前往化源商城
入驻化源商城

品牌现货直购
供应商:我要出现这里






查看所有供应商和价格请点击:

7440-50-8生产厂家

7440-50-8价格

7440-50-8

7440-50-8结构式
7440-50-8结构式
  • 常用中文名:铜粉
  • 常用英文名:Copper
  • CAS号:7440-50-8
  • 分子式:Cu
  • 分子量:63.545
  • 相关类别: 无机化工 单质
  • 发布时间:2018-02-03 08:00:00
  • 更新时间:2024-01-02 13:02:23
  • 【用途一】
    用作冶炼、电解铜的原料
    【用途二】
    用于粉末冶金零件、金刚石锯片、摩擦材料、电碳制品和化工触媒等
    【用途三】
    主要用于制导电器材和合金(青铜、黄铜、白铜等)
    【用途四】
    用作分析试剂、催化剂、还原剂
    【用途五】
    主要用于炼铜工业的原料
    【用途六】
    用作普通试剂、催化剂及还原剂
    【用途七】
    用作教学试剂
    【用途八】
    为电子工业用材料,用作高纯分析试剂。
    【用途九】
    供制造化学用具、电力用具、建筑材料和其他工业装置及用具。用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。校准仪器和装置;评价方法;工作标准;质量保证/质量控制;其他。
    【用途十】
    试剂、合金、电镀。

化源商城直购

中文名
英文名 copper atom
中文别名 线状铜
铜离子
铜粉/铜片/高纯铜/纳米铜粉
电解铜粉
铜标液,铜标样
超细球形铜粉
水质铜标样
铜箔
铜粉
英文别名 MFCD00239961
Cu(II)
m3s
cda122
cda110
m3r
copper(2+) ion
cda102
cda101
copper(II) cation
Cu++
Copper (II)
Copper(2+)
COPPER (II) ION
EINECS 231-159-6
cum3
ce1110
copper(II)
Cu+2
Copper
密度 8.92
沸点 2580 °C
熔点 1083.4 °C(lit.)
分子式 Cu
分子量 63.545
闪点 -23 °C
精确质量 62.928505
外观性状 wire
储存条件

储存于阴凉、通风的库房。远离火种、热源。应与氧化剂、酸类、卤素分开存放,切忌混储。配备相应品种和数量的消防器材。储区应备有合适的材料收容泄漏物。

稳定性 1.外围电子排布3d 104s 1,位于第四周期IB族。原子半径127.8皮米,Cu2+半径72皮米,第一电离能为750kJ/mol,电负性1.9,常见氧化数+1、+2。有良好的延展性和传热、导电性。化学性质不很活泼,在干燥空气中稳定,在含有二氧化碳的潮湿空气中易生成碱式碳酸铜,俗称铜绿(Cu 2(OH) 2CO 3)。 2.应避免与强酸、强氧化剂、卤素接触。 3.溶于硝酸,热浓硫酸,极缓慢溶于盐酸、氨水、稀硫酸,亦溶于醋酸和其他有机酸,不溶于冷水和热水。露置空气中变暗,在潮湿空气中表面逐渐形成绿色碱式碳酸盐。 4.生产人员要穿防护工作服,戴口罩、防尘眼镜,生产设备要密闭,车间通风良好,工作下班后要洗淋浴。金属铜易溶于硝酸等氧化性酸,若无氧化剂或适宜配位试剂存在,则不溶于非氧化性酸。遇碱易被侵蚀。在干燥空气中稳定,但在潮湿空气中表面生成绿色的碱式碳酸铜。
水溶解性 insoluble
计算化学

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:0

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:1

8.表面电荷:0

9.复杂度:0

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

更多

1. 性状:略带红色的金属(面心立方晶系),富延展性。是热、电的良导体(仅次于银)。

2. 密度(g/mL,20℃)8.94

3. 相对蒸汽密度(g/mL,空气=1):未确定

4. 熔点(ºC):1083.4

5. 沸点(ºC,常压):2595

6. 沸点(ºC,5.2kPa):未确定

7. 折射率:未确定

8. 闪点(ºC):未确定

9. 比旋光度(º):未确定

10. 自燃点或引燃温度(ºC):700(粉云)

