10130-87-7

• 常用中文名：2-甲氧基苯磺酰氯
• 常用英文名：2-Methoxybenzenesulfonyl chloride
• CAS号：10130-87-7
• 分子式：C₇H₇ClO₃S
• 分子量：206.647
• 相关类别： 有机原料 羧酸类化合物及衍生物 羧酸酰卤化物
• 发布时间：2018-07-29 19:05:16
• 更新时间：2024-01-02 12:33:01

名称

• 中文名: 2-甲氧基苯磺酰氯
• 英文名: 2-Methoxybenzenesulfonyl chloride
• 英文别名: Benzenesulfonyl chloride, 2-methoxy-; 2-Methoxy-benzenesulfonyl chloride; 2-Methoxybenzenesulfonyl chloride

物化性质

• 密度: 1.4±0.1 g/cm3
• 沸点: 305.1±25.0 °C at 760 mmHg
• 熔点: 50-54ºC
• 分子式: C₇H₇ClO₃S
• 分子量: 206.647
• 闪点: 138.3±23.2 °C
• 精确质量: 205.980438
• PSA: 51.75000
• LogP: 1.90
• 外观性状: 固体;White to Light yellow powder to crystal
• 蒸汽压: 0.0±0.6 mmHg at 25°C
• 折射率: 1.536
• 储存条件: 2-8°C

MSDS

Material Safety Data Sheet Section1. Identification of the substance Product Name: 2-Methoxybenzenesulfonyl chloride Synonyms: Section2. Hazards identification Harmful by inhalation, in contact with skin, and if swallowed. H317:May cause an allergic skin reaction P280:Wear protective gloves/protective clothing/eye protection/face protection Section3. Composition/information on ingredients. Ingredient name:2-Methoxybenzenesulfonyl chloride CAS number:10130-87-7 Section4. First aid measures Immediately wash skin with copious amounts of water for at least 15 minutes while removing Skin contact: contaminated clothing and shoes. If irritation persists, seek medical attention. Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical attention. Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention. Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention. Section5. Fire fighting measures In the event of a fire involving this material, alone or in combination with other materials, use dry powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus should be worn. Section6. Accidental release measures Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national standards. Respiratory precaution:Wear approved mask/respirator Hand precaution:Wear suitable gloves/gauntlets Skin protection:Wear suitable protective clothing Eye protection:Wear suitable eye protection Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container for disposal. See section 12. Environmental precautions: Do not allow material to enter drains or water courses. Section7. Handling and storage Handling:This product should be handled only by, or under the close supervision of, those properly qualified in the handling and use of potentially hazardous chemicals, who should take into account the fire, health and chemical hazard data given on this sheet. Storage:Store in closed vessels. Section8. Exposure Controls / Personal protection Engineering Controls: Use only in a chemical fume hood. Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles. General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse. Section9. Physical and chemical properties Not specified Appearance: Boiling point:No data Melting point:No data Flash point:No data Density:No data Molecular formula:C7H7ClO3S Molecular weight:206.6 Section10. Stability and reactivity Conditions to avoid: Heat, flames and sparks. Materials to avoid: Oxidizing agents. Possible hazardous combustion products: Carbon monoxide, hydrogen chloride, sulfur oxides. Section11. Toxicological information No data. Section12. Ecological information No data. Section13. Disposal consideration Arrange disposal as special waste, by licensed disposal company, in consultation with local waste disposal authority, in accordance with national and regional regulations. Section14. Transportation information UN Number:UN3261 Class: 8 Packing group: III Proper shipping name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (2-Methoxybenzenesulfonyl chloride) Section15. Regulatory information No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302, or have known CAS numbers that exceed the threshold reporting levels established by SARA Title III, Section 313. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): Xi
• 风险声明 (欧洲): R34
• 安全声明 (欧洲): 26-36/37/39
• 危险品运输编码: UN 3261
• 包装等级: Ⅲ
• 海关编码: 2909309090

合成路线

100-66-3 ~82% 10130-87-7

文献：Milburn, Robert R.; Snieckus, Victor Angewandte Chemie - International Edition, 2004 , vol. 43, # 7 p. 892 - 894

5720-06-9 ~82% 10130-87-7

文献：Debergh, J. Robb; Niljianskul, Nootaree; Buchwald, Stephen L. Journal of the American Chemical Society, 2013 , vol. 135, # 29 p. 10638 - 10641

90-04-0 ~22% 10130-87-7

文献：Binisti, Carine; Assogba, Leon; Touboul, Estera; Mounier, Carine; Huet, Jack; Ombetta, Jean-Edouard; Dong, Chang Zhi; Redeuilh, Catherine; Heymans, Francoise; Godfroid, Jean-Jacques European Journal of Medicinal Chemistry, 2001 , vol. 36, # 10 p. 809 - 828

578-57-4 ~% 10130-87-7

文献：Journal of Organic Chemistry, , vol. 68, # 21 p. 8274 - 8276

13165-78-1 ~% 10130-87-7

文献：Australian Journal of Chemistry, , vol. 6, p. 318

3425-23-8 ~% 10130-87-7

文献：Chemische Berichte, , vol. 90, p. 841,843

68516-52-9 ~% 10130-87-7

文献：Journal of the Chemical Society [Section] C: Organic, , p. 1265 - 1267

海关

海关编码	2909309090
中文概述	2909309090 其他芳香醚及其卤化衍生物、磺化、硝化衍生物（包括亚硝化衍生物）。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%