16595-48-5

• 常用中文名：2-[7-(1,3-二氢-1,3,3-三甲基-2H-吲哚-2-亚基]-1,3,5-庚三烯基]-1,3,3-三甲基-3H-吲哚高氯酸盐
• 常用英文名：1,1',3,3,3',3'-hexamethylindotricarbocyanine perchlorate
• CAS号：16595-48-5
• 分子式：C₂₉H₃₃ClN₂O₄
• 分子量：509.04
• 相关类别： 研究领域 其他
• 发布时间：2018-12-23 12:09:14
• 更新时间：2024-01-11 21:42:47
• 1,1',3,3',3'-六甲基吲哚三碳菁高氯酸盐(HITC)是一种长波长、膜电位敏感的染料。它是一种慢响应电位荧光团,也被用作红外激光器的激光染料。

名称

• 中文名: 2-[7-(1,3-二氢-1,3,3-三甲基-2H-吲哚-2-亚基]-1,3,5-庚三烯基]-1,3,3-三甲基-3H-吲哚高氯酸盐
• 英文名: 1,1',3,3,3',3'-hexamethylindotricarbocyanine perchlorate
• 中文别名: 2-[7-(1,3-二氢-1,3,3-三甲基-2H-吲哚-2-亚基]-1,3,5-庚三烯基]-1,3,3-三甲基-3H-吲哚高氯酸盐; 1,1',3,3,3',3'-六甲基吲哚三羰花青高氯酸盐
• 英文别名: HITC PERCHLORATE); 1,1'',3,3,3'',3''-HEXAMETHYLINDOTRICARBO-CYANINE PERCHLORATE,LASER GADE; 1,1',3,3,3',3',-HEXAMETHYLINDOTRICARBOCYANINE PERCHLORATE,LASER GRADE,PURE; 1,3,3,1'',3'',3''-Hexamethyl-2,2''-indotricarbocyanine perchlorate; MFCD00067693; 3,3-trimethyl-rienyl]-perchlorate; HITCP; 1,1',3,3,3',3'-HEXAMETHYL-2,2'-INDOTRICARBOCYANINE PERCHLORATE; 1,1',3,3,3',3'-hexamethylindotricarbocyanine; 1,1',3,3,3',3',-Hexamethylindotricarbocyanineperchlorate,pure,laser grade; EINECS 240-652-5

物化性质

• 熔点: 235ºC (dec.)(lit.)
• 分子式: C₂₉H₃₃ClN₂O₄
• 分子量: 509.04
• 精确质量: 508.21300
• PSA: 80.52000
• LogP: 6.91080
• 储存条件:

  密闭于阴凉干燥环境中

• 稳定性:

  遵照规定使用和储存则不会分解。

• 分子结构:

  1、摩尔折射率：无可用

  2、 摩尔体积（cm³/mol）：无可用

  3、 等张比容（90.2K）：无可用

  4、 表面张力（dyne/cm）：无可用

  5、 极化率：无可用

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:5

  4.可旋转化学键数量:4

  5.互变异构体数量:无

  6.拓扑分子极性表面积80.5

  7.重原子数量:36

  8.表面电荷:0

  9.复杂度:852

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:4

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:2

• 更多:

  1. 性状：无可用

  2. 密度（g/mL,25/4℃）：无可用

  3. 相对蒸汽密度（g/mL,空气=1）：无可用

  4. 熔点（ºC）：235

  5. 沸点（ºC,常压）：无可用

  6. 沸点（ºC,5.2kPa）：无可用

  7. 折射率：无可用

  8. 闪点（ºC）：无可用

  9. 比旋光度（º）：无可用

  10. 自燃点或引燃温度（ºC）：无可用

  11. 蒸气压（kPa,25ºC）：无可用

  12. 饱和蒸气压（kPa,60ºC）：无可用

  13. 燃烧热（KJ/mol）：无可用

  14. 临界温度（ºC）：无可用

  15. 临界压力（KPa）：无可用

  16. 油水（辛醇/水）分配系数的对数值：无可用

  17. 爆炸上限（%,V/V）：无可用

  18. 爆炸下限（%,V/V）：无可用

  19. 溶解性：无可用

生物活性

• 描述: 1,1',3,3',3'-六甲基吲哚三碳菁高氯酸盐(HITC)是一种长波长、膜电位敏感的染料。它是一种慢响应电位荧光团,也被用作红外激光器的激光染料。
• 相关类别:
  研究领域 >> 其他

