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16919-27-0生产厂家

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16919-27-0

16919-27-0结构式
16919-27-0结构式
  • 常用中文名:氟钛酸钾
  • 常用英文名:Potassium Fluortitanate (K2TiF6)
  • CAS号:16919-27-0
  • 分子式:F6K2Ti
  • 分子量:240.05400
  • 相关类别: 无机化工 无机盐 金属卤化物及卤酸盐 金属氟化物及盐
  • 发布时间:2018-07-05 13:38:34
  • 更新时间:2024-01-02 09:51:19
  • 【用途一】
    是金属磷化表调剂的组成成分,用作聚丙烯合成催化剂等
    【用途二】
    用作分析试剂,也用于钛酸和金属钛的制造
    【用途三】
    可用做聚丙烯合成的催化剂。
    【用途四】
    用于聚丙稀合成的催化剂,制钛酸、金属钛、制铝钛硼合金等。

化源商城直购

中文名 氟钛酸钾
英文名 Potassium hexafluorotitanate
中文别名 氟化钛钾
(OC-6-11)六氟合钛酸(2-)钾
氟化鉀鈦
英文别名 TITANIUM POTASSIUM FLUORIDE
EINECS 240-969-9
POTASSIUM FLUOROTITANATE
Dipotassium hexafluorotitanate;Titanium potassium hexafluoride
Dipotassium hexafluorotitanate Titanium potassium hexafluoride
CATALYST PTF
POTASSIUM TITANIUM FLUORIDE
MFCD00011380
Postassium fluorotitanate
Dikaliumhexafluorotitanat
fluotitanatedepotassium
Potassium Fluortitanate (K2TiF6)
密度 3.01
沸点 235-237°C
熔点 780℃
分子式 F6K2Ti
分子量 240.05400
闪点 235-237°C
精确质量 239.86600
LogP 2.52120
外观性状 白色结晶粉末
储存条件

1.常温密闭避光,通风干燥,储存于阴凉干燥通风库房中。

2.运输时应防雨受潮,防止碰撞。

3.远离火种、热源。严禁与氧化剂、食用化学品等混装混运。

稳定性

常温常压下稳定

避免的物料:氧化物 在空气中加热到500℃以上,逐步氧化为二氧化钛。微溶于无机酸和冷水,可溶于热水,不溶于氨。有毒!对皮肤、黏膜有刺f??作用。工作人员应作好防护,若不慎触及皮肤和眼睛,应立即用大量流动清水冲洗。
计算化学

1、疏水参数计算参考值(XlogP):

2、氢键供体数量:0

3、氢键受体数量:6

4、可旋转化学键数量:0

5、互变异构体数量:

6、拓扑分子极性表面积(TPSA);0

7、重原子数量:9

8、表面电荷:0

9、复杂度:0

10、同位素原子数量:0

11、确定原子立构中心数量:0

12、不确定原子立构中心数量:0

13、确定化学键立构中心数量:0

14、不确定化学键立构中心数量:0

15、:共价键单元数量:9

更多

1.性状:白色片状结晶

2.密度(g/mL,25/4℃):3.012

3.熔点(ºC):780

4.沸点(ºC,常压):235-237

5.闪点(ºC):235-23719.溶解性:溶于热水,微溶于冷水和无机酸。

6.溶解性:溶于热水,微溶于冷水和无机酸。


Section 1. Chemical Product and Company Identification
Potassium titanium fluoride
Common Name/
Trade Name
Manufacturer
Commercial Name(s)
Synonym
Chemical Name
Chemical Family
Potassium titanium fluoride

Section 4. First Aid Measures
Eye ContactCheck for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. Get medical attention.
Skin ContactWash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.
Serious Skin ContactNot available.
InhalationIf inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
Serious InhalationNot available.
IngestionDo NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
clothing such as a collar, tie, belt or waistband.
Serious IngestionNot available.

