69807-81-4

• 常用中文名：(1-甲基-1H-吡咯-2-yl)甲基胺
• 常用英文名：(1-Methyl-1H-pyrrol-2-yl)methanamine
• CAS号：69807-81-4
• 分子式：C₆H₁₀N₂
• 分子量：110.157
• 发布时间：2018-12-26 00:06:22
• 更新时间：2024-01-10 19:07:34

名称

• 中文名: (1-甲基-1H-吡咯-2-yl)甲基胺
• 英文名: (1-methylpyrrol-2-yl)methanamine
• 英文别名: 1-(1-Methyl-1H-pyrrol-2-yl)methanamine; (1-methyl-1H-pyrrol-2-yl)aminomethane; 2-aminomethyl-1-methyl-1H-pyrrole; 1H-Pyrrole-2-methanamine, 1-methyl-; (1-methyl-1H-pyrrol-2-yl)methanamine; 2-(3-BUTOXYPHENYL)-7-CHLORO-8-METHYLQUINOLINE-4-CARBOXYLIC ACID; C-(1-methyl-1H-pyrrol-2-yl)methylamine; F2169-1279; (1-Methyl-1H-Pyrrol-2-Yl)Methylamine; 2-(1-methyl)pyrrolylmethyl amine

物化性质

• 密度: 1.0±0.1 g/cm3
• 沸点: 199.6±15.0 °C at 760 mmHg
• 分子式: C₆H₁₀N₂
• 分子量: 110.157
• 闪点: 74.5±20.4 °C
• 精确质量: 110.084396
• PSA: 30.95000
• LogP: 0.08
• 蒸汽压: 0.3±0.4 mmHg at 25°C
• 折射率: 1.536
• 储存条件: 2-8°C

MSDS

Name: (1-Methyl-1H-pyrrol-2-yl)methylamine 97% Material Safety Data Sheet Synonym: CAS: 69807-81-4 Section 1 - Chemical Product MSDS Name:(1-Methyl-1H-pyrrol-2-yl)methylamine 97% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 69807-81-4 (1-Methyl-1H-pyrrol-2-yl)methylamine 97% unlisted Hazard Symbols: C Risk Phrases: 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Causes burns.Moisture sensitive. Potential Health Effects Eye: Causes eye burns. Skin: Causes skin burns. Ingestion: Causes gastrointestinal tract burns. Inhalation: Causes chemical burns to the respiratory tract. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Store in a tightly closed container. Store in a dry area. Keep refrigerated. (Store below 4C/39F.) Store under an inert atmosphere. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 69807-81-4: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Viscous liquid Color: yellow Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 53 - 57 deg C @0.5mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C6H10N2 Molecular Weight: 110 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, exposure to moist air or water. Incompatibilities with Other Materials: Strong oxidizing agents, acids, acid chlorides, halogens, halogenated agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 69807-81-4 unlisted. LD50/LC50: Not available. Carcinogenicity: (1-Methyl-1H-pyrrol-2-yl)methylamine - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.* Hazard Class: 8 UN Number: 2735 Packing Group: III IMO Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S. Hazard Class: 8 UN Number: 2735 Packing Group: III RID/ADR Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S. Hazard Class: 8 UN Number: 2735 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 34 Causes burns. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 69807-81-4: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 69807-81-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 69807-81-4 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危险品运输编码: UN 2735
• 海关编码: 2933990090

合成路线

52160-51-7 ~% 69807-81-4

文献：Journal of Medicinal Chemistry, , vol. 44, # 26 p. 4505 - 4508

37110-15-9 ~% 69807-81-4

文献：Morikawa; Honda; Endoh; Matsumoto; Akamatsu; Mitsui; Koizumi Chemical and Pharmaceutical Bulletin, 1990 , vol. 38, # 4 p. 930 - 935

64230-41-7 ~% 69807-81-4

文献：Journal of Medicinal Chemistry, , vol. 38, # 21 p. 4198 - 4210

96-54-8 ~% 69807-81-4

文献：Journal of Medicinal Chemistry, , vol. 38, # 21 p. 4198 - 4210

4513-94-4 ~% 69807-81-4

文献：Tetrahedron, , vol. 54, # 10 p. 2021 - 2030

上下游产品

上游产品  5
52160-51-7 37110-15-9 64230-41-7 96-54-8
4513-94-4
下游产品  1
26171-06-2

海关

海关编码	2933990090
中文概述	2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期
Summary	2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%