12083-92-0
12083-92-0结构式
- 常用中文名：二氯(二环戊二烯基)铂(Ⅱ)
- 常用英文名：Dichloro(dicyclopentadienyl)platinum(II)
- CAS号：12083-92-0
- 分子式：C10H12Cl2Pt
- 分子量：398.18600
- 发布时间：2018-04-24 08:00:00
- 更新时间：2024-01-06 21:32:35
| 中文名 | 二氯(二环戊二烯基)铂(Ⅱ) |
|---|---|
| 英文名 | dichloro(dicyclopentadienyl)platinum(ii) |
| 中文别名 |
(二聚环戊二烯)二氯化铂(II)
二氯（二环戊二烯）铂 |
| 英文别名 |
[Pt(dicyclopentadiene)Cl2]
Bis-(cyclopentadienyl)-platinum dichloride Platinum,dichloro(3A,4,7,7A-tetrahydro-4,7-methanoindene) (dicyclopentadiene)platinum(II) chloride |
| 沸点 | 170ºC at 760mmHg |
|---|---|
| 熔点 | 220-222°C (lit.) |
| 分子式 | C10H12Cl2Pt |
| 分子量 | 398.18600 |
| 闪点 | 46.8ºC |
| 精确质量 | 396.99600 |
| LogP | 3.76110 |
| 外观性状 | 固体 |
| 蒸汽压 | 1.99mmHg at 25°C |
| 储存条件 | 室温 |
| 分子结构 | 1、摩尔折射率：无可用的 2、摩尔体积（cm3/mol）：无可用的 3、等张比容（90.2K）：无可用的 4、表面张力（dyne/cm）：无可用的 5、介电常数：无可用的 6、极化率（10-24cm3）：无可用的 7、单一同位素质量：396.996406 Da 8、标称质量：397 Da 9、平均质量：398.1923 Da |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:0 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积0 7.重原子数量:13 8.表面电荷:0 9.复杂度:215 10.同位素原子数量:0 11.确定原子立构中心数量:2 12.不确定原子立构中心数量:2 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:2 |
| 更多 | 1. 性状：未确定 2. 密度（g/mL, 18 ℃ ）：未确定 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：250 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC，1mmHg）：未确定 7. 折射率：未确定 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（20ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
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Section 1: Product Identification Chemical Name:Dichloro(dicyclopentadienyl)platinum (II), 99% CAS Registry Number:12083-92-0 Formula:C10H12PtCl2 EINECS Number:None Chemical Family:metallocene Synonym:dicyclopentadienylplatinum dichloride
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound12083-92-0100%1mg/m3(as-Pt)no data Section 3: Hazards Identification Emergency Overview:Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed. Primary Routes of Exposure:Ingestion, inhalation, skin Eye Contact:Causes mild to moderate irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Irritating to skin, eyes and respiratory tract. Ingestion:Ingestion may lead to dizziness, abdominal cramps, and vomiting. Irritating to skin, eyes and respiratory tract. Exposure to platinum compounds may lead to wheezing, coughing, Acute Health Affects: and running of the nose. Skin exposure may lead to dermatitis. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self- contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic and corrosive fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a cool, dry place in a tightly sealed container. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:To minimize exposure, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:To minimize exposure, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:off-white pwdr. Molecular Weight:398.19 Melting Point:no data Boiling Point:no data Vapor Pressure:not applicable Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:oxidizing agents, halogens, and active metals Decomposition Products:carbon dioxide, carbon monoxide, nitrogen oxides, hydrogen chloride, organic fumes, and platinum salts. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data Mutagenic Effects:No data Tetratogenic Effects:No data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Not regulated by Title 313. Second Ingredient:None SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危害码 (欧洲) | Xn |
|---|---|
| 风险声明 (欧洲) | 36/37/38 |
| 安全声明 (欧洲) | 26-36/37/39 |
| 上游产品 6 | |
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| 下游产品 0 | |