Section 5. Fire and Explosion Data
Flammability of the Product Non-flammable.
Auto-Ignition Temperature Not applicable.
Flash PointsNot applicable.
Flammable LimitsNot applicable.
Products of CombustionNot available.
Fire Hazards in Presence of Not applicable.
Various Substances
Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
of Various Substances
Not applicable.
Fire Fighting Media
and Instructions
When heated to decomposition it emits highly toxic fumes of potassium oxides, fluorine, titanium/titanium oxides.
Special Remarks on
Fire Hazards
Special Remarks on Explosion Not available.
Hazards

Section 6. Accidental Release Measures
Small SpillUse appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
Large SpillUse a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water
on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not
present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.
Potassium titanium fluoride

Section 7. Handling and Storage
PrecautionsDo not breathe dust. Avoid contact with eyes. Never add water to this product. Wear suitable protective
clothing. If ingested, seek medical advice immediately and show the container or the label. Store in an
appropriate container.
StorageKeep container tightly closed. Keep container in a cool, well-ventilated area.

Section 8. Exposure Controls/Personal Protection
Engineering ControlsUse process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Personal ProtectionSplash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
a Large Spillto avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Exposure LimitsTWA: 2.5 (mg(F)/m3) from OSHA (PEL) [United States]
TWA: 2.5 (mg/(F)m3) from ACGIH (TLV) [United States]
Consult local authorities for acceptable exposure limits.

Section 9. Physical and Chemical Properties
Physical state and appearance Solid.OdorNot available.
Not available.
Taste
Molecular Weight239.84 g/mole
Not available.
Color
Not available.
pH (1% soln/water)
Boiling PointNot available.
Not available.
Melting Point
Critical TemperatureNot available.
Specific GravityNot available.
Vapor PressureNot applicable.
Vapor DensityNot available.
Not available.
Volatility
Odor ThresholdNot available.
Water/Oil Dist. Coeff.Not available.
Ionicity (in Water)Not available.
Dispersion PropertiesNot available.
SolubilityNot available.

Section 10. Stability and Reactivity Data
StabilityThe product is stable.
Instability TemperatureNot available.
Conditions of InstabilityIncompatible materials
Incompatibility with various Reactive with oxidizing agents.
substances
Potassium titanium fluoride
CorrosivityNot available.
Special Remarks onNot available.
Reactivity
Special Remarks onNot available.
Corrosivity
PolymerizationWill not occur.

Section 11. Toxicological Information
Routes of EntryInhalation. Ingestion.
Toxicity to AnimalsLD50: Not available.
LC50: Not available.
Chronic Effects on Humans Not available.
Other Toxic Effects onHazardous in case of ingestion.
Humans
Slightly hazardous in case of skin contact (irritant), of inhalation.
Special Remarks onNot available.
Toxicity to Animals
Special Remarks onNot available.
Chronic Effects on Humans
Special Remarks on otherAcute Potential Health Effects:
Toxic Effects on HumansSkin: May cause skin irritation.
Eyes: Causes eye irritation.
Inhalation: May cause respiratory tract irritation.
Ingestion: May be harmful if swallowed.

Section 12. Ecological Information
EcotoxicityNot available.
Not available.
BOD5 and COD
Possibly hazardous short term degradation products are not likely. However, long term degradation products may
Products of Biodegradation
arise.
Toxicity of the ProductsThe product itself and its products of degradation are not toxic.
of Biodegradation
Special Remarks on theNot available.
Products of Biodegradation

Section 13. Disposal Considerations
Waste DisposalWaste must be disposed of in accordance with federal, state and local environmental
control regulations.