11. 蒸气压(mmHg, ºC):未确定

12. 饱和蒸气压(kPa, ºC):未确定

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC):未确定

15. 临界压力(KPa):未确定

16. 油水(辛醇/水)分配系数的对数值:未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V):未确定

19. 溶解性:不溶于稀盐酸和稀硫酸,溶于硝酸和热浓硫酸,能溶于氨水和氰化钾溶液并生成配合物。

国标编号:
CAS: 7440-50-8
中文名称:
英文名称: Copper
别 名:
分子式: Cu
分子量: 63.55
熔 点: 1083℃
密 度: 相对密度(水=1)8.92
蒸汽压:
溶解性: 不溶于水,溶于碱、盐酸、硫酸
稳定性: 稳定
外观与性状: 带有红色光泽的金属
危险标记:
用 途: 供制造化学用具、电力用具、建筑材料和其他工业装置及用具

0.005
I类
0.05
II类

2.对环境的影响:

一、健康危害

侵入途径:吸入、食入。健康危害:动物吸入铜的粉尘和烟雾,可引起呼吸道刺激症状,发生支气管炎或支气管肺炎,甚至肺水肿。长期接触铜尘的工人常发生接触性皮炎和鼻眼的刺激症状,引起烟痛、鼻塞、鼻炎、咳嗽等症状。铜熔炼工人可发生铜铸造热。长期吸入尚可引起肺部纤维组织增生。铜的毒性较小,但铜过剩出可引起中毒。铜盐的毒性以CuAc2和CuSO4较大,经口服即使微量也会引起急性中毒,发生流涎、恶心、呕吐、阵发性腹痛,严重者可有头痛、心跳迟缓、呼吸困难甚至虚脱,也可引起中枢神经系统的损害。

二、毒理学资料及环境行为

急性毒性:属微毒类。铜的污染来源为冶金、电镀、催化、仪表、合金和化工等的废水和废渣。自然界的铜化合物以一价或二价状态存在。一价铜多存在于矿物中,有氧化亚铜形式和硫化亚铜形式。环境中的铜主要以二价铜离子存在,二价铜可和无机配位体NH3、CO32-、HCO3-、SO42-形成络合物。

迁移转化:利用含铜废水灌溉农田或施用含铜污泥,铜可积蓄在土壤中。随水进入到土壤中的铜可被土壤吸持。土壤中的腐殖酸、富里酸含 有羧基、酚基、羰基等含氧基团,能与铜形成螯合物而固定铜。

危险特性:其粉体遇高温、明火能燃烧。 燃烧(分解)产物:氧化铜。


3.现场应急监测方法:

试纸法;速测管法;化学测试组法《突发性环境污染事故应急监测与处理处置技术》万本太主编便携式比色计(意大利哈纳公司产品)


4.实验室监测方法:

原子吸收法(GB7475-87,水质)原子吸收法(GB/T15555.2-95,固体废物浸出液)原子吸收法《空气和废气监测分析方法》国家环保局编


5.环境标准:
中国(GB5749-85) 生活饮用水水质标准 1.0mg/L
中国(GB5048-92) 农田灌溉水持标准 旱作 1.0mg/L(总铜)
中国(GB11607-89) 渔业水质标准 0.01mg/L
中国(GB15618-1995) 土壤环境质量标准(mg/kg) 一级35;二级50~100;三级400(农田等)
二级150~200;三级400(果园)
中国(4284-84) 农用污泥污染物控制标准 250mg/kg干污泥(酸性土壤)
500mg/kg干污泥(中、碱性土壤)
中国(GB5058.3-1996) 固体废弃物浸出毒性鉴别标准值 50mg/L

6.应急处理处置方法:

一、泄漏应急处理

隔离泄漏污染区,周围设警告标志,切断火源。应急处理人员戴好防毒面具,穿一般消防防护服。避免扬尘,使用无火花工具收集于干燥净洁有盖的容器中,转移回收。当水体受到污染时,可采用加入纯碱中和,使铜以碱式碳酸铜形式沉淀而从水中转入污泥中,而污泥再做进一步的无害化处理。对于受铜污染的土壤,可采取排土、土层改良、深耕、施加石灰质矿物及磷酸钙等措施治理。

