| 中文名 | 氘代三正丁基锡 |
|---|---|
| 英文名 | tributyl(deuterio)stannane |
| 英文别名 |
Tributyltin deuteride
Tributylhydro-d-tin Tributyldeuteriostannane Tributyl-stannane-d MFCD00064886 Tributylstannyl Deuteride EINECS 211-704-4 tri-n-butyldeuteriostannane Tri-n-butyltin deuteride |
| 密度 | 1.082 g/mL at 25ºC(lit.) |
|---|---|
| 沸点 | 65ºC (0.6 mmHg) |
| 分子式 | C12H27DSn |
| 分子量 | 292.05800 |
| 闪点 | 104 °F |
| 精确质量 | 293.12800 |
| LogP | 4.61380 |
| 折射率 | n20/D 1.472(lit.) |
| 储存条件 | 避光，阴凉干燥处，密封保存 |
| 稳定性 | 常温常压下稳定，无色液体 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:0 4.可旋转化学键数量:9 5.互变异构体数量:无 6.拓扑分子极性表面积0 7.重原子数量:13 8.表面电荷:0 9.复杂度:72.1 10.同位素原子数量:1 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：无色液体 2. 密度（g/mL, 25 ℃ ）：1.082 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：79-81 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC，0.6mmHg）：65 7. 折射率：1.472 8. 闪点（ºF）：104 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（20ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
Synonym:Tri-n-butyltin deuteride Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 10 21 25 36/38 48/23/25 50/53 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Flammable. Harmful in contact with skin. Toxic if swallowed. Irritating to eyes and skin. Toxic : danger of serious damage to health by prolonged exposure through inhalation and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Moisture sensitive.Air sensitive. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. Causes respiratory tract irritation. Chronic: The critical effect of tributyltin compounds in rats is on the immune system (ACGIH 7th Edition Documentation of the TLVs). Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Antidote: None reported. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air. Vapors can travel to a source of ignition and flash back. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT get water inside containers. Do NOT use straight streams of water. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Use only with adequate ventilation. Keep away from heat, sparks and flame. Avoid breathing vapor or mist. Storage: Keep away from sources of ignition. Flammables-area. Keep refrigerated. (Store below 4C/39F.) Do not expose to air. Store protected from moisture. Store under an inert atmosphere. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Limits CAS# 6180-99-0: United Kingdom, WEL - TWA: (listed as tin organic compounds): 0.1 mg/m3 TWA (except cyhexatin, as Sn) United Kingdom, WEL - STEL: (listed as tin organic compounds): 0. mg/m3 STEL (except cyhexatin, as Sn) United States OSHA: 0.1 mg/m3 TWA (as Sn) (listed under Tin orga compounds). Belgium - TWA: (listed as tin organic compounds): 0.1 mg/m3 VLE ( Sn) Belgium - STEL: (listed as tin organic compounds): 0.2 mg/m3 VLE Sn) France - VME: (listed as tin organic compounds): 0.1 mg/m3 VME (a Sn) France - VLE: (listed as tin organic compounds): 0.2 mg/m3 VLE (a Sn) Germany: (listed as tin organic compounds): 0.1 mg/m3 VME (as Sn) Germany: (listed as tin organic compounds): Skin absorber Malaysia: (listed as tin organic compounds): 0.1 mg/m3 TWA (as Sn Netherlands: (listed as tin organic compounds): 0.2 mg/m3 STEL (a Sn) Netherlands: (listed as tin organic compounds): 0.1 mg/m3 MAC (as Spain: (listed as tin organic compounds): 0.1 mg/m3 VLA-ED (as Sn Spain: (listed as tin organic compounds): 0.2 mg/m3 VLA-EC (as Sn Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: colorless to very faint yellow Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 65 deg C @ .60mm Hg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: 39 deg C ( 102.20 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 1.08 g/cm3 Molecular Formula: C12H27DSn Molecular Weight: 292.06 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stability unknown. Conditions to Avoid: Ignition sources, moisture, exposure to air, excess heat. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, tin/tin oxides. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 6180-99-0 unlisted. LD50/LC50: Not available. Carcinogenicity: Tributyltin deuteride - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Other No information available. Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.* Hazard Class: 3 (6.1) UN Number: 1992 Packing Group: III IMO Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S. Hazard Class: 3.3 (6.1) UN Number: 1992 Packing Group: III RID/ADR Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S. Hazard Class: 3 (6.1) UN Number: 1992 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: T N Risk Phrases: R 10 Flammable. R 21 Harmful in contact with skin. R 25 Toxic if swallowed. R 36/38 Irritating to eyes and skin. R 48/23/25 Toxic : danger of serious damage to health by prolonged exposure through inhalation and if swallowed. R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety Phrases: S 35 This material and its container must be disposed of in a safe way. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S 60 This material and its container must be disposed of as hazardous waste. S 61 Avoid release to the environment. Refer to special instructions/safety data sheets. WGK (Water Danger/Protection) CAS# 6180-99-0: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 6180-99-0 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 6180-99-0 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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毒理学数据: 主要的刺激性影响： 在皮肤上面：刺激皮肤和粘膜 在眼睛上面：刺激的影响 致敏作用：没有已知的敏化现象 生态学数据: 对水是危害的，即使是小量的产品深入地下，也会对饮用水造成危害 对水中的有机物有危害
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| 危害码 (欧洲) | T,N |
|---|---|
| 风险声明 (欧洲) | 21-25-36/38-48/23/25-50/53 |
| 安全声明 (欧洲) | 35-36/37/39-45-60-61 |
| 危险品运输编码 | UN 1993 3/PG 3 |
| WGK德国 | 3 |
| 包装等级 | II |
| 危险类别 | 6.1 |
| 海关编码 | 28459000 |
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| 文献：Tetrahedron Letters, , vol. 50, # 12 p. 1340 - 1344 |
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| 文献：Journal of Organometallic Chemistry, , vol. 32, p. C72 |
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| 文献：Journal of Organometallic Chemistry, , vol. 234, # 1 p. 41 - 62 |
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