78-87-5

• 常用中文名：1,2-二氯丙烷
• 常用英文名：1,2-Dichloropropane
• CAS号：78-87-5
• 分子式：C₃H₆Cl₂
• 分子量：112.986
• 相关类别： 有机原料 烃类化合物及其衍生物 烃类卤化物
• 发布时间：2018-02-03 08:00:00
• 更新时间：2026-07-02 11:01:38
• 【用途一】
  用作溶剂和用于有机合成
  【用途二】
  用作有机合成原料，油类、脂肪的溶剂，洗涤剂，树脂、农药的原料。经氨化可制得丙二胺。1,2-二氯丙烷和1,3-二氯丙烯，作为农药即滴滴混剂、D-D、Vidden D，[8003-19-8]。D-D为播前杀线虫剂，能有效地防治土壤线虫，包括根瘤线虫、草地线虫、刺线虫、剑线虫、螺旋线虫和甜菜线虫。当药剂施入15-20cm土壤深度时效果最好。该品有药害，在施药和种植之间，至少必须间隔15d。对蜜蜂毒性小。
  【用途三】
  油类和脂肪的溶剂。干洗剂。脱脂剂。杀虫熏蒸混合剂。

名称

• 中文名: 1,2-二氯丙烷
• 英文名: 1,2-dichloropropane
• 中文别名: 甲醇中1,2-二氯丙烷分析校准用标准样品; 1,2-二氯丙烷、二氯丙烷; 1,2-二氯丙烷(STANDD FOR ,); 二硫化碳中1,2-二氯丙烷; 1,2-二氯丙烷(标准品); 二氯化丙烯; 1,2-二氯丙烷(1MG/ML的甲醇溶液)[用于水分析]; 1,2-二氯丙烷-S; 1,2-二氯乙烷和多硫化钠的聚合物; 1,2-二氯丙烷标准溶液; 丙邻二氯; 二硫化碳中1,2-二氯丙烷溶液标准物质; 二氯丙烷(1,2-二氯丙烷); 二氯丙烷/三号稀释油; 1,2-二氯丙烷 溶液; 氯化丙烯; 1,2-二氯丙烷/氯化丙烯; 二氯丙烷; 522 1,2-二氯丙烷 二氯化丙烯; 标准物质/二硫化碳中1,2-二氯丙烷; 1，2-二氯丙烷; 甲醇中1,2-二氯丙烷
• 英文别名: 1,2-Dichlorpropan; 1,2-Dichloropropane >; 1,2 DICHLOROPROPANE, 1X1ML, MEOH, 200UG/ ML; Propylene chloride; 1,2-DichloropropaneSolution,5,000mg/L,2x; 1,2-Propylenechloride; 2H-4,16a-oxybenzo[7,8]fluoreno[2,1-b]quinolizine, cevane-3,4,12,14,16,17,20-htol deriv; ent15; alpha,beta-dichloropropane; Chlorinated C3 hydrocbons; l，2-Dichloropropane; EINECS 201-152-2; Propane,1,2-dichloro; Dichloropropane; CH3CHClCH2Cl; PROPYLENE DICHLORIDE; chloroethylmethylchloride; 1,2-DICHLOROPROPANE, 5000MG, NEAT; propylenedichloride(1,2-dichloropropane); 1,2-two chloropropane; 1,2-DichloropropaneSolution,2,000mg/L; rcrawastenumberu083; 1.2-Dichloropropane [-5]; propylene dichloride; 1,2-D; ENT 15; 1,2-DICHLOROPROPANE; Caswell No. 324; Dwuchloropropan; 1,2-dichloro-propane; bichloruredropylene; alpha,beta-Propylene dichloride; 1,2-DICHLOROPROPANE, STANDD FOR; Rcra waste number U083; Propylendichlorid; 1,2-dichloropropane propylene dichloride; bichloruredropylene(french); Dichloropropanes; α,β-Dichloropropane; 1,2-DICHLOROPROPANE PESTANAL; 1.2-Dichloropr; Cevane-3,4,12,14,16,17,20-htol, 4,9-oxy-, 3-(3,4-dimethoxybenzoate), (3B,4A,16B); Propane,1,2-dichloro-,(±); MFCD00000868; Bichlorure de propylene; PROPYLENE CHLORIDE; 1,2-dichloropropane solution; dichloro-1,2-propane; 1,2-Dichloropropane Standd; R270da; alpha,beta-propylenedichloride; NCI-C55141; 1,2-DICHLOROPROPANE OEKANAL; dwuchloropropan(polish); 1,2-dichloro-propan; 1,2-dichloropropane(asimpurityonly; 1,2-Dichloropropane (1mg/ml in Methanol) [for Water Analysis]; Propylene Chloride Propylene Dichloride; 1,2-dichlorpropan