二、防护措施

一般不需特殊防护,但需防止烟尘危害。

三、急救措施

皮肤接触:脱去污染的衣着,用肥皂水及清水彻底冲洗。就医。眼睛接触:立即翻开上下眼睑,用流动清水或生理盐水冲洗至少15分钟。就医。吸入:迅速脱离现场至空气新鲜处。就医。食入:误服者立即漱口,饮牛奶或蛋清。就医。

灭火方法:干粉、砂土。禁止用水。

毒理学数据:

对皮肤有刺激作用。粉尘刺激眼睛,并引起角膜溃疡。

生态学数据:

水中嗅觉阈浓度: 水中浓度为 3-5mg/L,使水变味。

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GL5325000
CHEMICAL NAME :
Copper
CAS REGISTRY NUMBER :
7440-50-8
LAST UPDATED :
199712
DATA ITEMS CITED :
78
MOLECULAR FORMULA :
Cu
MOLECULAR WEIGHT :
63.54

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human
DOSE/DURATION :
120 ug/kg
TOXIC EFFECTS :
Gastrointestinal - nausea or vomiting
REFERENCE :
PHRPA6 Public Health Reports. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1878- Volume(issue)/page/year: 73,910,1958
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
3500 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985. Volume(issue)/page/year: 2A,1623,1981 ** TUMORIGENIC DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intrapleural
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
100 mg/kg
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Lungs, Thorax, or Respiration - fibrosis, focal (pneumoconiosis) Lungs, Thorax, or Respiration - tumors
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 41,836,1980 ** REPRODUCTIVE DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
152 mg/kg
SEX/DURATION :
female 22 week(s) pre-mating
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) Reproductive - Specific Developmental Abnormalities - Central Nervous System
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 45(3),8,1980
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
1520 ug/kg
SEX/DURATION :
female 22 week(s) pre-mating
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 45(3),8,1980
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
1210 ug/kg
SEX/DURATION :
female 35 week(s) pre-mating
TOXIC EFFECTS :
Reproductive - Fertility - pre-implantation mortality (e.g. reduction in number of implants per female; total number of implants per corpora lutea) Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants)
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 42(8),30,1977
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intrauterine
DOSE :
250 ug/kg
SEX/DURATION :
female 1 day(s) pre-mating
REFERENCE :
IJEBA6 Indian Journal of Experimental Biology. (Publications & Information Directorate, CSIR, Hillside Rd., New Delhi 110 012, India) V.1- 1963- Volume(issue)/page/year: 19,1124,1981 *** REVIEWS *** ACGIH TLV-TWA 1 mg(Cu)/m3, dust, mist DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 0.2 mg(Cu)/m3, fume DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 TOXICOLOGY REVIEW TRBMAV Texas Reports on Biology and Medicine. (Galveston, TX) V.1-41(2), 1943-81/82. Discontinued. Volume(issue)/page/year: 33,85,1975 TOXICOLOGY REVIEW QURBAW Quarterly Reviews of Biophysics. (Cambridge Univ. Press, The Edinburgh Bldg., Shaftesbury Rd., Cambridge CB2 2RU, UK) V.1- 1968- Volume(issue)/page/year: 7,75,1974 TOXICOLOGY REVIEW JAVMA4 Journal of the American Veterinary Medical Association. (American Veterinary Medical Assoc., 930 N. Meacham Rd., Schaumburg, IL 60196) V.48- 1915- Volume(issue)/page/year: 164,277,1974 TOXICOLOGY REVIEW IJMDAI Israel Journal of Medical Sciences. (POB 1435, Jerusalem 91013, Israel) V.1- 1965- Volume(issue)/page/year: 10,416,1974 TOXICOLOGY REVIEW KOTTAM Kogai to Taisaku. Journal of Environmental Pollution Control. (Kogai Taisaku Gijutsu Dokokai, Shuwa-Akasaka Bldg., 9-1-244, Akasaka, Minato-ku, Tokyo 107, Japan) V.1- 1965- Volume(issue)/page/year: 11,1300,1975 TOXICOLOGY REVIEW FOREAE Food Research. (Champaign, IL) V.1-25, 1936-60. For publisher information, see JFDSAZ. Volume(issue)/page/year: 7,313,1942 TOXICOLOGY REVIEW MIBUBI Mikrobiyoloji Bulteni. Bulletin of Microbiology. (c/o Dr. A. Tevfik Cenqiz, Ankara Universitesi Tip Fakultesi Mikrobiyoloji Ana Bilim Dah, Ankara, Turkey) V.1- 1967- Volume(issue)/page/year: 9,321,1975 TOXICOLOGY REVIEW PEXTAR Progress in Experimental Tumor Research. (S. Karger AG, Postfach CH-4009 Basel, Switzerland) V.1- 