22464-99-9

• 常用中文名：2-乙基己酸氧锆(IV)盐
• 常用英文名：Zirconium(2+) bis(2-ethylhexanoate)
• CAS号：22464-99-9
• 分子式：C₃₂H₆₀O₈Zr
• 分子量：377.631
• 相关类别： 有机原料 有机金属类化合物 有机锆
• 发布时间：2018-08-16 19:33:46
• 更新时间：2024-01-02 13:23:06
• 【用途一】
  用作油墨催干剂及塑料增塑剂

名称

• 中文名: 异辛酸锆
• 英文名: 2-ethylhexanoate,zirconium(2+)
• 中文别名: 2-乙基己酸锆
• 英文别名: Hexanoic acid, 2-ethyl-, zirconium(2+) salt (2:1); Zirconium(2+) bis(2-ethylhexanoate); MFCD00072684; Hexanoic acid,2-ethyl-,zirconium salt; EINECS 245-018-1

物化性质

• 密度: 1,27 g/cm3
• 沸点: 167-178 °C/760 mmHg
• 分子式: C₃₂H₆₀O₈Zr
• 分子量: 377.631
• 闪点: 65°C
• 精确质量: 376.119110
• PSA: 105.20000
• LogP: 9.41760
• 外观性状: NA
• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:4

  4.可旋转化学键数量:8

  5.互变异构体数量:无

  6.拓扑分子极性表面积80.3

  7.重原子数量:21

  8.表面电荷:0

  9.复杂度:93.9

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:2

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:3

• 更多:

  1.性状：未确定

  2.密度（g/mL,25/4℃）：1.27

  3.相对蒸汽密度（g/mL,空气=1）：未确定

  4.熔点（ºC）：未确定

  5.沸点（ºC,常压）：未确定

  6.沸点（ºC,5.2kPa）：未确定

  7.折射率：未确定

  8.闪点（ºC）： 65

  9.比旋光度（º）：未确定

  10.自燃点或引燃温度（ºC）：未确定

  11.蒸气压（kPa,25ºC）：未确定

  12.饱和蒸气压（kPa,60ºC）：未确定

  13.燃烧热（KJ/mol）：未确定

  14.临界温度（ºC）：未确定

  15.临界压力（KPa）：未确定

  16.油水（辛醇/水）分配系数的对数值：未确定

  17.爆炸上限（%,V/V）：未确定

  18.爆炸下限（%,V/V）：未确定

  19.溶解性：未确定

MSDS

Section 1: Product Identification Chemical Name:Zirconyl 2-ethylhexanoate in mineral spirits (approx. 6% Zr) CAS Registry Number:22464-99-9 Formula:Zr[OOCCH(C2H5)C4H9]4 EINECS Number:none Chemical Family:metal carboxylate Synonym:2-ethylhexanoic acid, zirconium salt, in petroleum spirits, paraffin oil. Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound22464-99-920%5mg/m3 (as Zr)5mg/m3 (as Zr) mineral spirits64475-85-080%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. May be harmful if swallowed or inhaled. Primary Routes of Exposure:Ingestion, eyes, inhalation, skin Eye Contact:Causes mild irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Vapor is irritating to the nose, mucous membranes and respiratory tract, and cause drowsiness. Ingestion:Ingestion may cause gastrointestinal distress, dizziness, weakness, and drowsiness. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Chronic Health Affects:No data available NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical Skin Exposure: assistance if irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Do not Ingestion: induce vomiting unless directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:104°F Autoignition Temperature:445°F (mineral spi Explosion Limits:0.7-8.9% in air (mineral s Extinguishing Medium:carbon dioxide, dry powder or foam If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained Special Fire Fighting Procedures: breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes. Decomposion Products: Unusual Fire or Explosion Hazards: Flammable material. No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Eliminate all ignition sources. Small spills may be adsorbed into diatomaceous earth, sand, or other suitable Spill and Leak Procedures: adsorbent, and swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a tightly sealed container and store in a cool place. Handle in a well ventilated area. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear appropriate chemical resistant gloves and protective clothing. Ventilation:Material may form a vapor. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a vapor. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:liq. Molecular Weight:not applicable Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:organic odor Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable liquid Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:Keep away from heat and ignition sources including open flame and electrostatic discharge. Incompatibility:oxidizing agents Decomposition Products:Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates. SECTION 11: Toxicological Information No information available in the RTECS files for title compound. For Mineral Spirits: Oral (rat); LD50:>34600 RTECS Data:mg/Kg; Inhalation (rat) LC50: >21400 mg/m3/4H; Intraperitoneal (rat) LDLo: 8560 mg/kg; Skin (rabbit) LD50: 15400 mg/kg. Carcinogenic Effects:No data available Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Flammable liquids, N.O.S. Hazard Class (CFR):3 Additional Hazard Class (CFR):NA Packaging Group (CFR):III UN ID Number (CFR):UN# 1993 Shipping Name (IATA):Flammable liquid, N.O.S. Hazard Class (IATA):3 Additional Hazard Class (IATA):NA Packaging Group (IATA):III UN ID Number (IATA):UN# 1993 SECTION 15: Regulatory Information TSCA:Listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:Listed in the TSCA inventory SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

毒理学数据: 生态学数据:

安全

• 危害码 (欧洲): Xi
• 风险声明 (欧洲): R36/37/38
• 安全声明 (欧洲): S26-S36
• 危险品运输编码: 1993
• 包装等级: III
• 危险类别: 3

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