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| 中文名 | 三(2,2,6,6-四甲基-3,5-庚二酮酸)铕(III) |
|---|---|
| 英文名 | Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(III) |
| 中文别名 |
三(2,2,6,6-四甲基-3,5-庚二酮酸)铕
三(2,2,6,6-四甲基-3,5-庚二酸)铕 |
| 英文别名 |
Europium(III)-tris-(2,2,6,6-tetramethyl-3,5-heptanedionate)
Europium(III) Tris(2,2,6,6-tetramethyl-3,5-heptanedionato) EINECS 239-565-5 Europium tris(2,2,6,6-tetramethyl-3,5-heptanedionate) Tris(2,2,6,6-tetraMethyl-3,5-heptanedionato)europiuM(III) MFCD00000019 |
| 沸点 | 275ºC |
|---|---|
| 熔点 | 188-89ºC |
| 分子式 | C33H60EuO6 |
| 分子量 | 704.79000 |
| 闪点 | 109.7ºC |
| 精确质量 | 705.36000 |
| PSA | 102.42000 |
| LogP | 7.82070 |
| 外观性状 | Powder | yellow |
| 蒸汽压 | 0.00138mmHg at 25°C |
| 储存条件 | 常温密闭避光，通风干燥 |
| 稳定性 | 常温常压下稳定 避免的物料：水分/潮湿 氧化物 酸 |
| 计算化学 | 1、疏水参数计算参考值（XlogP）： 2、氢键供体数量：0 3、氢键受体数量：6 4、可旋转化学键数量：12 5、互变异构体数量：4 6、拓扑分子极性表面积（TPSA）：102 7、重原子数量：40 8、表面电荷：0 9、复杂度：189 10、同位素原子数量：0 11、确定原子立构中心数量：0 12、不确定原子立构中心数量：0 13、确定化学键立构中心数量：0 14、不确定化学键立构中心数量：0 15、共价键单元数量：4 |
| 更多 | 1.性状：未确定 2.密度（g/mL,25/4℃）：未确定 3.相对蒸汽密度（g/mL,空气=1）：未确定 4.熔点（ºC）：187-191 5.沸点（ºC,常压）：275 6.沸点（ºC,5.2kPa）：未确定 7.折射率：未确定 8.闪点（ºC）：未确定 9.比旋光度（º）：未确定 10.自燃点或引燃温度（ºC）：未确定 11.蒸气压（kPa,25ºC）：未确定 12.饱和蒸气压（kPa,60ºC）：未确定 13.燃烧热（KJ/mol）：未确定 14.临界温度（ºC）：未确定 15.临界压力（KPa）：未确定 16.油水（辛醇/水）分配系数的对数值：未确定 17.爆炸上限（%,V/V）：未确定 18.爆炸下限（%,V/V）：未确定 19.溶解性：未确定 |
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Tris(2,2,6,6-tetramethyl-3,5-
Revision number: 5
heptanedionato)europium(III) [NMR Shift Reagent] SAFETY DATA SHEET Section1. IDENTIFICATION Product name:Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(III) [NMR Shift Reagent]
Revision number:5
Section2. HAZARDS IDENTIFICATION GHS classification PHYSICAL HAZARDSNot classified Not classified HEALTH HAZARDS ENVIRONMENTAL HAZARDSNot classified GHS label elements, including precautionary statements Pictograms or hazard symbolsNone Signal wordNo signal word Hazard statementsNone Precautionary statements:None Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substance Substance/mixture: Components:Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(III) [NMR Shift Reagent] .... Percent: CAS Number:15522-71-1 Eu(dpm)3 , Europium(III) Tris(2,2,6,6-tetramethyl-3,5-heptanedionato) Synonyms: Chemical Formula:C33H57EuO6 Section4. FIRST AID MEASURES Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. Skin contact:Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation or rash occurs: Get medical advice/attention. Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Get medical advice/attention if you feel unwell. Rinse mouth. Ingestion: Protection of first-aiders:A rescuer should wear personal protective equipment, such as rubber gloves and air- tight goggles. Section5. FIRE-FIGHTING MEASURES Dry chemical, foam, water spray, carbon dioxide. Suitable extinguishing media: Tris(2,2,6,6-tetramethyl-3,5- heptanedionato)europium(III) [NMR Shift Reagent] Section5. FIRE-FIGHTING MEASURES Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Remove movable containers if safe to do so. Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment. equipment for firefighters: Section6. ACCIDENTAL RELEASE MEASURES Use personal protective equipment. Keep people away from and upwind of spill/leak. Personal precautions, protective equipment and Entry to non-involved personnel should be controlled around the leakage area by emergency procedures: roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it. containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with up: appropriate laws and regulations. Section7. HANDLING AND