132-68-3

• 常用中文名：N-萘-1-基-3-羟基萘-2-甲酰胺
• 常用英文名：Naphthol AS-BO
• CAS号：132-68-3
• 分子式：C₂₁H₁₅NO₂
• 分子量：313.34900
• 相关类别： 染料及颜料 染料 冰染染料(显色染料)
• 发布时间：2018-12-11 13:31:58
• 更新时间：2024-01-02 14:33:04
• 【用途一】
  主要用于棉织物的印染打底剂，并用于快色素及有机颜料的中间体
  【用途二】
  色酚 AS-BO 主要用于棉纤维染色和棉布印花打底剂，也用于维纶、黏胶纤维、蚕丝、锦纶的染色。与红色基 B 配合染紫酱色，有较好的日晒牢度。也用于制造快色素和有机颜料。
  【用途三】
  主要用作棉纤维染色、印花的打底剂，并用作有机颜料中间体，以及用于制造快色素。

名称

• 中文名: N-萘-1-基-3-羟基萘-2-甲酰胺
• 英文名: 3-Hydroxy-N-naphthalen-1-ylnaphthalene-2-carboxamide
• 中文别名: 2-羟基-3-萘甲酸-1-萘酰胺; 色酚AS-BO; 纳夫妥AS-BO; 3-羟基-N-(1-萘基)-2-萘甲酰胺; 冰染偶氮组分4
• 英文别名: Azonaphtol AN; Naphthol AS-BO; Cibanaphthol RN; 3-HYDROXY-NAPHTHALENE-2-CARBOXYLIC ACID NAPHTHALEN-1-YLAMIDE; naphthol ASSW; Acco Naphthol AS-BO; Brenthol AN; 2-Hydroxy-3-naphthoic Acid 1-Naphthylamide; Dragonthol BO; EINECS 205-075-5; Naphtanilide BO; 3-hydroxy-[2]naphthoic acid-[1]naphthylamide; Azoic Coupling Component 4; 3-Hydroxy-N-(naphthyl-(1))-naphthamid-(2); Solunaptol ANL; 3-Hydroxy-[2]naphthoesaeure-[1]naphthylamid; MFCD00043900; Naphtoelan BO; 3-Hydroxy-N-(1-naphthyl)-2-naphthamide; Naphthoide BO

物化性质

• 密度: 1.333 g/cm3
• 沸点: 479.3ºC at 760 mmHg
• 熔点: 222~223℃
• 分子式: C₂₁H₁₅NO₂
• 分子量: 313.34900
• 精确质量: 313.11000
• PSA: 49.33000
• LogP: 5.02390
• 外观性状: 淡浅黄色黄色粉末
• 蒸汽压: 8.27E-10mmHg at 25°C
• 折射率: 1.778
• 储存条件: 室温，密封
• 稳定性:

  基本性质

  该品为米色粉末。不溶于水和碳酸钠溶液，可溶于二甲苯。于氢氧化钠溶液中呈黄色。熔点为222-223℃

• 分子结构:

  五、分子性质数据：

  1、 摩尔折射率：98.39

  2、 摩尔体积（m³/mol）：234.9

  3、 等张比容（90.2K）：669.5

  4、 表面张力（3.0 dyne/cm）：65.9

  5、 极化率（0.5 10 ^-24cm ³）：39.00

• 计算化学:

  1.疏水参数计算参考值（XlogP）:5.5

  2.氢键供体数量:2

  3.氢键受体数量:2

  4.可旋转化学键数量:2

  5.互变异构体数量:9

  6.拓扑分子极性表面积49.3

  7.重原子数量:24

  8.表面电荷:0

  9.复杂度:451

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

MSDS

3-Hydroxy-N-(1-naphthyl)-2-naphthamide Revision number: 5 SAFETY DATA SHEET Section1. IDENTIFICATION Product name:3-Hydroxy-N-(1-naphthyl)-2-naphthamide Revision number:5 Section2. HAZARDS IDENTIFICATION GHS classification PHYSICAL HAZARDSNot classified Not classified HEALTH HAZARDS ENVIRONMENTAL HAZARDSNot classified GHS label elements, including precautionary statements Pictograms or hazard symbolsNone No signal word Signal word Hazard statementsNone None Precautionary statements: Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/mixture:Substance Components:3-Hydroxy-N-(1-naphthyl)-2-naphthamide Percent:.... CAS Number:132-68-3 Synonyms:2-Hydroxy-3-naphthoic Acid 1-Naphthylamide , Naphthol AS-BO , Azoic Coupling Component 4 C21H15NO2 Chemical Formula: Section4. FIRST AID MEASURES Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. Skin contact:Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation or rash occurs: Get medical advice/attention. Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion:Get medical advice/attention if you feel unwell. Rinse mouth. A rescuer should wear personal protective equipment, such as rubber gloves and air- Protection of first-aiders: tight goggles. Section5. FIRE-FIGHTING MEASURES Suitable extinguishingDry chemical, foam, water spray, carbon dioxide. media: Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to from the chemical:generate poisonous fume. 3-Hydroxy-N-(1-naphthyl)-2-naphthamide Section5. FIRE-FIGHTING MEASURES Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Remove movable containers if safe to do so. Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment. equipment for firefighters: Section6. ACCIDENTAL RELEASE MEASURES Use personal protective equipment. Keep people away from and upwind of spill/leak. Personal precautions, protective equipment and Entry to non-involved personnel should be controlled around the leakage area by emergency procedures: roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it. containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with up: appropriate laws and regulations. Section7. HANDLING AND STORAGE Precautions for safe handling Handling is performed in a well ventilated place. Wear suitable protective equipment. Technical measures: Prevent dispersion of dust. Wash hands and face thoroughly after handling. Use a local exhaust if dust or aerosol will be generated. Advice on safe handling: Avoid contact with skin, eyes and clothing. Conditions for safe storage, including any incompatibilities Storage conditions:Keep container tightly closed. Store in a cool and dark place. Store away from incompatible materials such as oxidizing agents. Packaging material:Comply with laws. Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Install a closed system or local exhaust as possible so that workers should not be Engineering controls: exposed directly. Also install safety shower and eye bath. Personal protective equipment Respiratory protection: Dust respirator. Follow local and national regulations. Hand protection:Protective gloves. Eye protection:Safety glasses. A face-shield, if the situation requires. Skin and body protection: Protective clothing. Protective boots, if the situation requires. Section9. PHYSICAL AND CHEMICAL PROPERTIES Physical state (20°C):Solid Form:Crystal- Powder Colour:White - Slightly pale yellow red Odour:No data available pH: No data available Melting point/freezing point:No data available No data available Boiling point/range: Flash point:No data available Flammability or explosive limits: No data available Lower: Upper:No data available No data available Relative density: Solubility(ies): No data available [Water] [Other solvents]No data available 3-Hydroxy-N-(1-naphthyl)-2-naphthamide Section10. STABILITY AND REACTIVITY Chemical stability:Stable under proper conditions. Possibility of hazardous No special reactivity has been reported. reactions: Incompatible materials: Oxidizing agents Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx) products: Section11. TOXICOLOGICAL INFORMATION ipr-rat LD50:7320 mg/kg Acute Toxicity: orl-rat LD:>12 g/kg Skin corrosion/irritation: No data available Serious eyeNo data available damage/irritation: Germ cell mutagenicity: No data available Carcinogenicity: IARC =No data available No data available NTP = Reproductive toxicity:No data available QJ1897300 RTECS Number: Section12. ECOLOGICAL INFORMATION Ecotoxicity: Fish:No data available Crustacea:No data available Algae:No data available Persistence / degradability: No data available BioaccumulativeNo data available potential(BCF): Mobility in soil Log Pow:No data available Soil adsorption (Koc):No data available Henry's LawNo data available constant(PaM3/mol): Section13. DISPOSAL CONSIDERATIONS Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when disposing of the substance. Section14. TRANSPORT INFORMATION Hazards Class:Does not correspond to the classification standard of the United Nations UN-No:Not listed Section15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002 and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were prescribed. 3-Hydroxy-N-(1-naphthyl)-2-naphthamide SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

毒理学数据: 急性毒性数据： 大鼠经口LD：>12mg/kg 大鼠腹腔LD50：7320mg/kg 小鼠经口LD：>12mg/kg 小鼠腹腔LD50：5280mg/kg CHEMICAL IDENTIFICATION RTECS NUMBER : QJ1897300 CHEMICAL NAME : 2-Naphthalenecarboxamide, 3-hydroxy-N-1-naphthalenyl- CAS REGISTRY NUMBER : 132-68-3 BEILSTEIN REFERENCE NO. : 1824371 LAST UPDATED : 199701 DATA ITEMS CITED : 5 MOLECULAR FORMULA : C21-H15-N-O2 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD - Lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : >12 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 33(10),57,1989 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 7320 mg/kg TOXIC EFFECTS : Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Behavioral - irritability Gastrointestinal - other changes REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 33(10),57,1989 TYPE OF TEST : LD - Lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : >12 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 33(10),57,1989 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 5280 mg/kg TOXIC EFFECTS : Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Behavioral - irritability Gastrointestinal - other changes REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 33(10),57,1989

安全

• 危害码 (欧洲): Xi
• RTECS号: QJ1897300
• 海关编码: 2924299090

合成路线

134-32-7 92-70-6 ~% 132-68-3

文献：DE293897 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 12, p. 912

551-06-4 92-70-6 ~% 132-68-3

文献：DE506837 , ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 17, p. 696

上下游产品

上游产品  3
134-32-7 92-70-6 551-06-4
下游产品  0

制备

生产方法简述

以2,3酸为原料，用氯苯与烧碱成盐、脱水，再与甲萘胺和三氯化磷缩合，而后经中和、蒸馏、过滤、洗涤及干燥而得。原料消耗(kg/t)2,3酸（100%） 660甲萘胺 500三氯化磷 250氯苯（98%） 173纯碱（98%） 500

海关

海关编码	2924299090
中文概述	2924299090. 其他环酰胺（包括环氨基甲酸酯）（包括其衍生物以及他们的盐）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途, 包装
Summary	2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%