物化性质

• 密度: 1.1±0.1 g/cm3
• 沸点: 94.5±8.0 °C at 760 mmHg
• 熔点: −100 °C(lit.)
• 分子式: C₃H₆Cl₂
• 分子量: 112.986
• 闪点: 4.4±0.0 °C
• 精确质量: 111.984657
• LogP: 1.76
• 外观性状: 无色液体,带有特有的气味
• 蒸汽密度: 3.89 (vs air)
• 蒸汽压: 53.9±0.2 mmHg at 25°C
• 折射率: 1.420
• 储存条件:

  密封保存。库房通风低温干燥; 与氧化剂、酸类分开存放。可用铁、软钢或铝制容器贮存。

• 稳定性: 其蒸气与空气形成爆炸性混合物，遇明火、高热能引起燃烧爆炸，爆炸极限3.4~14.5（体积）受高热分解产生有毒的腐蚀性气体。 纯净干燥的1,2-二氯丙烷对金属无腐蚀性，有水存在时释放出有强烈腐蚀性的氯化氢，光照能加速分解反应的进行。加热至540~750℃生成3-氯丙烯和1-氯丙烯的混合物。加压下在碱的水溶液中加热至96℃以上生成2-氯丙烯。与碱的醇溶液加热至60~75℃生成2-氯丙烯与1-氯丙烯的混合物。与低级脂肪酸盐反应生成1,2-丙二醇的酯。与浓氨水加热至80℃得到1,2-二氨基丙烷的盐酸盐。
• 水溶解性: 3 g/L (20 ºC)
• 分子结构:

  1、 摩尔折射率：25.60

  2、 摩尔体积（cm³/mol）：101.2

  3、 等张比容（90.2K）：225.7

  4、 表面张力（dyne/cm）：24.7

  5、 极化率（10^-24cm³）：10.15

• 计算化学:

  1.疏水参数计算参考值（XlogP）:1.8

  2.氢键供体数量:0

  3.氢键受体数量:0

  4.可旋转化学键数量:1

  5.互变异构体数量:无

  6.拓扑分子极性表面积0

  7.重原子数量:5

  8.表面电荷:0

  9.复杂度:20.9

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:1

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：无色液体，有氯仿的气味。

  2. 沸点（ºC）：95~96

  3. 熔点（ºC）：-100

  4. 相对密度（g/mL,20ºC）：1.156

  5. 相对蒸汽密度（g/mL,空气=1）：3.9

  6. 折射率：1.4388

  7. 黏度（mPa·s,20ºC）：0.865

  8. 闪点（ºC）：4

  9. 燃点（ºC）：557.2

  10. 蒸发热（KJ/kg,b.p.）：323.2

  11. 熔化热（KJ/kg）：56.6

  12. 燃烧热（KJ/mol）：1545.4

  13. 比热容（KJ/(kg·K),20ºC）：1.30

  14. 临界温度（ºC）：304.3

  15. 临界压力（MPa）：4.4

  16. 蒸气压（kPa,20ºC）：5.33

  17. 爆炸下限（%,V/V）：3.4

  18. 爆炸上限（%,V/V）：14.5

  19. 体膨胀系数（K^-1,20ºC）：0.001108

  20. 溶解性：不溶于水，能与乙醇、乙醚、苯、四氯化碳等大多数有机溶剂混溶。能溶解油脂、蜡、橡胶、树脂及多种染料。20℃时在水中的溶解度为0.26%。

  21. 溶度参数(J·cm^-3)^0.5：18.395

  22. van der Waals面积（cm²·mol^-1）：7.640×10⁹

  23. van der Waals体积（cm³·mol^-1）：54.540

  24. 气相标准声称热(焓)( kJ·mol^-1) ：-162.8

  25. 液相标准声称热(焓)( kJ·mol^-1)：-198.8

  26. 液相标准热熔(J·mol^-1·K^-1)：145.8

MSDS

国标编号: 32036 ＣＡＳ: 78-87-5 中文名称: 1，2-二氯丙烷 英文名称: 1,2-Dichloropropane 别 名: 氯化丙烯 分子式: C3H6Cl2；ClCH2CHClCH3 分子量: 112.99 熔 点: -80℃ 沸点：96.8℃ 密 度: 相对密度(水=1)1.16； 蒸汽压: 15℃ 溶解性: 不溶于水，溶于多数有机溶剂 稳定性: 稳定 外观与性状: 无色液体，有类似氯仿的气味 危险标记: 7(中闪点易燃液体) 用 途: 用作脂肪、油、蜡、树脂和树胶的溶剂及杀虫剂等 2.对环境的影响: 一、健康危害 侵入途径：吸入、食入、经皮吸收。 健康危害：吸入、摄入或经皮肤吸收后对身体有害。1，2-二氯丙烷对中枢神经系统有抑制作用；可使皮肤干燥，脱屑和皲裂；对粘膜有刺激作用；可引起肝、肾和心肌脂肪性变。 二、毒理学资料及环境行为 急性毒性：LD502196mg/kg(大鼠经口)；8750mg/kg(兔经皮)；小鼠吸入4.6g/m3×3～4小时，致死；小鼠经口860mg/kg，致死。 亚急性和慢性毒性：小鼠吸入1.85g/m3×4～7小时/2～12次，肝细胞轻度脂肪变性；大鼠吸入4.4g/m3×7小时×6～32次，半数动物死亡。 致突变性：Ames试验沙门氏菌株TA1535、TA1978、TA100，10～50mg/皿阳性。 危险特性：其蒸气与空气形成爆炸性混合物，遇明火、高热能引起燃烧爆炸。与氧化剂能发生强烈反应。受高热分解产生有毒的腐蚀性气体。其蒸气比空气重，能在较低处扩散到相当远的地方，遇火源引着回燃。若遇高热，容器内压增大，有开裂和爆炸的危险。 燃烧(分解)产物：一氧化碳、二氧化碳、氯化氢、光气。 3.现场应急监测方法: 便携式气相色谱法 4.实验室监测方法: 吹扫捕集-气相色谱法(中国环境监测总站，水质) 气相色谱法《固体废弃物试验与分析评价手册》中国环境监测总站等译 色谱/质谱法 美国EPA524.2方法 5.环境标准: 前苏联 车间空气中有害物质的最高容许浓度 10mg/m3 嗅觉阈浓度 50ppm 6.应急处理处置方法: 一、泄漏应急处理 疏散泄漏污染区人员至安全区，禁止无关人员进入污染区，切断火源。建议应急处理人员戴自给式呼吸器，穿一般消防防护服。在确保安全情况下堵漏。喷水雾能减少蒸发，但不不能降低泄漏物在受限制家间内的易燃性。用沙土或其它不燃性吸附剂混合吸收，然后收集运至废物处理场所处置。也可以用不燃性分散剂制成的乳液刷洗，经稀释的洗水放入废水系统。如大量泄漏，利用围堤收容，然后收集、转移、回收或无害处理后废弃。 废弃物处置方法：用焚烧法。废料同其它燃料混合后焚烧。燃烧要充分，防止生成光气。焚烧炉排气中的卤化氢通过酸洗涤器除去。 二、防护措施 呼吸系统防护：空气中浓度超标时，应该佩带防毒面具。紧急事态抢救或逃生时，佩带自给式呼吸器。 眼睛防护：戴化学安全防护眼镜。 身体防护：穿相应的工作服。 手防护：必要时戴防化学品手套。 其它：工作现场严禁吸烟、进食和饮水。工作后，淋浴更衣。注意个人清洁卫生。 三、急救措施 皮肤接触：脱去污染的衣着，用肥皂水及清水彻底冲洗。 眼睛接触：立即提起眼睑，用流动清水冲洗。 吸入：迅速脱离现场至空气新鲜处。保持呼吸道通畅。呼吸困难时给输氧。呼吸停止时，立即进行人工呼吸。就医。 食入：误服者给饮大量温水，催吐，洗胃，就医。 灭火方法：雾状水、泡沫、二氧化碳、干粉、砂土。