STORAGE Precautions for safe handling Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment. Prevent dispersion of dust. Wash hands and face thoroughly after handling. Use a local exhaust if dust or aerosol will be generated. Advice on safe handling: Avoid contact with skin, eyes and clothing. Conditions for safe storage, including any incompatibilities Storage conditions:Keep container tightly closed. Store in a cool and dark place. Store under inert gas. Protect from moisture. Store away from incompatible materials such as oxidizing agents. Hygroscopic Packaging material:Comply with laws. Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls:Install a closed system or local exhaust as possible so that workers should not be exposed directly. Also install safety shower and eye bath. Personal protective equipment Respiratory protection: Dust respirator. Follow local and national regulations. Hand protection:Protective gloves. Safety glasses. A face-shield, if the situation requires. Eye protection: Skin and body protection: Protective clothing. Protective boots, if the situation requires. Section9. PHYSICAL AND CHEMICAL PROPERTIES Physical state (20°C):Solid Crystal- Powder Form: Colour:Pale yellow - Yellow No data available Odour: pH: No data available Melting point/freezing point:190°C Boiling point/range:No data available No data available Flash point: Flammability or explosive limits: Lower:No data available Upper:No data available Relative density:No data available Solubility(ies): Tris(2,2,6,6-tetramethyl-3,5- heptanedionato)europium(III) [NMR Shift Reagent] Section9. PHYSICAL AND CHEMICAL PROPERTIES [Water]No data available [Other solvents]No data available Section10. STABILITY AND REACTIVITY Stable under proper conditions. Chemical stability: Possibility of hazardous No special reactivity has been reported. reactions: Incompatible materials: Oxidizing agents Hazardous decomposition Carbon monoxide, Carbon dioxide products: Section11. TOXICOLOGICAL INFORMATION Acute Toxicity:No data available Skin corrosion/irritation: No data available Serious eyeNo data available damage/irritation: Germ cell mutagenicity: No data available Carcinogenicity: IARC =No data available NTP =No data available Reproductive toxicity:No data available Section12. ECOLOGICAL INFORMATION Ecotoxicity: Fish:No data available No data available Crustacea: Algae:No data available Persistence / degradability: No data available BioaccumulativeNo data available potential(BCF): Mobility in soil Log Pow:No data available Soil adsorption (Koc):No data available No data available Henry's Law constant(PaM3/mol): Section13. DISPOSAL CONSIDERATIONS Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when disposing of the substance. Section14. TRANSPORT INFORMATION Hazards Class:Does not correspond to the classification standard of the United Nations UN-No:Not listed Section15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002 and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were prescribed. Tris(2,2,6,6-tetramethyl-3,5- heptanedionato)europium(III) [NMR Shift Reagent] SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 通常对水是不危害的，若无政府许可，勿将材料排入周围环境。
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| 风险声明 (欧洲) | R36/37/38 |
|---|---|
| 安全声明 (欧洲) | S26-S36/37/39 |
| WGK德国 | 3 |
| 海关编码 | 2914509090 |
| 海关编码 | 2914509090 |
|---|---|
| 中文概述 | 2914509090 含其他含氧基的酮. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途, 丙酮报明包装 |
| Summary | HS:2914509090 other ketones with other oxygen function VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0% |