MSDS

Name: 1 1 3 3 3 3 -Hexamethylindotricarbocyanine perchlorate laser grade Material Safety Data Sheet Synonym: 3H-Indolium CAS: 16595-48-5 Section 1 - Chemical Product MSDS Name:1 1 3 3 3 3 -Hexamethylindotricarbocyanine perchlorate laser grade Material Safety Data Sheet Synonym:3H-Indolium Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 16595-48-5 3H-Indolium,2-7-(1,3-dihydro-1,3,3-tri ca. 100 240-652-5 Hazard Symbols: O Risk Phrases: 8 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Contact with combustible material may cause fire.Heat sensitive. Potential Health Effects Eye: May cause conjunctivitis. May cause permanent corneal opacification. Skin: May cause severe irritation and possible burns. Ingestion: May cause burns to the gastrointestinal tract. May cause nausea, vomiting, and diarrhea, possibly with blood. Inhalation: May cause acute pulmonary edema, asphyxia, chemical pneumonitis, and upper airway obstruction caused by edema. Chronic: Effects may be delayed. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Discard contaminated clothing in a manner which limits further exposure. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water with caution and in flooding amounts. Some oxidizers may react explosively with hydrocarbons(fuel). May accelerate burning if involved in a fire. Containers may explode when heated. Extinguishing Media: Use agent most appropriate to extinguish fire. Contact professional fire-fighters immediately. For small fires, do NOT use dry chemicals, carbon dioxide, halon or foams. USE WATER ONLY. For large fires flood fire with water from a distance. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Remove all sources of ignition. Provide ventilation. Do not use combustible materials such as paper towels to clean up spill. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Keep away from heat, sparks and flame. Avoid contact with clothing and other combustible materials. Do not ingest or inhale. Storage: Keep away from heat, sparks, and flame. Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels. Exposure Limits CAS# 16595-48-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder Color: green Odor: none reported pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 235 deg C(dec) Autoignition Temperature: Not applicable. Flash Point: Not applicable. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: 235 deg C Solubility in water: Not available. Specific Gravity/Density: Not available. Molecular Formula: C29H33ClN2O4 Molecular Weight: 509.03 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Unstable if heated. Conditions to Avoid: Incompatible materials, ignition sources, dust generation, combustible materials, reducing agents, strong oxidants, heat. Incompatibilities with Other Materials: Reducing agents, heat, strong reducing agents, organic matter, finely powdered metals. Hazardous Decomposition Products: Hydrogen chloride, nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 16595-48-5 unlisted. LD50/LC50: Not available. Carcinogenicity: 3H-Indolium,2-7-(1,3-dihydro-1,3,3-trimethyl-2H-indol-2-ylie - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: OXIDIZING SOLID, N.O.S.* Hazard Class: 5.1 UN Number: 1479 Packing Group: III IMO Shipping Name: OXIDIZING SOLID, N.O.S. Hazard Class: 5.1 UN Number: 1479 Packing Group: III RID/ADR Shipping Name: OXIDIZING SOLID, N.O.S. Hazard Class: 5.1 UN Number: 1479 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: O Risk Phrases: R 8 Contact with combustible material may cause fire. Safety Phrases: S 17 Keep away from combustible material. WGK (Water Danger/Protection) CAS# 16595-48-5: No information available. Canada CAS# 16595-48-5 is listed on Canada's NDSL List. CAS# 16595-48-5 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 16595-48-5 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。

安全

• 危害码 (欧洲): Xi;O
• 风险声明 (欧洲): R8;R36/37/38
• 安全声明 (欧洲): S17-S26-S36
• 危险品运输编码: UN 1479
• 包装等级: III
• 危险类别: 5.1