38838-06-1

• 常用中文名：(3aS,4S,6R,6aR)-4-(碘甲基)-6-甲氧基-2,2-二甲基四氢呋喃并[3,4-d][1,3]二氧戊环
• 常用英文名：(3aS,4S,6R,6aR)-4-(iodomethyl)-6-methoxy-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxole
• CAS号：38838-06-1
• 分子式：C₉H₁₅IO₄
• 分子量：314.117
• 发布时间：2016-09-10 23:07:12
• 更新时间：2024-01-03 19:09:54

名称

• 中文名: (3aS,4S,6R,6aR)-4-(碘甲基)-6-甲氧基-2,2-二甲基四氢呋喃并[3,4-d][1,3]二噁戊环
• 英文名: (3aR,4R,6S,6aS)-6-(iodomethyl)-4-methoxy-2,2-dimethyl-3a,4,6,6a-tetrahydrofuro[3,4-d][1,3]dioxole
• 英文别名: Methyl 5-deoxy-5-iodo-2,3-O-isopropylidene-β-D-ribofuranoside; (2R,3R,4S,5S)-2-methoxy-3,4-O-isopropylidene-3,4-dihydroxy-5-iodomethyltetrahydrofuran; β-D-Ribofuranoside, methyl 5-deoxy-5-iodo-2,3-O-(1-methylethylidene)-; (3aS,4S,6R,6aR)-4-(Iodomethyl)-6-methoxy-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxole; AAEYGFITCYWQDV-WCTZXXKLSA; InChI=1/C9H15IO4/c1-9(2)13-6-5(4-10)12-8(11-3)7(6)14-9/h5-8H,4H2,1-3H3/t5-,6-,7-,8-/m1/s1; (2R,3R,4S,5S)-2-methoxy-3,4-O-isopropylidene-5-iodomethyltetrahydrofuran; (2R,3R,4S,5S)-2-methoxy-3,4-dihydroxy-3,4-O-isopropylidene-5-iodomethyltetrahydrofuran; (2R,3R,4R,5S)-2-methoxy-3,4-O-isopropylidene-5-iodomethyl-tetrahydrofuran

物化性质

• 密度: 1.7±0.1 g/cm3
• 沸点: 316.4±42.0 °C at 760 mmHg
• 分子式: C₉H₁₅IO₄
• 分子量: 314.117
• 闪点: 145.2±27.9 °C
• 精确质量: 314.001495
• PSA: 36.92000
• LogP: 2.09
• 蒸汽压: 0.0±0.6 mmHg at 25°C
• 折射率: 1.545
• 储存条件: 2-8°C，避光保存，惰性气氛

合成路线

67-56-1 532-20-7 67-64-1 ~65% 38838-06-1

文献：Davies, Stephen G.; Foster, Emma M.; Lee, James A.; Roberts, Paul M.; Thomson, James E. Tetrahedron Asymmetry, 2014 , vol. 25, # 6-7 p. 534 - 546

4099-85-8 ~99% 38838-06-1

文献：Classon, Bjoern; Liu, Zhengchun Journal of Organic Chemistry, 1988 , vol. 53, # 26 p. 6126 - 6130

4137-56-8 ~99% 38838-06-1

文献：Kobori, Yoshihiro; Myles, David C.; Whitesides, George M. Journal of Organic Chemistry, 1992 , vol. 57, # 22 p. 5899 - 5907

85558-05-0 ~70% 38838-06-1

文献：Hanessian, Stephen; Leblanc, Yves; Lavallee, Pierre Tetrahedron Letters, 1982 , vol. 23, # 43 p. 4411 - 4414

74925-17-0 ~92% 38838-06-1

文献：Binkley; Ambrose; Hehemann Journal of Organic Chemistry, 1980 , vol. 45, # 22 p. 4387 - 4391

50610-99-6 ~% 38838-06-1

文献：Kissman; Baker Journal of the American Chemical Society, 1957 , vol. 79, p. 5534,5537

36468-53-8 ~% 38838-06-1

文献：Devkota, Kanchan; Lohse, Brian; Liu, Qing; Wang, Ming-Wei; Staerk, Dan; Berthelsen, Jens; Clausen, Rasmus Praetorius ACS Medicinal Chemistry Letters, 2014 , vol. 5, # 4 p. 293 - 297

532-20-7 ~% 38838-06-1

文献：Abdel-Rahman, Adel A.-H.; Abdel-Megied, Ahmed E.-S.; Goda, Adel E.-S.; Zeid, Ibrahim F.; El Ashry, El Sayed H. Nucleosides, Nucleotides and Nucleic Acids, 2003 , vol. 22, # 11 p. 2027 - 2038

50-69-1 ~% 38838-06-1

文献：Kissman; Baker Journal of the American Chemical Society, 1957 , vol. 79, p. 5534,5537

上下游产品

上游产品  8
67-56-1 67-64-1 4099-85-8 4137-56-8
85558-05-0 50-69-1 50610-99-6 36468-53-8
下游产品  4
4099-85-8 23202-81-5 13039-75-3 155899-66-4