19241-34-0

• 常用中文名：异硫氰酸2-氯-6-甲基苯基酯
• 常用英文名：2-Chloro-6-methylphenyl isothiocyanate
• CAS号：19241-34-0
• 分子式：C₈H₆ClNS
• 分子量：183.65800
• 发布时间：2018-03-29 08:00:00
• 更新时间：2024-01-31 18:53:24

名称

• 中文名: 异硫氰酸2-氯-6-甲基苯基酯
• 英文名: 2-Chloro-6-methylphenyl isothiocyanate
• 中文别名: 2-氯-6-甲基异硫氰酸苯酯
• 英文别名: MFCD00037030; 1-chloro-2-isothiocyanato-3-methylbenzene

物化性质

• 密度: 1.18g/cm3
• 沸点: 288.2ºC at 760mmHg
• 分子式: C₈H₆ClNS
• 分子量: 183.65800
• 闪点: 128.1ºC
• 精确质量: 182.99100
• PSA: 44.45000
• LogP: 3.38270
• 蒸汽压: 0.00412mmHg at 25°C
• 折射率: n20/D 1.555(lit.)
• 储存条件: 0-6°C

MSDS

Name: 2-Chloro-6-methylphenyl isothiocyanate 95+% Material Safety Data Sheet Synonym: CAS: 19241-34-0 Section 1 - Chemical Product MSDS Name:2-Chloro-6-methylphenyl isothiocyanate 95+% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 19241-34-0 2-Chloro-6-methylphenyl isothiocyanate 95+% unlisted Hazard Symbols: XN Risk Phrases: 20/21/22 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin.Moisture sensitive. Potential Health Effects Eye: Causes eye irritation. Lachrymator (substance which increases the flow of tears). Skin: Causes skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. Causes respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Store under nitrogen. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 19241-34-0: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: colorless Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 134 - 135 deg C @10mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C8H6ClNS Molecular Weight: 183.66 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, exposure to moist air or water. Incompatibilities with Other Materials: Strong oxidizing agents, acids, bases. Hazardous Decomposition Products: Hydrogen chloride, chlorine, nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 19241-34-0 unlisted. LD50/LC50: Not available. Carcinogenicity: 2-Chloro-6-methylphenyl isothiocyanate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.* Hazard Class: 6.1 UN Number: 2810 Packing Group: III IMO Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2810 Packing Group: III RID/ADR Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2810 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 19241-34-0: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 19241-34-0 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 19241-34-0 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xn,T,C
• 风险声明 (欧洲): R20/21/22
• 安全声明 (欧洲): 26-36/37/39
• 危险品运输编码: UN 2206 6.1/PG 2
• WGK德国: 3
• 海关编码: 2930909090

合成路线

85046-68-0 ~90% 19241-34-0

文献：Chawng Siek Pak; In Kwon Youn; Yeon Soo Lee Synthesis, 1982 , # 11 p. 969 - 970

463-71-8 87-63-8 ~% 19241-34-0

文献：Journal of the Chemical Society, , p. 3285,3299

上下游产品

上游产品  3
85046-68-0 463-71-8 87-63-8
下游产品  1
52266-67-8

海关

海关编码	2930909090
中文概述	2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%