173831-50-0

• 常用中文名：(R)-2,2'-双(甲氧基甲氧基)-1,1'-联萘
• 常用英文名：2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
• CAS号：173831-50-0
• 分子式：C₂₄H₂₂O₄
• 分子量：374.429
• 发布时间：2018-06-19 19:13:18
• 更新时间：2024-01-08 19:42:56
• 下载msds

名称

• 中文名: (R)-(+)-2,2’-双(甲氧基甲氧基)-1,1’-联萘
• 英文名: (R)-2,2’-Bis(methoxymethoxy)-1,1'-binaphthyl
• 中文别名: (R)-(+)-2,2'-双(甲氧基甲氧基)-1,1'-联萘; (R)-2,2'-双(甲氧基甲氧基)-1,1'-联萘; (R)-(+)-2,2'-双(甲氧基甲氧基)-1,1'-联萘; (R)-(+)-2,2-双(甲氧甲基)-1,1-二萘酚
• 英文别名: (R)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthyl; (S)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL; 2,2'-Bis(methoxymethoxy)-1,1'-binaphthalene; (R)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthalene; 2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL; (R)-(+)-2,2′-Bis(methoxymethoxy)-1,1′-binaphthyl; MFCD03788935; 1,1'-Binaphthalene, 2,2'-bis(methoxymethoxy)-

物化性质

• 密度: 1.2±0.1 g/cm3
• 沸点: 477.8±45.0 °C at 760 mmHg
• 熔点: 92-96ºC(lit.)
• 分子式: C₂₄H₂₂O₄
• 分子量: 374.429
• 闪点: 126.2±35.6 °C
• 精确质量: 374.151794
• PSA: 36.92000
• LogP: 4.57
• 外观性状: 固体;White to Light yellow powder to crystal
• 蒸汽压: 0.0±1.1 mmHg at 25°C
• 折射率: 1.630
• 储存条件:

  密闭于阴凉干燥环境中

• 稳定性:

  遵照规定使用和储存则不会分解。

• 水溶解性: 可溶于：甲苯
• 分子结构:

  1、 摩尔折射率：112.64

  2、 摩尔体积（m³/mol）：316.6

  3、 等张比容（90.2K）：820.5

  4、 表面张力（dyne/cm）：45.0

  5、 极化率（10^-24cm³）：44.65

• 计算化学:

  1.疏水参数计算参考值（XlogP）:5.9

  2.氢键供体数量:0

  3.氢键受体数量:4

  4.可旋转化学键数量:7

  5.互变异构体数量:无

  6.拓扑分子极性表面积36.9

  7.重原子数量:28

  8.表面电荷:0

  9.复杂度:428

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：无可用

  2. 密度（g/mL,25/4℃）：无可用

  3. 相对蒸汽密度（g/mL,空气=1）：无可用

  4. 熔点（ºC）：92-96

  5. 沸点（ºC,常压）：无可用

  6. 沸点（ºC,5.2kPa）：无可用

  7. 折射率：无可用

  8. 闪点（ºC）：无可用

  9. 比旋光度（º）：无可用

  10. 自燃点或引燃温度（ºC）：无可用

  11. 蒸气压（kPa,25ºC）：无可用

  12. 饱和蒸气压（kPa,60ºC）：无可用

  13. 燃烧热（KJ/mol）：无可用

  14. 临界温度（ºC）：无可用

  15. 临界压力（KPa）：无可用

  16. 油水（辛醇/水）分配系数的对数值：无可用

  17. 爆炸上限（%,V/V）：无可用

  18. 爆炸下限（%,V/V）：无可用

  19. 溶解性：无可用

MSDS

Section 1: Product Identification Chemical Name:(R)-(+)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthyl, 98% CAS Registry Number:173831-50-0 Formula:C24H22O4 EINECS Number:none Chemical Family:organic alcohol Synonym:(R)-(+)-2,2'-Bis-methoxymethoxy-[1,1']binaphthalenyl Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound173831-50-0100%no datano data Section 3: Hazards Identification Emergency Overview:Dust is irritating to the respiratory tract, skin, eyes. May be harmful if swallowed. Primary Routes of Exposure:Ingestion, eyes, inhalation Eye Contact:Causes mild to moderate irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Dust is irritating to the nose, mucous membranes and respiratory tract. Ingestion:No specific information is available on the physiological effects of ingestion. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in Inhalation: breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:dry chemical, carbon dioxide, water or foam. If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes, carbon monoxide and carbon dioxide. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazard. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non-combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Handling and Storage:Store the material in a tightly sealed container in a cool, dry place. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:white powder Molecular Weight:374.43 Melting Point:100-103° Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:not determined Solubility in Water:slightly soluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:oxidizing agents Decomposition Products:carbon monoxide, carbon dioxide and organic fumes. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。

安全

• 符号: GHS05, GHS09
• 信号词: Danger
• 危害声明: H318-H410
• 警示性声明: P273-P280-P305 + P351 + P338-P501
• 个人防护装备: dust mask type N95 (US);Eyeshields;Gloves
• 危害码 (欧洲): Xi,N
• 风险声明 (欧洲): R41
• 安全声明 (欧洲): 26-39-60-61-36/39-25
• 危险品运输编码: UN 3077 9/PG 3

合成路线

107-30-2 602-09-5 ~99% 173831-50-0

文献：Wu, T. Robert; Shen, Lixin; Chong, J. Michael Organic Letters, 2004 , vol. 6, # 16 p. 2701 - 2704

150587-19-2 602-09-5 ~83% 173831-50-0

文献：Lv, Na; Xie, Meilan; Gu, Weibing; Ruan, Huanyang; Qiu, Song; Zhou, Chunshan; Cui, Zheng Organic Letters, 2013 , vol. 15, # 10 p. 2382 - 2385

18531-99-2 107-30-2 ~95% 173831-50-0

文献：Yu, Shanshan; Plunkett, Winston; Kim, Michael; Wu, Elaine; Sabat, Michal; Pu, Lin Journal of Organic Chemistry, 2013 , vol. 78, # 24 p. 12671 - 12680

135-19-3 ~% 173831-50-0

文献：Organic Letters, , vol. 15, # 10 p. 2382 - 2385

上下游产品

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