Section 14. Transport Information
DOT ClassificationNot a DOT controlled material (United States).
Not applicable.
Identification
Not applicable.
Special Provisions for
Transport
Potassium titanium fluoride
DOT (Pictograms)

Section 15. Other Regulatory Information and Pictograms
TSCA 8(b) inventory: Potassium titanium fluoride
Federal and State
Regulations
CaliforniaCalifornia prop. 65: This product contains the following ingredients for which the State of California has found
to cause cancer which would require a warning under the statute: No products were found.
Proposition 65
Warnings
California prop. 65: This product contains the following ingredients for which the State of California has found
to cause birth defects which would require a warning under the statute: No products were found.
Other RegulationsEINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No.
240-969-9).
Canada: Listed on Canadian Domestic Substance List (DSL).
China: Listed on National Inventory.
Japan: Listed on National Inventory (ENCS).
Korea: Listed on National Inventory (KECI).
Philippines: Listed on National Inventory (PICCS).
Australia: Listed on AICS.
Other ClassificationsWHMIS (Canada) CLASS D-2B: Material causing other toxic effects (TOXIC).
DSCL (EEC)R22- Harmful if swallowed.S26- In case of contact with eyes, rinse
R36- Irritating to eyes.immediately with plenty of water and seek
R43- May cause sensitization by skinmedical advice.
contact.S46- If swallowed, seek medical advice
immediately and show this container or label.
Health Hazard
HMIS (U.S.A.)2 National Fire Protection
0 Flammability
0 Association (U.S.A.)
Fire Hazard
2 0 Reactivity
Health
Reactivity
0
Specific hazard
Personal Protection
E
WHMIS (Canada)
(Pictograms)
DSCL (Europe)
(Pictograms)
TDG (Canada)
(Pictograms)
ADR (Europe)
(Pictograms)
Protective Equipment
Potassium titanium fluoride
Gloves.
Lab coat.
Dust respirator. Be sure to use an
approved/certified respirator or
equivalent.


SECTION 16 - ADDITIONAL INFORMATION
N/A

毒理学数据:

急性毒性:皮下注射:360 mg/kg。

生态学数据:

通常对水体是稍微有害的,不要将未稀释或大量产品接触地下水,水道或污水系统,未经政府许可勿将材料排入周围环境。

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TT1575000
CHEMICAL NAME :
Potassium hexafluorotitanate
CAS REGISTRY NUMBER :
16919-27-0
LAST UPDATED :
199701
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
F6-Ti.2K
MOLECULAR WEIGHT :
240.10
WISWESSER LINE NOTATION :
KA2 TI-F6

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Amphibian - frog
DOSE/DURATION :
360 mg/kg
REFERENCE :
CRSBAW Comptes Rendus des Seances de la Societe de Biologie et de Ses Filiales. (SPPIF, B.P.22, F-41353 Vineuil, France) V.1- 1849- Volume(issue)/page/year: 124,133,1937 *** REVIEWS *** TOXICOLOGY REVIEW AMSSAQ Acta Medica Scandinavica, Supplement. (Almqvist & Wiksell, POB 45150, S-10430 Stockholm, Sweden) No.1-730, 1921-88. Volume(issue)/page/year: 400,5,1963 *** U.S. STANDARDS AND REGULATIONS *** OSHA PEL (Gen Indu):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO FLUORIDES, INORGANIC-air:10H TWA 2.5 mg(F)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X2929 No. of Facilities: 63 (estimated) No. of Industries: 6 No. of Occupations: 13 No. of Employees: 8704 (estimated) No. of Female Employees: 40 (estimated)

符号 GHS05 GHS07
GHS05, GHS07
信号词 Danger
危害声明 H302-H317-H318
警示性声明 P280-P305 + P351 + P338
个人防护装备 dust mask type N95 (US);Eyeshields;Faceshields;Gloves
危害码 (欧洲) Xn:Harmful;
风险声明 (欧洲) R22;R41;R43
安全声明 (欧洲) S26-S36/37/39
危险品运输编码 3288
WGK德国 2
RTECS号 TT1575000
包装等级 III
危险类别 6.1

合成法 氢氟酸与偏钛酸作用生成氟钛酸,然后再用氢氧化钾中和制取氟钛酸钾。其

16919-27-0 preparation