毒性和生态

毒理学数据: 能刺激眼睛、黏膜，引起皮肤炎。高浓度对中枢神经系统有抑制作用。并损害肝、肾脏。嗅觉阈浓度231mg/m3，工作场所最高容许浓度350mg/m3（美国）。小鼠经口LD50为860mg/kg，大鼠吸入的致死浓度为9240mg/m3。 CHEMICAL IDENTIFICATION RTECS NUMBER : TX9625000 CHEMICAL NAME : Propane, 1,2-dichloro- CAS REGISTRY NUMBER : 78-87-5 BEILSTEIN REFERENCE NO. : 1718880 LAST UPDATED : 199712 DATA ITEMS CITED : 72 MOLECULAR FORMULA : C3-H6-Cl2 MOLECULAR WEIGHT : 112.99 WISWESSER LINE NOTATION : GY1&1G HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : Administration into the eye SPECIES OBSERVED : Rodent - rabbit TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1947 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 14 gm/m3/8H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1100 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 860 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value TYPE OF TEST : LCLo - Lowest published lethal concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 1000 ppm/2H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Unreported SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 960 mg/kg TOXIC EFFECTS : Gastrointestinal - ulceration or bleeding from stomach Gastrointestinal - ulceration or bleeding from small intestine TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Mammal - dog DOSE/DURATION : 5 gm/kg TOXIC EFFECTS : Behavioral - sleep Liver - other changes TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 8750 uL/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - guinea pig DOSE/DURATION : 2 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 28 gm/kg/14D-I TOXIC EFFECTS : Kidney, Ureter, Bladder - other changes Related to Chronic Data - death TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 109 mg/kg/26W-I TOXIC EFFECTS : Gastrointestinal - changes in structure or function of endocrine pancreas Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other hydrolases TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 16250 mg/kg/13W-I TOXIC EFFECTS : Liver - changes in liver weight Endocrine - changes in spleen weight Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - transaminases TYPE OF TEST : TCLo - Lowest published toxic concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 9 mg/m3/24H/94D-C TOXIC EFFECTS : Brain and Coverings - recordings from specific areas of CNS Lungs, Thorax, or Respiration - other changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase TYPE OF TEST : TCLo - Lowest published toxic concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 10 mg/m3/24H/60D-I TOXIC EFFECTS : Liver - other changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - phosphatases Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - dehydrogenases TYPE OF TEST : TCLo - Lowest published toxic concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1000 ppm/7H/20W-I TOXIC EFFECTS : Liver - fatty liver degeneration Blood - changes in spleen Related to Chronic Data - death TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 2500 mg/kg/5D-I TOXIC EFFECTS : Liver - other changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other transferases TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1400 mg/kg/4W-I TOXIC EFFECTS : Liver - other changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other transferases TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 28 gm/kg/14D-I TOXIC EFFECTS : Kidney, Ureter, Bladder - other changes Related to Chronic Data - death TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 32500 mg/kg/13W-I TOXIC EFFECTS : Related to Chronic Data - death TYPE OF TEST : TCLo - Lowest published toxic concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 400 ppm/7H/7W-I TOXIC EFFECTS : Liver - fatty liver degeneration Related to Chronic Data - death TYPE OF TEST : TCLo - Lowest published toxic concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Mammal - dog DOSE/DURATION : 1000 