1960- Volume(issue)/page/year: 12,102,1969 TOXICOLOGY REVIEW 85DHAX "Medical and Biologic Effects of Environmental Pollutants Series," Washington, DC, National Academy of Sciences, 1972-77 Volume(issue)/page/year: Cu,41,1977 TOXICOLOGY REVIEW AMTODM Advances in Modern Toxicology. (John Wiley & Sons, Inc., 605 Third Ave., New York, NY 10016) V.1, 1976-79. Discontinued. Volume(issue)/page/year: 3,209,1977 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 MSHA STANDARD-air:TWA 0.1 mg/m3 (fume,dusts & mists) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,59,1971 OSHA PEL (Gen Indu):8H TWA 0.1 mg(Cu)/m3, fume CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Gen Indu):8H TWA 1 mg(Cu)/m3, dusts and mists CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.1 mg(Cu)/m3, fume CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Construc):8H TWA 1 mg(Cu)/m3, dusts and mists CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.1 mg(Cu)/m3, fume CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Shipyard):8H TWA 1 mg(Cu)/m3, dusts and mists CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.1 mg/m3, fume CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 OSHA PEL (Fed Cont):8H TWA 1 mg/m3, dusts and mists CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.1 mg/m3 (fume) JAN 1993 OEL-AUSTRALIA:TWA 0.2 mg/m3 (fume) JAN 1993 OEL-AUSTRALIA:TWA 1 mg/m3 (dust) JAN 1993 OEL-BELGIUM:TWA 0.2 mg/m3 (fume) JAN 1993 OEL-BELGIUM:TWA 1 mg/m3 (dust) JAN 1993 OEL-DENMARK:TWA 0.1 mg/m3 (fume) JAN 1993 OEL-DENMARK:TWA 1 mg/m3 (dust) JAN 1993 OEL-FINLAND:TWA 0.2 mg/m3 (fume) JAN 1993 OEL-FINLAND:TWA 1 mg/m3 (dust) JAN 1993 OEL-FRANCE:TWA 0.2 mg/m3 (fume) JAN 1993 OEL-FRANCE:TWA 1 mg/m3;STEL 2 mg/m3 (dust) JAN 1993 OEL-GERMANY:TWA 0.1 mg/m3 (fume) JAN 1993 OEL-GERMANY:TWA 1 mg/m3 (dust) JAN 1993 OEL-HUNGARY:TWA 0.2 mg/m3;STEL 0.4 mg/m3 (dust) JAN 1993 OEL-INDIA:TWA 0.2 mg/m3 (fume) JAN 1993 OEL-THE NETHERLANDS:TWA 02 mg/m3 (fume) JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg/m3 (dust) JAN 1993 OEL-THE PHILIPPINES:TWA 1.0 mg/m3 (fume) JAN 1993 OEL-POLAND:TWA 0.1 mg/m3 (fume) JAN 1993 OEL-RUSSIA:STEL 0.5 ppm (1 mg/m3) (dust) JAN 1993 OEL-SWEDEN:TWA 0.2 mg/m3 (resp. dust) JAN 1993 OEL-SWEDEN:TWA 0.2 mg/m3 (fume) JAN 1993 OEL-SWEDEN:TWA 1 mg/m3 (total dust) JAN 1993 OEL-SWITZERLAND:TWA 0.1 mg/m3;STEL 0.2 mg/m3 (fume) JAN 1993 OEL-SWITZERLAND:TWA 1 mg/m3;STEL 1 mg/m3 JAN 1993 OEL-THAILAND:TWA 0.1 mg/m3 (fume) JAN 1993 OEL-THAILAND:TWA 1 mg/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.2 mg/m3 (fume) JAN 1993 OEL-UNITED KINGDOM:TWA 1 mg/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO COPPER, dusts and mists-air:10H TWA 1 mg/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO COPPER, fume-air:10H TWA 0.1 mg/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M2276 No. of Facilities: 1213 (estimated) No. of Industries: 27 No. of Occupations: 35 No. of Employees: 24737 (estimated) NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 20115 No. of Facilities: 12177 (estimated) No. of Industries: 176 No. of Occupations: 105 No. of Employees: 224406 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5915 No. of Facilities: 162 (estimated) No. of Industries: 5 No. of Occupations: 5 No. of Employees: 11889 (estimated) No. of Female Employees: 421 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5983 No. of Facilities: 4558 (estimated) No. of Industries: 51 No. of Occupations: 45 No. of Employees: 53282 (estimated) No. of Female Employees: 8758 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X6807 No. of Facilities: 16 (estimated) No. of Industries: 2 No. of Occupations: 2 No. of Employees: 625 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X8588 No. of Facilities: 204 (estimated) No. of Industries: 3 No. of Occupations: 7 No. of Employees: 9443 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 20115 No. of Facilities: 59839 (estimated) No. of Industries: 296 No. of Occupations: 158 No. of Employees: 920449 (estimated) No. of Female Employees: 72821 (estimated)

