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| 中文名 | (R)-(+)-1-(3-甲氧基苯基)乙胺 |
|---|---|
| 英文名 | (1R)-1-(3-methoxyphenyl)ethanamine |
| 中文别名 | (R)-1-(3-甲氧基苯基)乙胺 |
| 英文别名 |
(1R)-1-(3-Methoxyphenyl)ethanamine
(R)-m-Methoxy-α-methylbenzylamine MFCD00671655 (S)-1-(3'-methoxyphenyl)ethylamine (R)-1-(3-Methoxyphenyl)ethylamine (S)-1-(m-methoxyphenyl)ethylamine Benzenemethanamine, 3-methoxy-α-methyl-, (αR)- (1R)-1-(3-Methoxyphenyl)ethan-1-amine 1-(R)-(3-methoxyphenol)ethylamine (S)-1-methyl-m-methoxy-benzyl amine (S)-m-methoxy-1-phenylethylamine ZY1&R CO1 &&R Form (R)-1-(3-Methoxyphenyl)ethanamine (αR)-3-Methoxy-α-methylbenzenemethanamine R-3-methoxy-Alpha-methylbenzylamine (S)-(-)-1-(3-methoxylphenyl)ethylamine |
| 密度 | 1.0±0.1 g/cm3 |
|---|---|
| 沸点 | 234.6±23.0 °C at 760 mmHg |
| 分子式 | C9H13NO |
| 分子量 | 151.206 |
| 闪点 | 94.7±15.9 °C |
| 精确质量 | 151.099716 |
| PSA | 35.25000 |
| LogP | 1.35 |
| 蒸汽压 | 0.1±0.5 mmHg at 25°C |
| 折射率 | 1.523 |
| 储存条件 | 密闭，阴凉，干燥处 |
| 稳定性 | 按规定使用和贮存的不会分解，避氧化物 |
| 分子结构 | 1、 摩尔折射率：46.01 2、 摩尔体积（m3/mol）：150.6 3、 等张比容(90.2K)：368.2 4、 表面张力(dyne/cm)：35.6 5、 极化率(10-24cm3)：18.24 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:1 3.氢键受体数量:2 4.可旋转化学键数量:2 5.互变异构体数量:无 6.拓扑分子极性表面积35.2 7.重原子数量:11 8.表面电荷:0 9.复杂度:116 10.同位素原子数量:0 11.确定原子立构中心数量:1 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：无色液体 2. 密度（g/mL20 ºC）：1.023 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC0.38mmHg）：66 7. 折射率：1.5335 8. 闪点（ºC0.38mmHg）：66 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：＞100 11. 蒸气压（Pa,）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（正辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
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SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifiers : (R)-3-Methoxy-α-methylbenzylamine Product name REACH No.: A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later
registration deadline. CAS-No.: 88196-70-7 SECTION 2: Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Acute toxicity, Inhalation (Category 3), H331 Skin corrosion (Category 1B), H314 For the full text of the H-Statements mentioned in this Section, see Section 16. Classification according to EU Directives 67/548/EEC or 1999/45/EC C CorrosiveR34 Xn HarmfulR20 For the full text of the R-phrases mentioned in this Section, see Section 16. Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal wordDanger Hazard statement(s) Causes severe skin burns and eye damage. Toxic if inhaled. Precautionary statement(s) Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Wear protective gloves/ protective clothing/ eye protection/ face protection. P305 + P351 + P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Supplemental Hazardnone Statements According to European Directive 67/548/EEC as amended. Hazard symbol(s)C Corrosive R-phrase(s) R20Harmful by inhalation. R34Causes burns. S-phrase(s) S26In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39Wear suitable protective clothing, gloves and eye/face protection. S45In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Other hazards - none SECTION 3: Composition/information on ingredients Mixtures Synonyms: (R)-1-(3-Methoxyphenyl)ethylamine Formula: C9H13NO Molecular Weight: 151,21 g/mol Hazardous ingredients according to Regulation (EC) No 1272/2008 ComponentClassificationConcentration (R)-1-(3-Methoxyphenyl) ethylamine CAS-No.88196-70-7Acute Tox. 3; Skin Corr. 1B; <= 100 % H314, H331 (S)-(-)-3-Methoxy-α-methylbenzylamine CAS-No.82796-69-8Acute Tox. 4; Acute Tox. 3; < 5 % Skin Corr. 1B; Aquatic Chronic 3; H302, H314, H331, H412 Hazardous ingredients according to Directive 1999/45/EC ComponentClassificationConcentration (R)-1-(3-Methoxyphenyl) ethylamine CAS-No.88196-70-7C, R20 - R34<= 100 % (S)-(-)-3-Methoxy-α-methylbenzylamine CAS-No.82796-69-8C, Xn, R20 - R22 - R34<5% For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16 SECTION 4: First aid measures Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 Indication of any immediate medical attention and special treatment needed no data available SECTION 5: Firefighting measures Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Carbon oxides, nitrogen oxides (NOx), Metal oxides Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information no data available SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. For personal protection see section 8. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. Reference to other sections For disposal see section 13. SECTION 7: Handling and storage Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Normal measures for preventive fire protection. For precautions see section 2.2. Conditions for safe storage, including any incompatibilities Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store in cool place. Specific end use(s) A part from the uses mentioned in section 1.2 no other specific uses are stipulated SECTION 8: Exposure controls/personal protection Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Personal protective equipment Eye/face protection Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties a) AppearanceForm: liquid Colour: colourless, light yellow b) Odouramine-like c) Odour Thresholdno data available d) pH10,9 at 10 g/l at 20 °C e) Melting point/freezing66 °C at 0,5 hPa point f) Initial boiling point and no data available boiling range g) Flash pointno data available h) Evapouration rateno data available i) Flammability (solid, gas) no data available j) Upper/lowerno data available flammability or explosive limits k) Vapour pressureno data available l) Vapour densityno data available m) Relative densityno data available n) Water solubility10 g/l at 20 °C o) Partition coefficient: n- no data available octanol/water p) Auto-ignitionno data available temperature q) Decompositionno data available temperature r) Viscosityno data available s) Explosive propertiesno data available t) Oxidizing propertiesno data available Other safety information no data available SECTION 10: Stability and reactivity Reactivity no data available Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions no data available Conditions to avoid no data available Incompatible materials no data available Hazardous decomposition products Other decomposition products - no data available In the event of fire: see section 5 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity no data available Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitisation no data available Germ cell mutagenicity no data available Carcinogenicity IARC:No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Additional Information RTECS: Not available To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. SECTION 12: Ecological information Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted Other adverse effects Harmful to aquatic life. SECTION 13: Disposal considerations Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Contaminated packaging Dispose of as unused product. SECTION 14: Transport information UN number ADR/RID: 2735IMDG: 2735IATA: 2735 UN proper shipping name ADR/RID: AMINES, LIQUID, CORROSIVE, N.O.S. ((R)-1-(3-Methoxyphenyl) ethylamine) IMDG: AMINES, LIQUID, CORROSIVE, N.O.S. ((R)-1-(3-Methoxyphenyl) ethylamine) IATA:Amines, liquid, corrosive, n.o.s. ((R)-1-(3-Methoxyphenyl) ethylamine) Transport hazard class(es) ADR/RID: 8IMDG: 8IATA: 8 Packaging group ADR/RID: IIIMDG: IIIATA: II Environmental hazards ADR/RID: noIMDG Marine pollutant: noIATA: no Special precautions for user no data available SECTION 15: Regulatory information This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. Safety, health and environmental regulations/legislation specific for the substance or mixture no data available Chemical Safety Assessment SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 对水是稍微危害的，若无政府许可，勿将材料排入周围环境
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| 符号 |
GHS05, GHS06 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H314-H331 |
| 警示性声明 | P261-P280-P305 + P351 + P338-P310 |
| 危害码 (欧洲) | C |
| 风险声明 (欧洲) | R21/22;R34 |
| 安全声明 (欧洲) | S26-S36/37/39-S45 |
| 危险品运输编码 | UN 2735 |
| 包装等级 | III |
| 海关编码 | 2922299090 |
|
~%
88196-70-7 |
| 文献：Tetrahedron Asymmetry, , vol. 23, # 9 p. 716 - 721 |
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~%
88196-70-7 |
| 文献：Journal of the Chemical Society. Perkin Transactions 2, , # 7 p. 1339 - 1347 |
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88196-70-7 |
| 文献：Applied Organometallic Chemistry, , vol. 25, # 2 p. 105 - 109 |
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~%
88196-70-7 |
| 文献：Tetrahedron Asymmetry, , vol. 16, # 23 p. 3807 - 3813 |
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~%
88196-70-7 |
| 文献：Chemical Communications, , # 21 p. 2415 - 2416 |
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~%
88196-70-7 |
| 文献：Tetrahedron Asymmetry, , vol. 23, # 9 p. 716 - 721 |
| 上游产品 3 | |
|---|---|
| 下游产品 1 | |
| 海关编码 | 2922299090 |
|---|---|
| 中文概述 | 2922299090. 其他氨基(萘酚、酚)及醚、酯〔包括它们的盐, 但含有一种以上含氧基的除外〕. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装 |
| Summary | 2922299090. other amino-naphthols and other amino-phenols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0% |
