368-47-8

• 常用中文名：苯基三氟硅烷
• 常用英文名：phenyltrifluorosilane
• CAS号：368-47-8
• 分子式：C₆H₅F₃Si
• 分子量：162.18500
• 相关类别： 化学试剂 硅烷试剂
• 发布时间：2018-03-19 08:00:00
• 更新时间：2024-01-05 13:19:25

名称

• 中文名: 苯基三氟硅烷
• 英文名: trifluoro(phenyl)silane
• 英文别名: SILANE,PHENYLTRIFLUORO; MFCD00054907; Fenyl-trifluorsilan; Phenyltrifluorosilan; Trifluorophenylsilane

物化性质

• 密度: 1.14g/cm3
• 沸点: 101ºC
• 熔点: -19ºC
• 分子式: C₆H₅F₃Si
• 分子量: 162.18500
• 闪点: 15.2ºC
• 精确质量: 162.01100
• LogP: 1.74100
• 折射率: 1.411
• 储存条件: 库房通风低温干燥,与碱、氧化剂、酸,食品原料分开存放

毒性和生态

CHEMICAL IDENTIFICATION RTECS NUMBER : VV5250000 CHEMICAL NAME : Silane, phenyltrifluoro- CAS REGISTRY NUMBER : 368-47-8 BEILSTEIN REFERENCE NO. : 2935897 LAST UPDATED : 199612 DATA ITEMS CITED : 6 MOLECULAR FORMULA : C6-H5-F3-Si MOLECULAR WEIGHT : 162.20 WISWESSER LINE NOTATION : F-SI-FFR HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : Open irritation test ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962 TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit REFERENCE : 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1228,1986 TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : Administration into the eye SPECIES OBSERVED : Rodent - rabbit REFERENCE : 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1228,1986 ** ACUTE TOXICITY DATA ** TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 310 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962 TYPE OF TEST : LCLo - Lowest published lethal concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1000 ppm/4H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 640 uL/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962

安全

• 危害码 (欧洲): F: Flammable;
• 风险声明 (欧洲): R11
• 安全声明 (欧洲): 16-26-36/37/39-45
• 危险品运输编码: UN 2920
• 海关编码: 2931900090

合成路线

98-13-5 ~66% 368-47-8

文献：Powell, David A.; Fu, Gregory C. Journal of the American Chemical Society, 2004 , vol. 126, # 25 p. 7788 - 7789

694-53-1 ~53% 368-47-8

文献：Kunai, Atsutaka; Ohshita, Joji Journal of Organometallic Chemistry, 2003 , vol. 686, # 1-2 p. 3 - 15

7783-56-4 98-13-5 ~% 368-47-8

文献：Gmelin Handbook: Si: MVol.C, 40, page 122 - 124 Full Text Show Details Dow. Chemical Co. Patent: US2436777 , 1948 ; C. I, 1948 , p. 773

34136-85-1 ~% 420-56-4 107-46-0 368-47-8 详细

文献：Voronkov, M. G.; Basenko, S. V.; Vitkovskii, V. Yu.; Gebel', I. A.; Mirskov, R. G. Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1987 , vol. 36, # 5 p. 1082 - 1084 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1987 , vol. 36, # 5 p. 1169 - 1171

1235579-17-5 1235579-18-6 34224-10-7 ~% 368-45-6 详细

文献：Basenko; Zelenkov; Voronkov; Albanov Russian Journal of General Chemistry, 2010 , vol. 80, # 2 p. 242 - 244

上下游产品

上游产品  5
98-13-5 694-53-1 7783-56-4 34136-85-1
34224-10-7
下游产品  10
358-60-1 92-93-3 21331-86-2 135764-61-3
135764-62-4 20638-52-2 2046-18-6 605-02-7
603-36-1 7783-61-1

海关

海关编码	2931900090
中文概述	2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%
Summary	2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%