1428-33-7

• 常用中文名：烯丙基-1,1,2,2-四氟乙基醚
• 常用英文名：allyl 1,1,2,2-tetrafluoroethyl ether
• CAS号：1428-33-7
• 分子式：C₅H₆F₄O
• 分子量：158.09400
• 发布时间：2019-01-21 13:16:58
• 更新时间：2024-01-10 13:31:34

名称

• 中文名: 烯丙基-1,1,2,2-四氟乙基醚
• 英文名: 3-(1,1,2,2-tetrafluoroethoxy)prop-1-ene
• 中文别名: 四氟丙烯酸乙酯
• 英文别名: 2H-Perfluoroethyl allyl ether; 1,1,2,2-tetrafluoroethyl allyl ether; EINECS 215-847-3; HCF2CF2OCH2CH=CH2; 1,1,2,2-tetrafluoro-1-prop-2-enyloxyethane; MFCD00043822

物化性质

• 密度: 1.173g/cm3
• 沸点: 77.4ºC at 760mmHg
• 分子式: C₅H₆F₄O
• 分子量: 158.09400
• 闪点: -5°C
• 精确质量: 158.03500
• PSA: 9.23000
• LogP: 2.04690
• 蒸汽压: 107mmHg at 25°C
• 折射率: 1.328

MSDS

Name: Allyl 1 1 2 2-tetrafluoroethyl ether 99% Material Safety Data Sheet Synonym: Non CAS: 1428-33-7 Section 1 - Chemical Product MSDS Name:Allyl 1 1 2 2-tetrafluoroethyl ether 99% Material Safety Data Sheet Synonym:Non Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 1428-33-7 Allyl 1,1,2,2-Tetrafluoroethyl ether 99% 215-847-3 Hazard Symbols: XI Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed. Inhalation: The toxicological properties of this substance have not been fully investigated. May be harmful if inhaled. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids. Get medical aid immediately. Skin: Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use dry sand or earth to smother fire. Use water spray to cool fire-exposed containers. Autoignition Temperature: Not available. Flash Point: Not available. NFPA Rating: Not published. Explosion Limits, Lower: Not available. Upper: Not available. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with skin and eyes. Avoid ingestion and inhalation. Use only in a chemical fume hood. Storage: Keep away from heat, sparks, and flame. Store in a cool, dry place. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate general or local, explosion-proof ventilation to keep airborne levels to acceptable levels. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134. Always use a NIOSH-approved respirator when necessary. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Not available. Appearance: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Vapor Density: Not available. Evaporation Rate: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Decomposition Temperature: Not available. Solubility: Not available. Specific Gravity/Density: Not available. Molecular Formula: Not available. Molecular Weight: Not available. Section 10 - STABILITY AND REACTIVITY Chemical Stability: Has not been fully evaluated. Conditions to Avoid: Light, excess heat. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 1428-33-7 unlisted. LD50/LC50: Not available. Carcinogenicity: Allyl 1,1,2,2-Tetrafluoroethyl ether - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION For further information, contact Fisher Scientific. Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION CDG/CPL IMO Not regulated as a hazardous material. IATA Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Canadian TDG No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: WGK (Water Danger/Protection) CAS# 1428-33-7: Canada None of the chemicals in this product are listed on the DSL/NDSL list. WHMIS: Not available. CAS# 1428-33-7 is not listed on Canada's Ingredient Disclosure List. Exposure Limits US FEDERAL TSCA CAS# 1428-33-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): F,Xn
• 风险声明 (欧洲): R11;R20/22
• 安全声明 (欧洲): S16-S23-S33
• 危险品运输编码: UN 3271
• 包装等级: II
• 危险类别: 3.1
• 海关编码: 2909199090

合成路线

116-14-3 107-18-6 ~% 1428-33-7

文献：Doklady Akademii Nauk SSSR, , vol. 121, p. 307,309 Doklady Chemistry, 118-123<1958>541,543

上下游产品

上游产品  2
116-14-3 107-18-6
下游产品  3
113991-42-7 731-21-5 756-76-3

海关

海关编码	2909199090
中文概述	2909199090. 其他无环醚及其卤化衍生物（包括磺化，硝化或亚硝化衍生物）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%