122-15-6

• 常用中文名：地麦威
• 常用英文名：5,5-dimethyl-3-oxocyclohex-1-enyl dimethylcarbamate
• CAS号：122-15-6
• 分子式：C₁₁H₁₇NO₃
• 分子量：211.25800
• 发布时间：2018-07-17 12:24:48
• 更新时间：2024-01-09 12:15:24

名称

• 中文名: 地麦威
• 英文名: dimetan
• 英文别名: (5,5-dimethyl-3-oxocyclohexen-1-yl) N,N-dimethylcarbamate; DIMETAN; 5,5-Dimethyldihydroresorcinol dimethylcarbamate; dimethyl-carbamic acid-(5,5-dimethyl-3-oxo-cyclohex-1-enyl ester); 5,5-dimethyl-3-oxocyclohex-1-en-1-yl dimethylcarbamate; EINECS 204-525-8; 5,5-dimethyl-3-oxo-1-cyclohexen-1-yl N,N-dimethylcarbamate; ENT 24,728; Dimethyl-carbamidsaeure-(5,5-dimethyl-3-oxo-cyclohex-1-enylester); 5,5-Dimethyl-3-oxocyclohex-1-enyl dimethylcarbamate

物化性质

• 密度: 1.09g/cm3
• 沸点: 292.5ºC at 760mmHg
• 分子式: C₁₁H₁₇NO₃
• 分子量: 211.25800
• 闪点: 130.7ºC
• 精确质量: 211.12100
• PSA: 46.61000
• LogP: 1.95760
• 蒸汽压: 0.00183mmHg at 25°C
• 折射率: 1.499
• 储存条件: 库房通风低温干燥,与食品原料分开储运
• 分子结构:

  1、 摩尔折射率：59.30

  2、 摩尔体积（cm³/mol）：220.7

  3、 等张比容（90.2K）：554.1

  4、 表面张力（dyne/cm）：39.7

  5、 极化率（10-24cm3）：23.51

• 计算化学:

  1.疏水参数计算参考值（XlogP）:1.2

  2.氢键供体数量:0

  3.氢键受体数量:3

  4.可旋转化学键数量:2

  5.互变异构体数量:5

  6.拓扑分子极性表面积46.6

  7.重原子数量:15

  8.表面电荷:0

  9.复杂度:316

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

毒性和生态

CHEMICAL IDENTIFICATION RTECS NUMBER : FA1500000 CHEMICAL NAME : Carbamic acid, dimethyl-, ester with 3-hydroxy-5,5-dimethyl-2-cyclohexen-1-one CAS REGISTRY NUMBER : 122-15-6 BEILSTEIN REFERENCE NO. : 3280184 LAST UPDATED : 199612 DATA ITEMS CITED : 5 MOLECULAR FORMULA : C11-H17-N-O3 MOLECULAR WEIGHT : 211.29 WISWESSER LINE NOTATION : L6V BUTJ COVN1&1 E1 E1 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 120 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : WRPCA2 World Review of Pest Control. (London, UK) V.1-10, 1962-71. Discontinued. Volume(issue)/page/year: 9,119,1970 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Unreported SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 150 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971 Volume(issue)/page/year: -,196,1971 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 90 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 85DPAN "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel," Perkow, W., Berlin, Verlag Paul Parey, 1971-1976 Volume(issue)/page/year: -,-,1971/1976 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Unreported SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 150 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GUCHAZ Guide to the Chemicals Used in Crop Protection. (Information Canada, 171 Slater St., Ottawa, Ont., Canada) Volume(issue)/page/year: 6,206,1973 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Mammal - dog DOSE/DURATION : 50 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 85GYAV "Pflanzenschutz-und Schaedlingsbekaempfungsmittel: Abriss einer Toxikologie und Therapie von Vergiftungen," 2nd ed., Klimmer, O.R., Hattingen, Fed. Rep. Ger., Hundt-Verlag, 1971 Volume(issue)/page/year: -,66,1971

安全

• 危害码 (欧洲): T: Toxic;
• 风险声明 (欧洲): 25
• 安全声明 (欧洲): S45;S36/S37
• 海关编码: 2922499916

合成路线

126-81-8 68-12-2 ~40% 122-15-6

文献：Saberi, Dariush; Heydari, Akbar Tetrahedron Letters, 2013 , vol. 54, # 32 p. 4178 - 4180

126-81-8 79-44-7 ~% 122-15-6

文献：Geigy A.G. Patent: DE826133 , 1949 ; DRP/DRBP Org.Chem.

上下游产品

上游产品  3
126-81-8 68-12-2 79-44-7
下游产品  0

海关

海关编码	2924199090
中文概述	2924199090. 其他无环酰胺（包括无环氨基甲酸酯)(包括其衍生物及盐）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途, 包装
Summary	2924199090. other acyclic amides (including acyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%