ppm/7H/26W-I TOXIC EFFECTS : Liver - fatty liver degeneration Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis) Endocrine - other changes TYPE OF TEST : TCLo - Lowest published toxic concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - guinea pig DOSE/DURATION : 1500 ppm/7H/8W-I TOXIC EFFECTS : Liver - fatty liver degeneration Endocrine - other changes Related to Chronic Data - death TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 130 gm/kg/2Y-I TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Skin and Appendages - tumors TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral DOSE : 1250 mg/kg SEX/DURATION : female 6-15 day(s) after conception TOXIC EFFECTS : Reproductive - Maternal Effects - other effects TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral DOSE : 1950 mg/kg SEX/DURATION : female 7-19 day(s) after conception TOXIC EFFECTS : Reproductive - Maternal Effects - other effects MUTATION DATA TYPE OF TEST : Sister chromatid exchange TEST SYSTEM : Rodent - hamster Lung REFERENCE : ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 9,401,1987 *** REVIEWS *** ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-STEL 508 mg/m3 (110 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 347 mg/m3 (75 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 41,131,1986 IARC Cancer Review:Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 41,131,1986 IARC Cancer Review:Group 3 IMSUDL IARC Monographs, Supplement. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) No.1- 1979- Volume(issue)/page/year: 7,56,1987 TOXICOLOGY REVIEW PAREAQ Pharmacological Reviews. (Williams & Wilkins, 428 E. Preston St., Baltimore, MD 21202) V.1- 1949- Volume(issue)/page/year: 4,1,1952 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 75 ppm (350 mg/m3) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,218,1971 OSHA PEL (Gen Indu):8H TWA 75 ppm (350 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 75 ppm (350 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 75 ppm (350 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 75 ppm (350 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 75 ppm (350 mg/m3);STEL 110 ppm (510 mg/m3) JAN 1993 OEL-AUSTRIA:TWA 75 ppm (350 mg/m3) JAN 1993 OEL-BELGIUM:TWA 75 ppm (347 mg/m3);STEL 110 ppm (509 mg/m3) JAN 1993 OEL-DENMARK:TWA 75 ppm (350 mg/m3) JAN 1993 OEL-FINLAND:TWA 75 ppm (350 mg/m3);STEL 115 ppm (530 mg/m3) JAN 1993 OEL-FRANCE:TWA 75 ppm (350 mg/m3) JAN 1993 OEL-GERMANY:TWA 75 ppm (350 mg/m3) JAN 1993 OEL-HUNGARY:TWA 50 mg/m3;STEL 100 mg/m3;Skin JAN 1993 OEL-THE NETHERLANDS:TWA 75 ppm (350 mg/m3) JAN 1993 OEL-THE PHILIPPINES:TWA 75 ppm (350 mg/m3) JAN 1993 OEL-POLAND:TWA 50 mg/m3 JAN 1993 OEL-RUSSIA:STEL 10 mg/m3 JAN 1993 OEL-SWITZERLAND:TWA 75 ppm (350 mg/m3);STEL 375 ppm (1750 mg/m3) JAN 1993 OEL-TURKEY:TWA 74 ppm (350 mg/m3) JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO PROPYLENE DICHLORIDE-air:CA lowest feasible conc. REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 24390 No. of Facilities: 653 (estimated) No. of Industries: 13 No. of Occupations: 15 No. of Employees: 9601 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 24390 No. of Facilities: 116 (estimated) No. of Industries: 6 No. of Occupations: 15 No. of Employees: 2944 (estimated) No. of Female Employees: 1022 (estimated)

安全

• 符号: GHS02, GHS07
• 信号词: Danger
• 危害声明: H225-H302 + H332
• 警示性声明: P210
• 个人防护装备: Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
• 危害码 (欧洲): F:Flammable
• 风险声明 (欧洲): R11;R20/22
• 安全声明 (欧洲): S16-S24-S45-S36/37-S7
• 危险品运输编码: UN 1279 3/PG 2
• WGK德国: 3
• RTECS号: TX9625000
• 包装等级: II
• 危险类别: 3
• 海关编码: 2903199000

制备

由丙烯与氯气在二氯丙烷中液相低温氯化而得。丙烯高温氯化制氯丙烷时也副产该品。

【制法】　丙烯与氯气在二氯丙烷中液相低温氯化而得。

海关

海关编码	2903199000
中文概述	2903199000 其他无环烃的饱和氯化衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2903199000 other saturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%