 224

~%

10159-79-2结构式

10159-79-2

文献:Journal of the Chemical Society - Perkin Transactions 1, , # 2 p. 219 - 224

~%

10159-79-2结构式

10159-79-2

文献:Journal of the Chemical Society - Perkin Transactions 1, , # 2 p. 219 - 224

~%

10159-79-2结构式

10159-79-2

文献:Journal of the Chemical Society - Perkin Transactions 1, , # 2 p. 219 - 224

~%

10159-79-2结构式

10159-79-2

文献:Journal of the Chemical Society - Perkin Transactions 1, , # 2 p. 219 - 224