符号 GHS02 GHS09
GHS02, GHS09
信号词 Danger
危害声明 H228-H410
警示性声明 P210-P273
个人防护装备 Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
危害码 (欧洲) F:Flammable
风险声明 (欧洲) R11
安全声明 (欧洲) S5-S26-S16-S61-S62-S36/37
危险品运输编码 UN 3089 4.1/PG 2
WGK德国 3
RTECS号 GL5325000
包装等级 III
危险类别 4.1
海关编码 7402000090

1.电解法以金属铜为原料,溶解于浓硫酸。配成电解液组成为:含Cu52.3 g/L、H2SO4约200 g/L,电解液温度58.5℃,槽电压0.33 V,阴极电流密度1.82 A/cm2。经电解精炼,制得高纯铜粉成品。

2.将硝酸铜进行重结晶、干燥,并在800~850℃下灼烧以除去氮的氧化物。然后,把制得的氧化铜放入管式炉内的瓷皿中,并在250~300℃的条件下用氢气进行还原。用此法制得的铜呈粉红色粉末状,在较高温度(800~900℃)时,铜可黏结起来,而得到海绵状物质。

3.向硫酸铜的浓溶液中放入过量的锌棒、锌块或锌粉,通过置换反应使铜析出。当溶液褪色后,回收未起反应的锌,同时用加热到60~70℃的稀硫酸或稀盐酸浸泡含锌残渣的沉淀铜。在锌被完全溶解后,将沉淀铜转移至过滤器上,然后用稀盐酸、水洗涤,最后用乙醇洗涤,并在40~50℃的条件下将铜烘干。这一制法中也可用铁或铝来替代锌。

4.粉末状氧化铜,在管式炉中于135~150℃下通氢气还原,直至黑色氧化铜转变为玫瑰色铜粉为止。
停止加热,继续通氢气冷却,即可制得成品。若要制取在空气中相当稳定的粘结体,还原温度要控制在500~520℃

7440-50-8 preparation

5.先将工业铜用稀硝酸 ( 或稀硫酸)和蒸馏水洗去表面污物,然后用硝酸 ( 或硫酸)溶解,作为电解液,采用较纯铜片作为阴极,电流密度控制在120A/m2,电解产物根据产品要求,可以经水洗、酸洗、脱水、干燥。

海关编码 7402000090